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Issue
Korean Journal of Chemical Engineering,
Vol.33, No.2, 649-656, 2016
Kinetic model for sorption of divalent heavy metal ions on low cost minerals
Chawla A, Prasad M, Goswami R, Ranshore S, Kulshreshtha A, Sinha ASK
A mathematical model is proposed that could predict the kinetic parameters for adsorption of divalent heavy metal ions (lead, copper and zinc) onto low-cost adsorbents such as pyrophyllite and rock phosphate using experimental data. The experiments were conducted with the initial concentrations of metal ions ranging from 10mg/L to 100mg/L. The mathematical model is based on the application of the Redlich-Peterson isotherm to mass transfer across the film surrounding the adsorbent. The developed non-linear sorption kinetic (NSK) mathematical model was solved using numerical integration by the trapezoidal method in Microsoft Excel along with the SOLVER function to obtain the best simulated values of the Redlich-Peterson constants A, B, r, the order of reaction n, and the film transfer coefficient α. Dissolution followed by precipitation was found to be the most probable mechanism responsible for heavy metal ion uptake by rock phosphate, while for pyrophyllite physical adsorption was governing mechanism at low concentrations (<100mg/L). The values of parameters A, B, r and α lie in the ranges of 0.015-23.2, 0.00003-3.09, 0.072-1, and 0.000057-52.8 [(L/mg)(n.1)/min], respectively, under different experimental conditions.
Keywords: Adsorption; Divalent Heavy Metal Ions; Rock Phosphate; Pyrophyllite; Sorption Kinetic Model; Redlich-Peterson Isotherm
[References]
  1. Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2, 2010
  2. Barbier F, Duc G, Petit-Ramel M, Colloids Surf. A: Physicochem. Eng. Asp., 166, 153, 2000
  3. Lee SH, Vigneswaran S, Moon H, Ind. Chem. Eng., 40, 5, 1998
  4. Seki H, Suzuki A, J. Colloid Interface Sci., 171(2), 490, 1995
  5. Sen TK, Mahajan SP, Khila KC, Colloids Surf. A: Physicochem. Eng. Asp., 211, 91, 2002
  6. Brown PA, Gill SA, Allen SJ, Water Res., 34, 3907, 2000
  7. Ho YS, McKay G, Water Res., 34, 735, 2000
  8. Hoeffer PR, Lecuyer I, Cloirec PL, Water Res., 35, 965, 2001
  9. Burns CA, Cass PJ, Harding IH, Crawford RJ, Colloids Surf. A: Physicochem. Eng. Asp., 155, 63, 1999
  10. Prasad M, Amritphale SS, Saxena S, Chandra N, Miner. Eng., 13, 1301, 2000
  11. Prasad M, Amritphale SS, Saxena S, Chandra N, Ind. Eng. Chem. Res., 37, 4816, 2002
  12. Klapiszewski L, Bartczak P, Wysokowski M, Jankowska M, Kabat K, Jesionowski T, Chem. Eng. J., 260, 684, 2015
  13. Wysokowski M, Klapiszewski L, Moszynski D, Bartczak P, Szatkowski T, Majchrzak I, Stefanska KS, Bazhenov VV, Jesionowski T, Mar. Drugs., 12, 2245, 2014
  14. Prasad M, Saxena S, J. Environ. Manage., 88, 1273, 2008
  15. Scheidegger AM, Lamble GM, Sparks DI, Environ. Sci. Technol., 30, 548, 1996
  16. Gucek A, Sener S, Bilgen S, Mamano MA, J. Colloid Interface Sci., 286(1), 53, 2005
  17. Sayilkan H, Erdemoglu S, Sener S, Sayilkan F, Akarsu M, Erdemoglu M, J. Colloid Interface Sci., 275(2), 530, 2004
  18. Erdemoglu M, Erdemoglu S, Sayilkan F, Akarsu M, Sener S, Sayilkan H, Appl. Clay Sci., 27, 41, 2004
  19. Jeon BH, Dempsey BA, Burgos WD, Royer RA, Roden EE, Water Res., 38, 2499, 2004
  20. Faur-Brasquet C, Reddad Z, Kadirvelu K, Le Cloirec P, Appl. Surf. Sci., 196(1-4), 356, 2002
  21. Voegelin A, Kretzschmar R, Eur. J. Soil Sci., 54, 387, 2003
  22. Xu Y, Axe L, Yee N, Dyer JA, Environ. Sci. Technol., 40, 2213, 2006
  23. Babu BV, Ramakrishna V, Proceedings of International Symposium and 57th Annual Session of II ChE in Association with AIChE (CHEMCON) Mumbai, 27 (2004).
  24. Gupta N, Prasad M, Singhal N, Kumar V, Ind. Eng. Chem. Res., 48(4), 2125, 2009
  25. Singhal N, Prasad M, Gupta N, Kumar V, J. Colloid Interface Sci., 313(2), 423, 2007
  26. Ng JCY, Cheung WH, McKay G, J. Colloid Interface Sci., 255(1), 64, 2002
  27. Gimbert F, Morin-Crini N, Renault F, Badot PM, Crini G, J. Hazard. Mater., 157(1), 34, 2008
  28. Wong YC, Szeto YS, Cheung WH, McKay G, Process Biochem., 39, 693, 2004
  29. Jossens L, Prausnitz JM, Fritz W, Schlunder EU, Myers AL, Chem. Eng. Sci., 33, 1097, 1978
  30. Mullah AH, Robinson CW, Water Res., 30, 2901, 1996
  31. Saxena S, Removal of toxic elements from aqueous solutions using different substrate materials, Ph.D. Thesis, Barkatullah University, Bhopal (2001).
  32. Prasad M, Majumder AK, Rao LS, Rao TC, Project completion report on ‘Beneficiation and Industrial Utilisation of Some Fertliliser Minerals of Madhya Pradesh’ submitted to Department of Mines, Government of India, New Delhi (1996).
  33. Prasad M, Ph.D. Thesis: Ore beneficiation studies of low grade rock phosphate deposits of Madhya Pradesh, Barkatullah University, Bhopal (1998).
  34. Prasad M, Saxena S, J. Environ. Manage., 88, 1273, 2008
  35. Prasad M, Saxena S, Ind. Eng. Chem. Res., 43(6), 1512, 2004
  36. Chegrouche S, Mellah A, Telmoune S, Water Res., 31, 1733, 1997
  37. Suzuki T, Hatsushika T, Hayakawa Y, J. Chem. Soc.-Faraday Trans., 177, 1059, 1981
  38. Suzuki Y, Takuchi Y, J. Chem. Eng. Jpn., 27, 571, 1997
  39. Xu Y, Schwartz FW, Traina SJ, Environ. Sci. Technol., 28, 1472, 1994
  40. Ma QY, Traina SJ, Logan SJ, Ryan JA, Environ. Sci. Technol., 27, 1803, 1993
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