Issue
Korean Journal of Chemical Engineering,
Vol.33, No.6, 1846-1854, 2016
Catalytic activity of copper-ceria catalysts supported on different zeolites for CO oxidation
Copper-ceria catalysts for CO oxidation supported on 4A, 5A, NaX and NaY zeolites were prepared by incipient wetness impregnation and excess-solution impregnation. Catalysts were characterized by SEM, EDX, XRD, N2 adsorption-desorption, H2-TPR and XPS. Results revealed that the catalysts were greatly affected by zeolites and preparation method. EDX results indicated the metal loading of 4A-ES (5.1 wt% Cu, 15.7 wt% Ce), 5A-ES (5.9 wt% Cu, 19.2% Ce), NaX-ES (11.7wt% Cu, 4.2 wt% Ce) and NaY-ES (11.0 wt% Cu, 7.9 wt% Ce) greatly varied. TPR results suggested that the peak at around 195 oC was presented in NaX-ES and 4A-IW, standing for dispersed copper species that is very active for CO oxidation. The catalytic activity of 4A-ES and NaX-ES was the best among catalysts made by excess-solution impregnation, demonstrated by the lowest T50 at 127 and 129 ℃, respectively. The catalytic activity of catalysts made by incipient wetness impregnation was worse than that of catalysts made by excess-solution impregnation, examined by the T50 of 4A-IW and NaX-IW at 128 and 192 ℃, respectively.
[References]
  1. An K, Alayoglu S, Musselwhite N, Plamthottam S, Melaet G, Lindeman AE, Somorjai GA, J. Am. Chem. Soc., 135(44), 16689, 2013
  2. Lin JN, Wan BZ, Appl. Catal. B: Environ., 41(1-2), 83, 2003
  3. Chen MS, Cai Y, Yan Z, Gath KK, Axnanda S, Goodman DW, Surf. Sci., 601, 5326, 2007
  4. Qian K, Qian Z, Hua Q, Jiang Z, Huang W, Surf. Sci., 273, 357, 2013
  5. Liu X, Lu J, Qian K, Huang W, Luo M, J. Rare Earths., 27, 418, 2009
  6. Liu Y, Fu Q, Stephanopoulos MF, Catal. Today, 93-95, 241, 2004
  7. Perez NC, Miro EE, Zamaro JM, Catal. Today, 213, 183, 2013
  8. Gurbani A, Ayastuy JL, Gonzalez-Marcos MP, Herrero JE, Guil JM, Gutierrez-Ortiz MA, Int. J. Hydrog. Energy, 34(1), 547, 2009
  9. Zheng X, Wang S, Wang S, Zhang S, Huang W, Wu S, Catal. Commun., 5, 729, 2004
  10. Manasilp A, Gulari E, Appl. Catal. B: Environ., 37(1), 17, 2002
  11. Zhu HG, Liang CD, Yan WF, Overbury SH, Dai S, J. Phys. Chem. B, 110(22), 10842, 2006
  12. Kiwi-Minsker L, Yuranov I, Siebenhaar B, Renken A, Catal. Today, 54(1), 39, 1999
  13. Han WL, Zhang P, Tang ZC, Lu GX, Process Saf. Environ. Protect., 92(6), 822, 2014
  14. Perez NC, Miro EE, Zamaro JM, Appl. Catal. B: Environ., 129, 416, 2013
  15. Igarashi H, Uchida H, Suzuki M, Sasaki Y, Watanabe M, Appl. Catal. A: Gen., 159(1-2), 159, 1997
  16. Kolobova E, Pestryakov A, Shemeryankina A, Kotolevich Y, Martynyuk O, Vazquez HJT, Bogdanchikova N, Fuel, 138, 65, 2014
  17. Verboekend D, Keller TC, Mitchell S, Perez-Ramirez J, Adv. Funct. Mater., 23(15), 1923, 2013
  18. Tidahy HL, Siffert S, Lamonier JF, Cousin R, Zhilinskaya EA, Aboukais A, Su BL, Canet X, De Weireld G, Frere A, Giraudon JM, Leclercq G, Appl. Catal. B: Environ., 70(1-4), 377, 2007
  19. Jeong BH, Sotowa KI, Kusakabe K, J. Membr. Sci., 224(1-2), 151, 2003
  20. Rosso L, Galletti C, Saracco G, Garrone E, Specchia V, Appl. Catal. B: Environ., 48(3), 195, 2004
  21. Bowker M, Nuhu A, Soares J, Catal. Today, 122(3-4), 245, 2007
  22. Junges U, Jacobs W, Voigt-Martin I, Krutzsch B, Schuth F, J. Chem. Soc.-Chem. Commun., 2283, 1995
  23. Soares JMC, Morrall P, Crossley A, Harris P, Bowker M, J. Catal., 219(1), 17, 2003
  24. Bao WW, Zou HF, Gan SC, Xu XC, Ji GJ, Zheng KY, Chemical Research in Chinese Universities, 29, 126, 2013
  25. Erdem E, Karapinar N, Donat R, J. Colloid Interface Sci., 280(2), 309, 2004
  26. Hegazy EZ, Abdelmaksod IH, Kosa SA, CLEAN - Soil, Air, Water., 42, 775, 2014
  27. Gamarra D, Camara AL, Monte M, Rasmussen SB, Chinchilla LE, Hungria AB, Munuera G, Gyorffy N, Schay Z, Corberan VC, Conesa JC, Martinez-Arias A, Appl. Catal. B: Environ., 130-131, 224, 2013
  28. Valtchev VP, Tosheva L, Bozhilov KN, Langmuir, 21(23), 10724, 2005
  29. Naser-Azizi S, Dehnavi AR, Joorabdoozha A, Mater. Res. Bull., 48(5), 1753, 2013
  30. Serp P, Castillejos E, ChemCatChem., 2, 41, 2010
  31. Pinna F, Catal. Today, 41(1-3), 129, 1998
  32. Zhu P, Liu M, Zhou R, Indian J. Chem. Sect A-Inorg. Bio-Inorg. Phys. Theor. Anal. Chem., 51, 1529, 2012
  33. Gu CL, Lu SH, Miao J, Liu YA, Wang YQ, Int. J. Hydrog. Energy, 35(12), 6113, 2010
  34. Kim DH, Cha JE, Catal. Lett., 86(1-3), 107, 2003
  35. Zeng SH, Zhang WL, Sliwa M, Su HQ, Int. J. Hydrog. Energy, 38(9), 3597, 2013
  36. Luo MF, Ma JM, Lu JQ, Song YP, Wang YJ, J. Catal., 246(1), 52, 2007
  37. Gao Y, Xie K, Wang W, Mi S, Liu N, Pan G, Huang W, Catal. Sci. Technol., 5, 1568, 2015
  38. Bin F, Wei XL, Li B, Hui KS, Appl. Catal. B: Environ., 162, 282, 2015
  39. Katta L, Sudarsanam P, Thrimurthulu G, Reddy BM, Appl. Catal. B: Environ., 101(1-2), 101, 2010