| Issue |
Korean Journal of Chemical Engineering,
Vol.33, No.7, 2042-2049, 2016
Vol.33, No.7, 2042-2049, 2016
Prediction of biodiesel properties and its characterization using fatty acid profiles
Biodiesel, the mono-alkyl esters of vegetable oils or animal fats, is an eco-friendly alternative to petrodiesel. The molecular structures of biodiesels, fatty acid methyl esters were applied to predict the characteristics of biodiesel fuels. Based on the structural similarity of biodiesel and petroleum fractions, molecular weight of biodiesel was correlated with other characteristics including boiling point, viscosity and specific-gravity in the form of three equations. For 24 different kinds of biodiesel, the minimum average relative deviation (ARD) of these correlations was calculated to be 0.68%. Moreover, two correlations were developed to predict viscosity and flash point of biodiesel as a function of weighted-average number of carbon atoms (NC) and weighted-average number of double bonds (NDB) with ARD 3.72% and 4.24% respectively. Also, a high degree of correlation was shown by the logarithmic function with ARD 0.30% between specific gravity and viscosity of biodiesel. Proposed predictive models were verified by experimental data.
[References]
- Abbaszaadeh A, Ghobadian B, Omidkhah MR, Najafi G, Energy Conv. Manag., 63, 138, 2012
- An H, Yang WM, Maghbouli A, Chou SK, Chua KJ, Appl. Energy, 102, 647, 2013
- Perdomo FA, Milian BM, Aragon JL, Energy, 72, 274, 2014
- Hoekman SK, Broch A, Robbins C, Ceniceros E, Natarajan M, Renew. Sust. Energ. Rev., 16, 143, 2012
- Allen CAW, Watts KC, Ackman RG, Pegg MJ, Fuel, 78(11), 1319, 1999
- Ceriani R, Goncalves CB, Rabelo J, Caruso M, Cunha ACC, Cavaleri FW, Batista EAC, Meirelles AJA, J. Chem. Eng. Data, 52(3), 965, 2007
- Ceriani R, Goncalves CB, Coutinho JAP, Energy Fuels, 25(8), 3712, 2011
- Chang AF, Liu Y, Ind. Eng. Chem. Res., 49, 1197, 2009
- Su YC, Liu YA, Ind. Eng. Chem. Res., 50(11), 6809, 2011
- Ramirez-Verduzco LF, Garcia-Flores BE, Rodriguez-Rodriguez JE, Jaramillo-Jacob AD, Fuel, 90(5), 1751, 2011
- Meng XZ, Jia M, Wang TY, Fuel, 121, 133, 2014
- Rocabruno-Valdes CI, Ramirez-Verduzco LF, Hernandez JA, Fuel, 147, 9, 2015
- Zhokhova N, Baskin II, Palyulin V, Zefirov A, Zefirov N, Russ. Chem. Bull., 52, 1885, 2003
- Encinar JM, Sanchez N, Martinez G, Garcia L, Bioresour. Technol., 102(23), 10907, 2011
- Catoire L, Paulmier S, Naudet V, Process Saf. Prog., 25(1), 33, 2006
- Saxena P, Jawale S, Joshipura MH, Procedia Engineering, 51, 395, 2013
- Alptekin E, Canakci M, Fuel, 90(8), 2630, 2011
- Encinar JM, Sanchez N, Martinez G, Garcia L, Bioresour. Technol., 102(23), 10907, 2011
- Abdoli M, Mohamadi F, Ghobadian B, Fayyazi E, Int. J. Environ. Res., 8, 139, 2014
- Riazi M, Characterization and properties of petroleum fractions, ASTM International (2005).
- Santander CMG, Rueda SMG, da Silva ND, de Camargo CL, Kieckbusch TG, Maciel MRW, Fuel, 92(1), 158, 2012
- Poling BE, Prausnitz JM, John Paul OC, Reid RC, The properties of gases and liquids, McGraw-Hill, New York (2001).
- Yuan W, Hansen AC, Zhang Q, Fuel, 84(7-8), 943, 2005
- Smith JM, Introduction to chemical engineering thermodynamics, Rensselaer Polytechnic Institute (1975).
- Giakoumis EG, Renew. Energy, 50, 858, 2013
- Abou Kheira AA, Atta NMM, Biomass Bioenerg., 33(10), 1343, 2009
[Cited By]
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.