About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.34, No.3, 734-740, 2017
Efficient oxidative removal of 4-tert-octylphenol and 17α-ethynylestradiol from aqueous solutions using ferrate(VI)
Tiwari D, Sailo L, Choi SI, Yoon YY, Lee SM
Ferrate(VI) was utilized to treat micro-pollutants--4-tert-octylphenol (TOP) and 17α ethynylestradiol (EE2)--from aqueous solutions. Batch studies were conducted at various pHs (7.0 to 12.0) and concentrations of TOP/or EE2 (0.03 to 0.3mmol/L) using 0.1mmol/L ferrate(VI). Time-dependent degradation of TOP and EE2 was assessed as a function of pH and micro-pollutant concentrations and we found that significant mineralization of micro-pollutants was achieved by ferrate(VI) treatment. Second-order kinetics showed 1 : 1 stoichiometry was obtained between the ferrate(VI) and TOP/or EE2. Further, the effect of several background electrolytes on degradation of TOP and EE2 by ferrate(VI) was evaluated, showing insignificant effect of degradation.
Keywords: Ferrate(VI); 4-Tert-octylphenol; 17α-Ethynylestradiol; Endocrine Disruptors; Mineralization; Background Electrolytes
[References]
  1. Thanhmingliana, Lee SM, Tiwari D, Prasad SK, RSC Adv., 5, 46834, 2015
  2. Snyder SA, Westerhoff P, Yoon Y, Sedlak DL, Environ. Eng. Sci., 20, 449, 2003
  3. Zafra-Gomez A, Ballesteros O, Navalon A, Vilchez JL, Microchem. J., 88, 87, 2008
  4. Zhao Q, Wang Q, Wu D, Fu X, Jiang T, Yin H, J. Ind. Eng. Chem., 18(4), 1326, 2012
  5. Niu J, Ding S, Zhang L, Zhao J, Feng C, Chemosphere, 93, 1, 2013
  6. Larcher S, Yargeau V, Environ. Pollut., 173, 17, 2013
  7. Nowotny N, Epp B, von Sonntag C, Fahlenkamp H, Environ. Sci. Technol., 41, 2050, 2007
  8. Nakada N, Shinohara H, Murata A, Kiri K, Managaki S, Sato N, Takada H, Water Res., 41, 4373, 2007
  9. Yang B, Ying GG, Zhao JL, Liu S, Zhou LJ, Chen F, Water Res., 46, 2194, 2012
  10. Aoki M, Kurasaki M, Saito T, Seki S, Hosokawa T, Takahashi Y, Fujita H, Iwakura T, Life Sci., 741, 2301, 2004
  11. Hawrelak M, Bennett E, Metcalfe C, Chemosphere, 39, 745, 1999
  12. Yamazaki S, Mori T, Katou T, Sugihara M, Saeki A, Tanimura T, J. Photochem. Photobiol. A-Chem., 199, 330, 2008
  13. White R, Jobling S, Hoare SA, Sumpter JP, Parker MG, Endocrinology, 135, 175, 1994
  14. Kwak HI, Bae MO, Lee MH, Lee YS, Lee BJ, Kang KS, Chae CH, Sung HJ, Shin JS, Kim JH, Mar WC, Sheen YY, Cho MH, Environ. Toxicol. Chem., 20, 787, 2001
  15. Lech JJ, Lewis SK, Ren L, Fundamental Appl. Toxicol., 30, 229, 1996
  16. Yang X, Liu M, Wang Z, Li Q, Zhang Z, J. Environ. Sci., 25, 1712, 2013
  17. Zhou JL, Environ. Sci. Technol., 40, 2225, 2006
  18. Ferreira-Leach AMR, Hill EM, Marine Environ. Res., 51, 75, 2001
  19. Gadzala-Kopciuch R, Filipiak A, Buszewski B, Talanta, 74, 655, 2008
  20. Snyder SA, Keith TL, Verbrugge DA, Snyder EM, Gross TS, Kannan K, Giesy JP, Environ. Sci. Technol., 33, 2814, 1999
  21. Li C, Li XZ, Graham N, Gao NY, Water Res., 42, 109, 2008
  22. USFDA, U.S. Food and Drug Administration (USFDA) and National Center for Toxicological Research (NCTR), Endocrine Disruptor Knowledge Base (EDKB), (2012), http://www.fda.gov/scienceresearch/bioinformaticstools/endocrinedisruptorknowledgebase/default.htm.
  23. Tiwari D, Yang JK, Lee SM, Env. Eng. Res., 10, 269, 2005
  24. Pachuau L, Lee SM, Tiwari D, Chem. Eng. J., 230, 141, 2013
  25. Jiang JQ, J. Hazard. Mater., 146(3), 617, 2007
  26. Sharma VK, Adv. Environ. Res., 6, 143, 2002
  27. Graham N, Jiang CC, Li XZ, Jiang JQ, Ma J, Chemosphere, 56, 949, 2004
  28. Tiwari D, Sailo L, Pachuau L, Sep. Purif. Technol., 132, 77, 2014
  29. Jiang JQ, J. Hazard. Mater., 146(3), 617, 2007
  30. Tiwari D, Kim HU, Choi BJ, Lee SM, Kwon OH, Choi KM, Yang JK, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 42, 803, 2007
  31. Lee YH, Yoon J, Gunten UV, Environ. Sci. Technol., 39, 8978, 2005
  32. Jiang JQ, Yin Q, Zhou JL, Pearce P, Chemosphere, 61, 544, 2005
  33. Tiwari D, Lalhriatpuia C, Lee SM, J. Ind. Eng. Chem., 30, 167, 2015
  34. Li C, Li XZ, Graham N, Gao NY, Water Res., 42, 109, 2008
  35. Zhang PY, Zhang GM, Dong JH, Fan MH, Zeng GM, Sep. Purif. Technol., 84, 46, 2012
  36. Sharma VK, Mishra SK, Ray AK, Chemosphere, 62, 128, 2006
  37. Sharma VK, Ill GWL, Millero FJ, Chemosphere, 82, 1083, 2011
  38. Anquandah GAK, Sharma VK, Panditi VR, Gardinali PR, Kim H, Oturan MA, Chemosphere, 91, 105, 2013
  39. Yang B, Ying GG, Zhang LJ, Zhou LJ, Liu S, Fang YX, Water Res., 45, 2261, 2011
  40. Jiang JQ, Zhou ZW, Pahl O, Sep. Purif. Technol., 88, 95, 2012
  41. Zhang ZH, Feng YJ, Liu Y, Sun QF, Gao P, Ren NQ, J. Hazard. Mater., 181(1-3), 1127, 2010
  42. Environment Agency UK: Environmental Risk Evaluation Report:4-tert-octylphenol (2005).
  43. MITI-List: Biodegradation and Bioaccumulation of Existing Chemical Substances under the Chemical Substance Control Law. National Institute of Technology and Evaluation, Japan (2002).
  44. Garcia-Araya JF, Beltran FJ, Aguinaco A, J. Chem. Technol. Biotechnol., 85(6), 798, 2010
  45. Sharma VK, Zboril R, Varma RS, Acc. Chem. Res., 48, 182, 2015
  46. Sharma VK, Chen L, Zboril R, ACS Sustain. Chem. Eng., 4, 18, 2016
  47. Rush JD, Zhao Z, Bielski BHJ, Free Rad. Res., 24, 187, 1996
  48. Ohta T, Kamachi T, Shiota Y, Yoshizawa K, J. Org. Chem., 66, 4122, 2001
  49. Sharma VK, O’Connor DB, Cabelli D, Inorg. Chim. Acta., 357, 4587, 2004
  50. Sharma VK, Mishra SK, Nesnas N, Environ. Sci. Technol., 40, 7222, 2006
  51. Kamachi T, Nakayama N, Yoshizawa K, Bull. Chem. Soc. Jpn., 81, 1212, 2008
  52. Noorhasan N, Patel B, Sharma VK, Water Res., 44, 927, 2010
  53. Yang J, Tiwari D, Yu M, Pachuau L, Kim W, Lee S, Environ. Technol., 31, 791, 2010
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.