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Issue
Korean Journal of Chemical Engineering,
Vol.34, No.4, 1149-1158, 2017
Liquid-liquid equilibrium and physical properties of aqueous mixtures of poly(vinyl pyrrolidone) with potassium phosphate at different pH: Experiments and modeling
Rahmani A, Rostami AA, Pirdashti M, Mobalegholeslam P
Liquid-liquid equilibrium data for poly vinyl pyrrolidone (PVP) K30+K2HPO4+H2O system were measured at 298.15 K and different pH values (7.54, 8.05, and 9.47). A binodal curve was fitted to the Merchuk equation and the tie line compositions were fitted to both the Othmer-Tobias and Bancroft equations. The refractive indices and densities of several homogeneous binary and ternary solutions used for calibration were also measured within a range of 0-30 mass% of PVP and 0-50 mass% of K2HPO4. Then, the viscosities, densities, electrical conductivities, and refractive indices of binary (PVP K30+water; potassium phosphate+water) and ternary (PVP K30+potassium phosphate+water) systems were measured and correlated at different pH values. The density data showed a linear variation of the polymer and salt mass fractions. The viscosity data of PVP K30 solutions were correlated as a function of the mass fractions by using a nonlinear equation. The effects of the tie line lengths on the densities and viscosities of the aqueous two-phase systems were represented. Also, the modified UNIFAC-NRF is used to calculate the phase equilibria of the mention system. The fitted binary interaction parameters of the model were reported.
Keywords: Liquid-liquid Equilibrium Data; Viscosity; Density; Poly Vinyl Pyrrolidone; Potassium Phosphate; Modified UNIFAC-NRF
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[Cited By]
  1. Edrisi S, Bakhshi H, Rahimnejad M, Korean Journal of Chemical Engineering, 36(5), 780, 2019
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