| Issue |
Korean Journal of Chemical Engineering,
Vol.33, No.5, 1606-1611, 2016
Vol.33, No.5, 1606-1611, 2016
Effect of temperature on the electrochemical oxidation of ash free coal and carbon in a direct carbon fuel cell
The present study proposes the application of ash-free coal (AFC) as a primary fuel in a direct carbon fuel cell (DCFC) based on a molten carbonate fuel cell (MCFC). AFC was produced by solvent extraction using microwave irradiation. The influence of AFC-to-carbonate ratio (3 : 3, 3 : 1, 3 : 0 and 1 : 3 g/g) on the DCFC performance at different temperatures (650, 750 and 850 ℃) was systematically investigated with a coin-type cell. The performance of AFC was also compared with carbon and conventional hydrogen fuels. AFC without carbonate (AFC-to-carbonate ratio=3 : 0 g/g) gave a comparable performance to other compositions, indicating that the gasification of AFC readily occurred without a carbonate catalyst at 850 oC. The ease of gasification of AFC led to a much higher performance than for carbon fuel, even at 650 oC, where carbon cannot be gasified with a carbonate catalyst.
[References]
- Dicks AL, J. Power Sources, 156(2), 128, 2006
- Cao DX, Sun Y, Wang GL, J. Power Sources, 167(2), 250, 2007
- Dicks AL, J. Power Sources, 156(2), 128, 2006
- Cooper JF, Proc. 2nd International Conference on Fuel Cell Science, Engineering and Technology, Rochester, NY, 375 (2004).
- Cherepy NJ, Krueger R, Fiet KJ, Jankowski AF, Cooper JF, J. Electrochem. Soc., 152(1), A80, 2005
- Selman JR in Fuel cell systems (Eds. Blomen LJM, Mugerwa MN), Plenum Press, New York, 384 (1993).
- Joon K, J. Power Sources, 61, 129, 1996
- Zecevic S, Patton EM, Parhami P, Carbon, 42, 1983, 2004
- Nabae Y, Pointon KD, Irvine JTS, J. Electrochem. Soc., 156(6), B716, 2009
- Liu QH, Tian Y, Xia C, Thompson LT, Liang B, Li YD, J. Power Sources, 185(2), 1022, 2008
- Jain SL, Nabae Y, Lakeman BJ, Pointon KD, Irvine JTS, Solid State Ion., 179(27-32), 1417, 2008
- Nabae Y, Pointon KD, Irvine JTS, Energy Environ. Sci., 1, 148, 2008
- Jain SL, Lakeman BJ, Pointon KD, Irvine JTS, Ionics, 13, 413, 2007
- Vutetakis DG, Skidmore DR, Byker HJ, J. Electrochem. Soc., 134, 3027, 1987
- Chen MM, Wang CY, Niu XM, Zhao S, Tang J, Zhu B, Int. J. Hydrog. Energy, 35(7), 2732, 2010
- Yoshida T, Takanohashi T, Sakanishi K, Saito I, Fujita M, Mashimo K, Energy Fuels, 16(4), 1006, 2002
- Li CQ, Takanohashi T, Saito I, Energy Fuels, 18(1), 97, 2004
- Muthuvel M, Jin X, Botte GG, in Encycl. Electrochem. Power Sources, Vol. 3 (Ed. Jurgen Garche), Elesevier, 158 (2009).
- Kim SD, Woo KJ, Jeong SK, Rhim YJ, Lee SH, Korean J. Chem. Eng., 25(4), 758, 2008
- Okuyama N, Komatsu N, Shigehisa T, Kaneko T, Tsutuya S, Fuel Process. Technol., 85(8-10), 947, 2004
- Kim JP, Choi HK, Chang YJ, Jeon CH, Int. J. Hydrog. Energy, 37(15), 11401, 2012
- Lee CG, Hur H, Song MB, J. Electrochem. Soc., 158(4), B410, 2011
- Lee CG, Fuel Cells, 12, 550, 2012
- Vamvuka D, Woodburn ET, Senior PR, Fuel, 74, 1452, 1995
- Vamvuka D, Woodburn ET, Senior PR, Fuel, 74, 1461, 1995
- Nagase K, Shimodaira T, Itoh M, Zheng Y, Phys. Chem. Chem. Phys., 1, 5659, 1999
- Lee CG, Kim WK, Int. J. Hydrog. Energy, 40(15), 5475, 2015
- Lee CG, Kim WK, Vu DL, Korean J. Chem. Eng., 32(9), 1784, 2015
- Mckee DW, Chatterji D, Carbon, 16, 53, 1978
- Lee CG, Kang BS, Seo HK, Lim HC, J. Electroanal. Chem., 540, 169, 2003
- Ruflin J, Perwich AD, Brett C, Berner JK, Lux SM, J. Power Sources, 213, 275, 2012
- Guo L, Calo JM, Dicocco E, Bain EJ, Energy Fuels, 27, 1712, 2013
- Liu QH, Tian Y, Xia C, Thompson LT, Liang B, Li YD, J. Power Sources, 185(2), 1022, 2008
- Lee CG, J. Electroanal. Chem., 701, 36, 2013
- Kojima T, Miyazaki Y, Nomura K, Tanimoto K, J. Electrochem. Soc., 154(12), F222, 2007
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