Korean Journal of Chemical Engineering, Vol.33, No.4, 1232-1238, 2016
Efficient hydrolysis of cellulose over a magnetic lignin-derived solid acid catalyst in 1-butyl-3-methylimidazolium chloride
A green and efficient strategy for the hydrolysis of cellulose was developed by using a magnetic lignin-derived solid acid catalyst (MLC-SO3H) in the presence of ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM]Cl). The results indicated that reaction temperature, reaction time, catalyst loading and water content have a big influence on the yield of total reducing sugars (TRS). By optimizing these reaction parameters, 69.3% TRS yield was observed at
140 ℃ for 150 min with the addition of 40 wt% MLC-SO3H and 1 wt% water. More importantly, MLC-SO3H could be easily separated from the reaction mixture with an external magnet and could be repeatedly used five times without an obvious loss of catalytic activity, demonstrating that it possessed excellent recyclability. Furthermore, a plausible mechanism involving three consecutive processes of dissolution, adsorption and catalysis for the hydrolysis of cellulose in
[BMIM]Cl over a catalyst of MLC-SO3H was also proposed.
[References]
Luterbacher JS, Rand JM, Alonso DM, Han J, Youngquist JT, Maravelias CT, Pfleger BF, Dumesic JA, Science , 343 (6168), 277, 2014
Ni JP, Wang HL, Chen YY, She Z, Na HN, Zhu J, Bioresour. Technol. , 137 , 106, 2013
Vilcocq L, Castilho PC, Carvalheiro F, Duarte LC, ChemSusChem , 7 , 1010, 2014
Pang JF, Wang AQ, Zheng MY, Zhang T, Chem. Commun. , 46 , 6935, 2010
Gonzalez-Rivera J, Galindo-Esquivel IR, Onor M, Bramanti E, Longo I, Ferrari C, Green Chem. , 16 , 1417, 2014
Fan JJ, De Bruyn M, Budarin VL, Gronnow MJ, Shuttleworth PS, Breeden S, Macquarrie DJ, Clark JH, J. Am. Chem. Soc. , 135 (32), 11728, 2013
Cantero DA, Bermejo MD, Cocero MJ, ChemSusChem , 8 , 1026, 2015
Rinaldi R, Schuth F, ChemSusChem , 2 , 1096, 2009
Cantero DA, Bermejo MD, Cocero M, Bioresour. Technol. , 135 , 697, 2013
Zhang QH, Benoit M, De Oliveira Vigier K, Barrault J, Jegou G, Philippe M, Jerome F, Green Chem. , 15 , 963, 2013
Hu L, Lin L, Wu Z, Zhou SY, Liu SJ, Appl. Catal. B: Environ. , 174-175 , 225, 2015
Gupta KM, Jiang JW, Chem. Eng. Sci. , 121 , 180, 2015
Wang H, Gurau G, Rogers RD, Chem. Soc. Rev. , 41 , 1519, 2012
Klemm D, Heublein B, Fink HP, Bohn A, Angew. Chem.-Int. Edit. , 44 , 3358, 2005
Swatloski RP, Spear SK, Holbrey JD, Rogers RD, J. Am. Chem. Soc. , 124 (18), 4974, 2002
Sun N, Rodriguez H, Rahman M, Rogers RD, Chem. Commun. , 47 , 1405, 2011
Zakzeski J, Grisel RJ, Smit AT, Weckhuysen BM, ChemSusChem , 5 , 430, 2012
Yang ZZ, Huang RL, Qi W, Tong LP, Su RX, He ZM, Chem. Eng. J. , 280 , 90, 2015
Wu CY, Chen W, Zhong LX, Peng XW, Sun RC, Fang JJ, Zheng SB, J. Agric. Food Chem. , 62 , 7430, 2014
Freudenmann D, Wolf S, Wolff M, Feldmann C, Angew. Chem.-Int. Edit. , 50 , 11050, 2011
Zhang QH, Zhang SG, Deng YQ, Green Chem. , 13 , 2619, 2011
Startk A, Energy Environ. Sci. , 4 , 19, 2011
Wang JY, Zhou MD, Yuan YG, Zhang Q, Fang XC, Zang SL, Bioresour. Technol. , 197 , 42, 2015
Brandt A, Grasvik J, Hallett JP, Welton T, Green Chem. , 15 , 550, 2013
Remsing RC, Swatloski RP, Rogers RD, Moyna G, Chem. Commun. , 12 , 1271, 2006
Maki-Arvela P, Anugwom I, Virtanen P, Sjoholm R, Mikkola JP, Ind. Crop. Prod. , 32 , 175, 2010
Zhou LP, Yang XM, Xu JL, Shi MT, Wang F, Chen C, Xu J, Green Chem. , 17 , 1519, 2015
Parveen F, Patra T, Upadhyayula S, Carbohydr. Polym. , 135 , 280, 2016
Zhao XC, Wang J, Chen CM, Huang YQ, Wang AQ, Zhang T, Chem. Commun. , 50 , 3439, 2014
Shuai L, Pan XJ, Energy Environ. Sci. , 5 , 6889, 2012
Huang YB, Fu Y, Green Chem. , 15 , 1095, 2013
Rinaldi R, Palkovits R, Schuth F, Angew. Chem.-Int. Edit. , 47 , 8047, 2008
Gliozzi G, Innorta A, Mancini A, Bortolo R, Perego C, Ricci M, Cavani F, Appl. Catal. B: Environ. , 145 , 24, 2014
Cai HL, Li CZ, Wang AQ, Xu GL, Zhang T, Appl. Catal. B: Environ. , 123-124 , 333, 2012
Cheng MX, Shi T, Guan HY, Wang ST, Wang XH, Jiang ZJ, Appl. Catal. B: Environ. , 107 (1-2), 104, 2011
Takagaki A, Nishimura M, Nishimura S, Ebitani K, Chem. Lett. , 40 (10), 1195, 2011
Kobayashi H, Komanoya T, Hara K, Fukuoka A, ChemSusChem , 3 , 440, 2010
Suganuma S, Nakajima K, Kitano M, Yamaguchi D, Kato H, Hayashi S, Hara M, J. Am. Chem. Soc. , 130 (38), 12787, 2008
Guo HX, Qi XH, Li LY, Smith RL, Bioresour. Technol. , 116 , 355, 2012
Onda A, Ochi T, Yanagisawa K, Green Chem. , 10 , 1033, 2008
Hu L, Tang X, Wu Z, Lin L, Xu JX, Xu N, Dai BL, Chem. Eng. J. , 263 , 299, 2015
Miller GL, Anal. Chem. , 31 , 426, 1959
Zhou LP, Liu Z, Shi MT, Du SS, Su YL, Yangm XM, Xu J, Carbohydr. Polym. , 98 , 146, 2013
Shen SG, Wang CY, Cai B, Li HM, Han Y, Wang T, Qin HF, Fuel , 113 , 644, 2013
Liu M, Jia SG, Gong YY, Song CS, Guo XW, Ind. Eng. Chem. Res. , 52 (24), 8167, 2013
Qi XH, Lian YF, Yan LL, Smith RL, Catal. Commun. , 57 , 50, 2014
Hu SL, Smith TJ, Lou WY, Zong MH, J. Agric. Food Chem. , 62 , 1905, 2014
Xiong Y, Zhang ZH, Wang X, Liu B, Lin JT, Chem. Eng. J. , 235 , 349, 2014
Guo HX, Lian YF, Yan LL, Qi XH, Smith RL, Green Chem. , 15 , 2167, 2013
Kim SJ, Dwiatmoko AA, Choi JW, Suh YW, Suh DJ, Oh M, Bioresour. Technol. , 101 (21), 8273, 2010
Tian JA, Fan CY, Cheng MX, Wang XH, Chem. Eng. Technol. , 34 (3), 482, 2011
Lai DM, Deng L, Guo QX, Fu Y, Energy Environ. Sci. , 4 , 3552, 2011
이전 논문 다음 논문
Result Search