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Issue
Korean Journal of Chemical Engineering,
Vol.33, No.12, 3493-3503, 2016
Experimental solubility and absorption mechanism of dilute SO2 in aqueous diethylene glycol dimethyl ether solution
Xu Q, Xiao J, Zhang J, Wei X
SO2 absorption capabilities of DEGDME+H2O system with different compositions were systemically investigated. The DEGDME+H2O system exhibited superior SO2 absorption capability and optimal desorption property with a desorption rate of higher than 94% under the desorption conditions. In addition, it has been demonstrated that the DEGDME+H2O system possessed remarkable SO2 absorbing and releasing capability after multiple recycles. Moreover, GLE data were measured for dilute SO2 in the system of DEGDME+H2O, in which SO2 partial pressures were determined in the range of 0 to 140 Pa. By fitting of GLE data, HLC, ΔH, ΔS and ΔG of SO2 absorption process were obtained. UV, FTIR, 1H-NMR, and 13C-NMR spectra of absorbing systems in the SO2 absorption processes were studied to elucidate the absorption mechanism. On the basis of the spectral results, the intermolecular hydrogen bonding and S...O interaction between SO2 with the absorption system were discussed.
Keywords: Gas-liquid Equilibrium; Diethylene Glycol Dimethyl Ether; SO2; Thermodynamic Parameter; Absorption Mechanism
[References]
  1. Zhao Y, Han YH, Chen C, Ind. Eng. Chem. Res., 51(1), 480, 2012
  2. Zhi J, Yu X, Bao J, Jiang X, Yang H, Korean J. Mater. Res., 33(6), 1823, 2016
  3. Zhou YG, Zhang MC, Wang DF, Wang L, Ind. Eng. Chem. Res., 44(23), 8830, 2005
  4. Siddiqi MA, Krissmann J, Petersgerth P, Luckas M, Lucas K, J. Chem. Thermodyn., 28(7), 685, 1996
  5. Pereda S, Thomsen K, Rasmussen P, Chem. Eng. Sci., 55(14), 2663, 2000
  6. Krissmann J, Siddiqi MA, Lucas K, Fluid Phase Equilib., 141(1-2), 221, 1997
  7. Zimmermann K, Pasel C, Luckas M, Herbell JD, Fluid Phase Equilib., 279(2), 105, 2009
  8. Valtz A, Coquelet C, Richon D, Int. J. Thermophys., 25, 1695, 2004
  9. Zhang JB, Zhang PY, Chen GH, Han F, Wei XH, J. Chem. Eng. Data, 53(7), 1479, 2008
  10. Zhang JB, Liu LH, Huo TR, Liu ZY, Zhang T, Wei XH, J. Chem. Thermodyn., 43(10), 1463, 2011
  11. Zhang N, Zhang JB, Zhang YF, Bai J, Huo TR, Wei XH, Fluid Phase Equilib., 313, 7, 2012
  12. Guo B, Zhao T, Sha F, Zhang F, Li Q, Zhang J, Korean J. Chem. Eng., 33(6), 1883, 2016
  13. Sciamanna SF, Scott L, Ind. Eng. Chem. Res., 27, 492, 1988
  14. Revelli AL, Mutelet F, Jaubert JN, J. Phys. Chem. B, 114(40), 12908, 2010
  15. Sun SY, Yan YX, Sun ZC, Xu QX, Wei XH, RSC Adv., 5, 8706, 2015
  16. Niu YX, Gao F, Sun SY, Xiao JB, Wei XH, Fluid Phase Equilib., 344, 65, 2013
  17. Chang Y, Zhang J, Li Q, Li L, Guo B, Zhao T, Korean J. Chem. Eng., 31(2), 2245, 2014
  18. Douabul A, Riley J, J. Chem. Eng. Data, 24, 274, 1979
  19. Rumpf B, Maurer G, Fluid Phase Equilib., 81, 241, 1992
  20. Li H, Liu DZ, Wang FA, J. Chem. Eng. Data, 47(4), 772, 2002
  21. Li H, Jiao X, Chen W, Phys. Chem. Liq., 52, 349, 2014
  22. Rabe AE, Harris JF, J. Chem. Eng. Data, 8, 333, 1963
  23. Vosolsobe J, Simecek S, Michalek J, Kadler B, Chem. Prum., 15, 401, 1965
  24. Xu QX, Sun SY, Lan GJ, Xiao JB, Zhang JB, Wei XH, J. Chem. Eng. Data, 60(1), 2, 2015
  25. Dethlefsen C, Hvidt A, J. Chem. Thermodyn., 17, 193, 1985
  26. Aminabhavi TM, Gopalakrishna B, J. Chem. Eng. Data, 40(2), 462, 1995
  27. Rodriguez-Sevilla J, Alvarez M, Liminana G, Diaz MC, J. Chem. Eng. Data, 47(6), 1339, 2002
  28. Anthony JL, Maginn EJ, Brennecke JF, J. Phys. Chem. B, 106(29), 7315, 2002
  29. Henni A, Tontiwachwuthikul P, Chakma A, Can. J. Chem. Eng., 83(2), 358, 2005
  30. Bamford HA, Poster DL, Baker JE, Environ. Toxicol. Chem., 18, 1905, 1999
  31. Fu XC, Shen WX, Physical Chemistry, 5th Ed. Higher Press, Beijing (2005).
  32. Jin MJ, Hou YC, Wu WZ, Ren SH, Tian SD, Xiao L, Lei ZG, J. Phys. Chem. B, 115(20), 6585, 2011
  33. Zhang JB, Han F, Wei XH, Shui LK, Gong H, Zhang PY, Ind. Eng. Chem. Res., 49(5), 2025, 2010
  34. Douabul A, Riley J, J. Chem. Eng. Data, 24, 274, 1979
  35. Al-Enezi G, Ettouney H, El-Dessouky H, Fawzi N, Ind. Eng. Chem. Res., 40(5), 1434, 2001
  36. Shaw AC, Romero MA, Elder RH, Ewan BCR, Allen RWK, Int. J. Hydrog. Energy, 36(8), 4749, 2011
  37. Augusta S, Anal. Chem., 45, 1744, 1973
  38. Lasgabaster A, Abad MJ, Barral L, Eur. Polym. J., 42, 3121, 2006
  39. Vandam MH, Lamine AS, Roizard D, Lochon P, Roizard C, Ind. Eng. Chem. Res., 36(11), 4628, 1997
  40. Yarra M, Rachapudi BNP, Mallampalli LKS, Eur. J. Inorg. Chem., 5, 260, 2014
  41. Frech R, Huang WW, Macromolecules, 28, 1246, 1994
  42. William DH, Fleming I, Spectroscopy Methods in Org. chemistry, 6th Ed. New York, McGraw-Hill (2005).
  43. Zhao XY, Sun XY, Spectral identification for organic molecular structure, 2th Ed. Beijing (2010).
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