Issue
Korean Journal of Chemical Engineering,
Vol.34, No.4, 987-996, 2017
Process optimization and kinetic modeling for esterification of propionic acid with benzyl alcohol on ion-exchange resin catalyst
Benzyl propionate, an ester with floral and fruity odor, has significant applications in perfumery and flavor industries. This paper describes the optimization of the synthesis of benzyl propionate catalyzed by Amberlyst-15. The effects of various process parameters such as catalyst loading, alcohol-to-acid molar ratio and reaction temperature on propionic acid conversion and yield of ester were assessed by response surface methodology (RSM). The external and internal mass transfer limitations were found to be absent. Analysis of variance (ANOVA) showed that the acquired quadratic model successfully interpreted the experimental data with the coefficient of determination values, (R2>0.98) and adjusted R2 values, (>0.97). The RSM model was validated by good agreement between the model predicted and experimental values for responses. Pseudohomogeneous (PH) kinetic model was used and validated (R2>0.95) with the experimental data. The activation energy and frequency factor were evaluated as 42.07 kJ mol-1 and 19,874.64 L mol-1 min.1, respectively.
[References]
  1. McKetta JJ, Encyclopedia of Chemical Processing and Design; Marcel Dekker, New York (1983).
  2. Yadav GD, Mehta PH, Ind. Eng. Chem. Res., 33(9), 2198, 1994
  3. Lee HY, Yen LT, Chien IL, Huang HP, Ind. Eng. Chem. Res., 48(15), 7186, 2009
  4. Khder AERS, Appl. Catal. A: Gen., 343(1-2), 109, 2008
  5. Qin X, Zhao W, Han B, Liu B, Lian B, Wu S, Korean J. Chem. Eng., 32(6), 1064, 2015
  6. Zhou L, Niu Y, Yang J, Li C, Guo X, Li L, Qiu T, Korean J. Chem. Eng., 33(8), 2478, 2016
  7. Su H, Wang X, Kim YG, Kim SB, Seo YG, Kim JS, Kim CJ, Korean J. Chem. Eng., 31(11), 2070, 2014
  8. Valdeilson SB, Ivoneide CL, Garcia FAC, Dias SCL, Dias JA, Catal. Today, 133-135, 106, 2008
  9. Pereira CSM, Pinho SP, Silva VMTM, Rodrigues AE, Ind. Eng. Chem. Res., 47(5), 1453, 2008
  10. Silva VMTM, Rodrigues AE, Chem. Eng. Sci., 61(2), 316, 2006
  11. JagadeeshBabu PE, Sandesh K, Saidutta MB, Ind. Eng. Chem. Res., 50(12), 7155, 2011
  12. Sharma M, Wanchoo RK, Toor AP, Ind. Eng. Chem. Res., 53(6), 2167, 2014
  13. Schmid B, Doker M, Gmehling J, Ind. Eng. Chem. Res., 47(3), 698, 2008
  14. Teo HTR, Saha B, J. Catal., 228(1), 174, 2004
  15. Toor AP, Sharma M, Kumar G, Wanchoo RK, Bull. Chem. React. Eng. Catal., 6, 23, 2011
  16. Izci A, Bodur F, React. Funct. Polym., 67(12), 1458, 2007
  17. Ali SH, Tarakmah A, Merchant SQ, Al-Sahhaf T, Chem. Eng. Sci., 62(12), 3197, 2007
  18. Delgado P, Sanz MT, Beltran S, Chem. Eng. J., 126(2-3), 111, 2007
  19. Cruz VJ, Izquierdo JF, Cunill F, Tejero J, Iborra M, Fite C, Bringue R, React. Funct. Polym., 67(3), 210, 2007
  20. Kolah AK, Asthana NS, Vu DT, Lira CT, Miller DJ, Ind. Eng. Chem. Res., 47(15), 5313, 2008
  21. Khan JA, Jamal Y, Shahid A, Boulanger BO'N, Korean J. Chem. Eng., 33(2), 582, 2016
  22. Chen W, Yin P, Chen H, Wang Z, Ind. Eng. Chem. Res., 51(15), 5402, 2012
  23. Yang JI, Cho SH, Kim HJ, Joo H, Jung H, Lee KY, Can. J. Chem. Eng., 85(1), 83, 2007
  24. Liu W, Yin P, Liu XG, Chen W, Chen H, Liu CP, Qu RJ, Xu Q, Energy Conv. Manag., 76, 1009, 2013
  25. Nandiwale KY, Niphadkar PS, Joshi PN, Sonar SK, Deshpande SS, Patil VS, Bokade VV, Appl. Catal. A: Gen., 460-461, 90, 2013
  26. Tesser R, Di Serio M, Guida M, Nastasi M, Santacesaria E, Ind. Eng. Chem. Res., 44(21), 7978, 2005
  27. Pera-Titus M, Bausach M, Tejero J, Iborra M, Fite C, Cunill F, Izquierdo JF, Appl. Catal. A: Gen., 323, 38, 2007
  28. Mao W, Wang XL, Wang H, Chang HY, Zhang XW, Han J, Chem. Eng. Process., 47(5), 761, 2008
  29. Chandane VS, Rathod AP, Wasewar KL, Sonawane SS, Korean J. Chem. Eng., 34(1), 249, 2017
  30. Nandiwale KY, Bokade VV, Ind. Eng. Chem. Res., 53(49), 18690, 2014
  31. Yin P, Chen L, Wang Z, Qu RJ, Liu XG, Xu Q, Ren SH, Fuel, 102, 499, 2012
  32. Liao CC, Chung TW, Chem. Eng. Res. Des., 91(12), 2457, 2013
  33. Liu HL, Chiou YR, Chem. Eng. J., 112(1-3), 173, 2005
  34. Su CH, Bioresour. Technol., 130, 522, 2013
  35. Patel A, Brahmkhatri V, Fuel Process. Technol., 113, 141, 2013
  36. Brahmkhatri V, Patel A, Appl. Catal. A: Gen., 403(1-2), 161, 2011