| Issue |
Korean Journal of Chemical Engineering,
Vol.34, No.9, 2390-2396, 2017
Vol.34, No.9, 2390-2396, 2017
De-chlorination and solidification of radioactive LiCl waste salt by using SiO2-Al2O3-P2O5 (SAP) inorganic composite including B2O3 component
SAP (SiO2-Al2O3-P2O5) composite has been recently studied in KAERI to deal with the immobilization of radioactive salt waste, one of the most problematic wastes in the pyro-chemical process. Highly unstable salt waste was successfully converted into stable compounds by the dechlorination process with SAPs, and then a durable waste form with a high waste loading was produced when adding glassy materials to dechlorination product. In the present study, U-SAP composite which is SAP bearing glassy component (Boron) was synthesized to remove the adding and mixing steps of glassy materials for a monolithic wasteform. With U-SAPs prepared by a sol-gel process, a series of wasteforms were fabricated to identify a proper reaction condition. Physical and chemical properties of dechlorination products and U-SAP wasteforms were characterized by XRD, DSC, SEM, TGA and PCT-A. A U-SAP wasteform showed suitable properties as a radioactive wasteform such as dense surface morphology, high waste loading, and high durability at the optimized U-SAP/salt ratio 2.
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