Korean Journal of Chemical Engineering, Vol.34, No.1, 199-205, 2017
Parametric studies for CO2 reforming of methane in a membrane reactor as a new CO2 utilization process
A one-dimensional reactor model was employed to perform parametric studies for CO2 reforming of methane in a membrane reactor to investigate its feasibility as a new CO2 utilization process. The effect of key variables such as hydrogen permeance and Ar sweep gas flow rate to facilitate H2 transport from a shell side (retentate) to a tube side (permeate) on the performance in a membrane reactor was studied at various temperatures with numerical simulation validated by experimental results. In addition, increase in CH4 conversion and H2 yield enhancement observed in membrane reactor was successfully confirmed by profiles of H2 partial pressure difference between shell and tube sides. From the numerical simulation studies, the feasibility of using a membrane reactor for CO2 reforming of methane was confirmed by increased CH4 conversion and H2 yield enhancement compared to a packed-bed reactor at the same condition, which in turn leads to significant cost reductions due to a reduced operating temperature. Moreover, a window of H2 permeance and a guideline for Ar sweep gas flow rate for the efficient membrane reactor design was obtained from this study.
[References]
Thomas JM, Thomas WJ, Heterogeneous catalysis, VCH, Weinheim (1997).
Seong M, Shin M, Cho JH, Lee YC, Park YK, Jeon JK, Korean J. Chem. Eng. , 31 (3), 412, 2014
Lee HJ, Shin GS, Kim YC, Korean J. Chem. Eng. , 32 (7), 1267, 2015
Marcano JGS, Tsotsis TT, Catalytic membranes and membrane reactors, WILEY-VCH, Weinheim (2002).
Lee D, Hacarlioglu P, Oyama ST, Top. Catal. , 29 , 45, 2004
Irusta S, Munera J, Carrara C, Lombardo EA, Cornaglia LM, Appl. Catal. A: Gen. , 287 (2), 147, 2005
Tsuru T, Yamaguchi K, Yoshioka T, Asaeda M, AIChE J. , 50 (11), 2794, 2004
Hacarlioglu P, Gu Y, Oyama ST, J. Nat. Gas Chem. , 15 , 73, 2006
Tong JH, Matsumura Y, Appl. Catal. A: Gen. , 286 (2), 226, 2005
Patil CS, Annaland MVS, Kuipers JAM, Chem. Eng. Sci. , 62 (11), 2989, 2007
Kikuchi E, Kawabe S, Matsukata M, J. Jpn. Pet. Inst. , 46 , 93, 2003
Lee DW, Nam SE, Sea B, Ihm SK, Lee KH, Catal. Today , 118 (1-2), 198, 2006
Basile A, Gallucci F, Paturzo L, Catal. Today , 104 (2-4), 244, 2005
Lim H, Gu YF, Oyama ST, J. Membr. Sci. , 351 (1-2), 149, 2010
Tosti S, Basile A, Borgognoni F, Capaldo V, Cordiner S, Di Cave S, Gallucci F, Rizzello C, Santucci A, Traversa E, J. Membr. Sci. , 308 (1-2), 250, 2008
Vasileiadis S, Ziaka Z, Tsimpa M, Int. Trans. J. Eng. Manag. Sci. Technol. , 2 , 129, 2011
Vasileiadis S, Ziaka-Vasileiadou Z, Chem. Eng. Sci. , 59 (22-23), 4853, 2004
Ziaka Z, Membrane reactors for fuel cells and environmental energy systems, Xlibris, USA (2009).
Vasileiadis S, Ziaka Z, J. Nano Res. , 12 , 105, 2010
Tosti S, Basile A, Chiappetta G, Rizzello C, Violante V, Chem. Eng. J. , 93 (1), 23, 2003
Basile A, Chiappetta G, Tosti S, Violante V, Sep. Purif. Technol. , 25 (1-3), 549, 2001
Brunetti A, Barbieri G, Drioli E, Lee KH, Sea B, Lee DW, Chem. Eng. Process. , 46 (2), 119, 2007
Brunetti A, Caravella A, Barbieri G, Drioli E, J. Membr. Sci. , 306 (1-2), 329, 2007
Barbieri G, Brunetti A, Tricoli G, Drioli E, J. Power Sources , 182 (1), 160, 2008
Mendes D, Chibante V, Zheng JM, Tosti S, Borgognoni F, Mendes A, Madeira LM, Int. J. Hydrog. Energy , 35 (22), 12596, 2010
Mendes D, Sa S, Tosti S, Sousa JM, Madeira LM, Mendes A, Chem. Eng. Sci. , 66 (11), 2356, 2011
Zhang YT, Wu ZJ, Hong Z, Gu XH, Xu NP, Chem. Eng. J. , 197 , 314, 2012
Cornaglia CA, Tosti S, Sansovini M, Munera J, Lombardo EA, Appl. Catal. A: Gen. , 462-463 , 278, 2013
Cornaglia CA, Adrover ME, Munera JF, Pedernera MN, Borio DO, Lombardo EA, Int. J. Hydrog. Energy , 38 (25), 10485, 2013
Lim H, Korean J. Chem. Eng. , 32 (8), 1522, 2015
Majidian N, Habibi N, Rezaei M, Korean J. Chem. Eng. , 31 (7), 1162, 2014
Rahemi N, Haghighi M, Babaluo AA, Jafari MF, Allahyari S, Korean J. Chem. Eng. , 31 (9), 1553, 2014
Prabhu AK, Oyama ST, J. Membr. Sci. , 176 (2), 233, 2000
Prabhu AK, Liu A, Lovell LG, Oyama ST, J. Membr. Sci. , 177 (1-2), 83, 2000
Gallucci F, Tosti S, Basile A, J. Membr. Sci. , 317 (1-2), 96, 2008
Bosko ML, Munera JF, Lombardo EA, Cornaglia LM, J. Membr. Sci. , 364 (1-2), 17, 2010
Li JL, Yoon H, Wachsman ED, Int. J. Hydrog. Energy , 37 (24), 19125, 2012
Garcia-Garcia FR, Soria MA, Mateos-Pedrero C, Guerrero-Ruiz A, Rodriguez-Ramos I, Li K, J. Membr. Sci. , 435 , 218, 2013
Munera J, Faroldi B, Frutis E, Lombardo E, Cornaglia L, Carrazan SG, Appl. Catal. A: Gen. , 474 , 114, 2014
Sumrunronnasak S, Tantayanon S, Kiatgamolchai S, Sukonket T, Int. J. Hydrog. Energy , 41 (4), 2621, 2016
Oyama ST, Lim H, Chem. Eng. J. , 151 (1-3), 351, 2009
Lim H, Clean Technol. , 20 (4), 425, 2014
Alamdari A, J. Nat. Gas Sci. Eng. , 27 , 934, 2015
Richardson JT, Paripatyadar SA, Appl. Catal. , 61 , 293, 1990
Fogler HS, Essentials of Chemical Reaction Engineering, Pearson Education, Inc., New Jersey (2010).
[Cited By]
Im YH, Lee JH, Kang MS, Korean Journal of Chemical Engineering , 34 (6), 1669, 2017
Kim JY, Do JY, Park NK, Lee SJ, Hong JP, Kang MS, Korean Journal of Chemical Engineering , 35 (5), 1089, 2018
Kim SH, Song JS, Lim HK, Korean Journal of Chemical Engineering , 35 (7), 1509, 2018
Li F, Dong J, Wang M, Lin X, Cai W, Liu X, Korean Journal of Chemical Engineering , 39 (7), 1744, 2022
이전 논문 다음 논문
Result Search