| Issue |
Korean Journal of Chemical Engineering,
Vol.34, No.1, 214-224, 2017
Vol.34, No.1, 214-224, 2017
Density, refractive index and kinematic viscosity of MIPK, MEK and phosphonium-based ionic liquids and the excess and deviation properties of their binary systems
The density, refractive index, and kinematic viscosity were measured for extraction solvents for molybdenum: methyl ethyl ketone (MEK), methyl isopropyl ketone (MIPK), trihexyl tetradecyl phosphonium chloride ([P666,14] [Cl]), trihexyl tetradecyl phosphonium dicyanamide ([P666,14][DCA]) and trihexyl tetradecyl phosphonium bis (2,2,4-trimethyl pentyl) phosphinate ([P666,14][TMPP]) at atmospheric pressure for a temperature range of 288.15-318.15 K. The experimental data were correlated using the Daubert and Danner equation, a linear equation and the Goletz and Tassion equation. In addition, the excess molar volumes (VE) and the deviations in molar refractivity (ΔR) at 298.15 K were reported for the following binary systems: {MEK+[P666,14][Cl]}, {MEK+[P666,14][DCA]}, {MEK+[P666,14][TMPP]}, {MIPK+[P666,14][Cl]}, {MIPK+[P666,14][DCA]} and {MIPK+[P666,14][TMPP]}. The determined VE and ΔR values were correlated with the Redlich-Kister equation. The binary density and refractive index data at 298.15 K were also predicted using several mixing rules, and these results were then compared with the experimental data.
[References]
- Molybdenum, Chemicool Periodic Table. Chemicool.com. 17. Oct. 2012. http://www.chemicool.com/elements/molybdenum.html.
- Faneite AM, Garces SL, Aular JA, Urdaneta MR, Soto D, Fluid Phase Equilib., 334, 117, 2012
- Soriano AN, Doma BT, Li MH, J. Taiwan Inst. Chem. Eng., 41, 115, 2010
- Redlich O, Kister AT, Ind. Eng. Chem., 40, 345, 1948
- Lorentz HA, Wied. Ann. Phys., 9, 641, 1880
- Dale TP, Gladstone JH, Philos. Trans. R. Soc. Lond. Ser. A-Math. Phys. Eng. Sci., 148, 887, 1858
- Wiener O, Berichte uber die Verhandlungen der Koniglich-Sachsischen, 62, 256, 1910
- Heller W, J. Phys. Chem., 69, 1123, 1965
- Faranda S, Foca G, Marchetti A, Palyi G, Tassi L, Zucchi C, J. Mol. Liq., 111, 117, 2004
- Wisniak J, Thermochim. Acta, 257, 51, 1995
- Psutka S, Wichterle I, Fluid Phase Equilib., 264(1-2), 55, 2008
- Hwang IC, Park SJ, Han KJ, Fluid Phase Equilib., 309(2), 145, 2011
- Goncalves FAMM, Costa CSMF, Ferreira CE, Bernardo JCS, Johnson I, Fonseca IMA, Ferreira AGM, J. Chem. Thermodyn., 43(6), 914, 2011
- Jeong IY, Kwon RH, Park SJ, Choi YY, J. Chem. Eng. Data, 59(2), 289, 2014
- Resa JM, Gonzalez C, Goenaga JM, J. Chem. Eng. Data, 51(1), 73, 2006
- Froba AP, Kremer H, Leipertz A, J. Phys. Chem. B, 112(39), 12420, 2008
- Laesecke A, Fortin TJ, Splettt JD, Energy Fuels, 26(3), 1844, 2012
- Fortin TJ, Laesecke A, Freund M, Outcalt S, J. Chem. Thermodyn., 57, 276, 2013
- Chirico RD, Frenkel M, Magee JW, Diky V, Muzny CD, Kazakov AF, Kroenlein K, Abdulagatov I, Hardin GR, Acree WE, Brenneke JF, Brown PL, Cummings PT, de Loos TW, Friend DG, Goodwin ARH, Hansen LD, Haynes WM, Koga N, Mandelis A, Marsh KN, Mathias PM, McCabe , J. Chem. Eng. Data, 58(10), 2699, 2013
- Widegren JA, Laesecke A, Magee JW, Chem. Commun., 12, 1610, 2005
- Neves CMSS, Carvalho PJ, Freire MG, Coutinho JAP, J. Chem. Thermodyn., 43(6), 948, 2011
- Rintelen JC, Saylor JH, Gross PM, J. Am. Chem. Soc., 59, 1129, 1937
- Fermeglia M, Lapasin R, Torriano G, J. Chem. Eng. Data, 35, 260, 1990
- Clara RA, Marigliano ACG, Solimo HN, J. Chem. Eng. Data, 51(4), 1473, 2006
- Mears TW, Fookson A, Pomerantz P, Rich EH, Dussinger CS, Howard FL, J. Res. Natl. Bur. Stand., 44, 299, 1950
- Almeida HFD, Lopes-da-Silva JA, Freire MG, Coutinho JAP, J. Chem. Thermodyn., 57, 372, 2013
- De Lorenzi L, Fermeglia M, Torriano G, J. Chem. Eng. Data, 43(2), 183, 1998
- Daubert TE, Danner RP, Physical and Thermodynamic Properties of Pure Chemicals, Hemisphere Publishing Corp., New York (1989).
- Reid RC, Prausnitz JM, Poling BE, The Properties of Gases and Liquids, 4th Ed., McGraw-Hill, Singapore (1989).
- Oh JH, Park SJ, J. Chem. Eng. Data, 43(6), 1009, 1998
- Han KJ, Oh JH, Park SJ, Gmehling J, J. Chem. Eng. Data, 50(6), 1951, 2005
- Aminabhavi TM, Gopalakrishna B, J. Chem. Eng. Data, 40(4), 856, 1995
- Al-Dujaili AH, Yassen AA, Awwad AM, J. Chem. Eng. Data, 45, 647, 2000
- Akaike H, IEEE T. Automat. Contr., 19, 716, 1974
- Kirkup L, Data Analysis with Excel, Cambridge University Press:Cambridge (2002).
- Kim JI, Park SJ, Kim SB, Choi YY, Fluid Phase Equilib., 314, 7, 2012
- Kauzman W, Eyring H, J. Am. Chem. Soc., 62, 3113, 1940
- Brocos P, Pineiro A, Bravo R, Amigo A, Phys. Chem. Chem. Phys., 5, 550, 2003
- Nain AK, J. Chem. Eng. Data, 53(3), 850, 2008
- Nakata M, Sakurai M, J. Chem. Soc.-Faraday Trans., 83, 2449, 1987
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