About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.33, No.7, 2084-2089, 2016
Effects of oxidized biodiesel on formation of particulate matter and NOx from diesel engine
Kang H, Song H, Ha J, Na BK
A test was conducted to investigate the effect of pure biodiesel without additives on formation of particulate matter (PM) and nitrogen oxide (NOx) in the exhaust gas of a diesel engine. Pure biodiesel from waste cooking oil without adding any additive was used. The biodiesel was oxidized at 110 ℃ for 10 days and blended with commercial automobile diesel oil distributed in the market as a testing fuel. Blended fuels were produced by adding 10% of oxidized biodiesel and un-oxidized biodiesel to automobile diesel oil, respectively. Material properties such as density, kinematic viscosity, oxidation stability, and cetane number were tested. Emission tests were conducted using a large diesel engine of direct injection type, inline six-cylinder, 4 stroke, turbocharger and intercooler. The oxidized and unoxidized biodiesel blends did not show any difference in density and kinematic viscosity. The oxidation stability of the oxidized biodiesel blends was lower than that of the unoxidized biodiesel blends. In the emission test, the two blends showed almost no difference in the total number of concentration of the micro-particles, and also showed almost no difference in particle size distribution such as nucleation mode and accumulation mode. On the other hand, the oxidized biodiesel blends showed less PM and NOx emission than the unoxidized biodiesel blends.
Keywords: Particulate Matter; Total Particle Number; NOx; Hydroperoxide; Fatty Acid Methyl Ester; Lower Heating Value
[References]
  1. Fino D, Russo N, Badini C, Saracco G, Specchia V, Korean J. Chem. Eng., 20(3), 451, 2003
  2. Fino D, Fino P, Saracco G, Specchia V, Korean J. Chem. Eng., 20(3), 445, 2003
  3. Jung H, Kittelson DB, Zachariah MR, Environ. Sci. Technol., 40(16), 4949, 2006
  4. Tsolakis A, Energy Fuels, 20(4), 1418, 2006
  5. Rakopoulos CD, Rakopoulos DC, Hountalas DT, Giakoumis EG, Andritsakis EC, Fuel, 87(2), 147, 2008
  6. Mayer A, Czerwinski J, Wyser M, Mattrel P, Heitzer A, SAE, Paper NO. 2005-01-1728 (2005).
  7. Tinsdale M, Price P, Chen R, SAE, Paper NO. 2010-01-0796 (2010).
  8. Pinto AC, Guarieiro LLN, Rezende MJC, ribeiro NM, Torres EA, Lopes WA, de P. Pereira PA, de Andrade JB, J. Braz. Chem. Soc., 16, 1313, 2005
  9. Schumacher L, Borgelt SC, SAE Tech. Pap. Ser. 1996, No962233.
  10. Chang DYZ, VanGerpen JH, Lee I, Johnson LA, Hammond EG, Marley SJ, J. Amer. Oil Chem. Soc., 73, 1549, 1996
  11. Peterson CL, Reece DL, Thompson JC, Beck SM, Chase C, Biomass Bioenerg., 10(5-6), 331, 1996
  12. Peterson C, Reece D, Transactions of the ASAE, 39, 805, 1996
  13. Hong YK, Hong WH, Korean Chem. Eng. Res., 45(5), 424, 2007
  14. Formo MW, Jungermann E, Noris F, Sonntag NOV, Bailey’s Industrial Oil And Fat Products, Volume I, (Fourth Edition), Swern D, Editor, John Wiley and Sons, 698-711 (1979).
  15. Clothier PQE, Aguda BD, Moise A, Pritchard HO, Chem. Soc. Rev., 22, 101, 1993
  16. Neff WE, Mounts TL, Rinsch WM, Konishi H, J. Am. Oil Chem. Soc., 70(2), 163, 1993
  17. Neff WE, El-Agaimy MA, Mounts TL, J. Am. Oil Chem. Soc., 71(10), 1111, 1994
  18. Wexler H, Chem. Rev., 64(6), 591, 1964
  19. Chang SS, Kummerow FA, J. Am. Oil Chem. Soc., 31(8), 324, 1954
  20. Van Gerpen J, Cetane Number Testing of Biodiesel, www.biodiesel.org.
  21. Matheaus AC, Neely GD, Ryan TW, Sobotowski RA, Wall JC, Hobbs CH, Passavant GW, Bond TJ, SAE, Paper NO. 2000-01-1858 (2000).
  22. Mason RL, Matheaus AC, Ryan TW, Sobotowski RA, Wall JC, Hobbs CH, Passavant GW, Bond TJ, SAE, Paper NO. 2000-01-1859 (2000).
  23. Zhu L, Zhang W, Liu W, Huang Z, Sci. Total Environ., 408(5), 1050, 2010
  24. McEnally CS, Pfefferle LD, Environ. Sci. Technol., 45(6), 2498, 2011
  25. Haynes BS, Wagner HG, Prog. Energy Combust. Sci., 7(4), 229, 1981
  26. Maricq MM, Combust. Flame, 158(1), 105, 2011
  27. Tan P, Hu Z, Lou D, Li B, SAE, Paper No. 2009-01-2726 (2009).
  28. Schmidt K, Van Gerpen J, SAE, Paper No. 961086 (1996).
  29. Lin CY, Lin HA, Fuel Process. Technol., 89(11), 1237, 2008
  30. Lin CY, Lin SA, Fuel, 86(1-2), 210, 2007
  31. Bora DK, Baruah DC, Renew. Sust. Energ. Rev., 16(3), 1616, 2012
[Cited By]
  1. Mohadesi M, Aghel B, Khademi MH, Sahraei S, Korean Journal of Chemical Engineering, 34(4), 1013, 2017
  2. Devarajan Y, Nagappan BK, Munuswamy DB, Korean Journal of Chemical Engineering, 34(4), 1021, 2017
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.