Issue
Korean Journal of Chemical Engineering,
Vol.33, No.5, 1571-1589, 2016
Increasing ethylene production as a high value hydrocarbon in Fischer-Tropsch (FT) reactor: A concept reactor for combining FT with oxidative coupling of methane
The paper proposes a concept configuration of reactors for coupling OCM and FTS, and presents systematic simulation results. FTS section is a combination of fixed bed and membrane fluidized bed reactor, and feed of the FT reactor is supplied by OCM. The reactor configuration is compared with the consecutive reactors of OCM and one fixed bed FT reactor. Effects of CH4/O2 ratio, percent of N2 in the feed, contact time, and input temperature on the yield of ethylene and valuable hydrocarbons are studied. The results show that compared with one FTS reactor configuration, the dual FTS reactor configuration is more effective and thus gives much higher product yields. Furthermore, a main decrease is observed in the formation of CO2 and CH4.
[References]
  1. Keller GE, Bhasin MM, J. Catal., 73, 9, 1982
  2. Su YS, Ying JY, Green WH, J. Catal., 218(2), 321, 2003
  3. Stunkel S, Martini W, Arellano-Garcia H, Wozny G, Chem. Ing. Tech., 83(4), 488, 2011
  4. Arndt S, Laugel G, Levchenko S, Horn R, Baerns M, Scheffler M, Schlogl R, Schomacker R, Catal. Rev.-Sci. Eng., 53(4), 424, 2011
  5. Sinev MY, Fattakhova ZT, Lomonosov VI, Gordienko YA, J. Nat. Gas. Chem., 18, 273, 2009
  6. Ehsani MR, Bateni H, Parchikolaei GR, Korean J. Chem. Eng., 29(7), 855, 2012
  7. Lee MR, Park MJ, Jeon W, Choi JW, Suh YW, Suh DJ, Korean J. Chem. Eng., 28(11), 2142, 2011
  8. Godini HR, Xiao S, Kim M, Holst N, Jaso S, Gorke O, Steinbach J, Wozny G, J. Ind. Eng. Chem., 20(4), 1993, 2014
  9. Marvast MA, Sohrabi M, Zarrinpashne S, Baghmisheh G, Chem. Eng. Technol., 28(1), 78, 2005
  10. Ghareghashi A, Ghader S, Hashemipour H, J. Ind. Eng. Chem., 19(6), 1811, 2013
  11. Park N, Kim JR, Yoo Y, Lee J, Park MJ, Fuel, 122, 229, 2014
  12. Moazami N, Wyszynski ML, Mahmoudi H, Tsolakis A, Zou Z, Panahifar P, Rahbar K, Fuel, 154, 140, 2015
  13. Stansch Z, Mleczko L, Baerns M, Ind. Eng. Chem. Res., 36(7), 2568, 1997
  14. Montazer-Rahmati, Mehdi M, Bargah-Soleimani M, Can. J. Chem. Eng., 79(5), 800, 2001
  15. Fischer-Tropsch pilot plant of Research Institute of Petroleum Industry and National Iranian Oil Company, Iran (2004).
  16. Cussler EL, “Diffusion, Mass Transfer in Fluid Systems,” Cambridge:Cambridge University Press, 525, II (1984).
  17. Wilke CR, Chem. Eng. Prog., 45, 218, 1949
  18. Panahi M, Master’s Thesis, Sharif University of Technology (2005).
  19. Rahimpour MR, Lotfinejad M, Chem. Eng. Technol., 31(1), 38, 2008
  20. Rahimpour MR, Mostafazadeh AK, Barmaki MM, Fuel Process. Technol., 89(12), 1396, 2008
  21. Guazzone F, Engwall EE, Ma YH, Catal. Today, 118(1-2), 24, 2006
  22. Deshmukh SARK, Laverman JA, Cents AHG, Annaland MVS, Kuipers JAM, Ind. Eng. Chem. Res., 44(16), 5955, 2005
  23. Chang J, Bai L, Teng BT, Zhang RL, Yang J, Xu YY, Xiang HW, Li YW, Chem. Eng. Sci., 62(18-20), 4983, 2007
  24. Kunii D, Levenspiel O, Fluidization Engineering, Butterworth-Heinemann, Boston (1991).
  25. Ghajar J, Master’s Thesis, Shiraz University, Department of Chemical and Petroleum Engineering (2000).