Korean Journal of Chemical Engineering, Vol.33, No.2, 582-586, 2016
Esterification of acetic and oleic acids within the Amberlyst 15 packed catalytic column
A packed column system was used to study the esterification of acetic and oleic acids by the macro-porous acidic resin, Amberlyst 15. All reactions were at a constant temperature (75 oC) and catalyst mass (3 g). The impact of column flow rate conditions and the molar fatty acid to ethanol feedstock ratio on ester production is reported. The maximum ester production was noted at a flow rate of 0.25mL/min. The maximum observed ester yield for acetic acid (95.2±0.5%) and oleic acid (43.8±1.3%) was observed at an acid:ethanol molar ratio of 1 : 3 and 1 : 1, respectively. The difference in yield indicates the importance of the fatty acid chain length to the reaction.
[References]
Pirola C, Manenti F, Galli F, Bianchi CL, Chem. Eng. Trans. , 37 , 553, 2014
Yin P, Chen L, Wang Z, Qu RJ, Liu XG, Xu Q, Ren SH, Fuel , 102 , 499, 2012
Peng-Lim B, Ganesan S, Maniam GP, Khairuddean M, Efendi J, Energy Conv. Manag. , 65 , 392, 2013
Demirbas A, Energy Conv. Manag. , 50 (11), 2782, 2009
Demirbas A, Appl. Energy , 88 (1), 17, 2011
US Department of Energy, DOE/GO-102008-2542, www.eere.energy.gov/cleancities accessed date: 11.08.2014 (2008).
Tokunaga K, Konan DE, Appl. Energy , 125 , 123, 2014
Russbueldt BME, Hoelderich WF, Appl. Catal. A: Gen. , 362 (1-2), 47, 2009
Chongkhong S, Tongurai C, Chetpattananondh R, Renew. Energy , 34 (4), 1059, 2009
Leung DYC, Wu X, Leung MKH, Appl. Energy , 87 (4), 1083, 2010
Banerjee A, Chakraborty R, Resour. Conserv. Recycl. , 53 , 490, 2009
Sharma YC, Agrawal S, Singh B, Frometa AEN, Can. J. Chem. Eng. , 90 (2), 483, 2012
Huang GH, Chen F, Wei D, Zhang XW, Chen G, Appl. Energy , 87 (1), 38, 2010
Boro J, Thakur AJ, Deka D, Fuel Process. Technol. , 92 (10), 2061, 2011
Hayyan A, Alam MZ, Mirghani MES, Kabbashi NA, Hakimi NINM, Siran YM, Tahiruddin S, Bioresour. Technol. , 101 (20), 7804, 2010
Giri BY, Rao KN, Devi BLAP, Lingaiah N, Suryanarayana I, Prasad RBN, Catal. Commun. , 6 , 788, 2005
Lam MK, Lee KT,Mohamed AR, Biotechnol. Adv. , 28 , 500, 2010
Park JY, Kim DK, Lee JS, Bioresour. Technol. , 101 , S62, 2010
Park JY, Wang ZM, Kim DK, Lee JS, Renew. Energy , 35 (3), 614, 2010
Hayyan A, Hashim MA, Mirghani MES, Hayyan M, AlNashef IM, Korean J. Chem. Eng. , 30 (6), 1229, 2013
Yu MJ, Jo YB, Kim SG, Lim YK, Jeon JK, Park SH, Kim SS, Park YK, Korean J. Chem. Eng. , 28 (12), 2287, 2011
Tesser R, Casale L, Verde D, Di Serio M, Santacesaria E, Chem. Eng. J. , 157 (2-3), 539, 2010
Son SM, Kimura H, Kusakabe K, Bioresour. Technol. , 102 (2), 2130, 2011
Lucena IL, Saboya RMA, Oliveira JFG, Rodrigues ML, Torres AEB, Cavalcante CL, Parente EJS, Silva GF, Fernandes FAN, Fuel , 90 (2), 902, 2011
de la Cuesta PJM, Martinez ER, Perez FIP, Sarria FR, Can. J. Chem. Eng. , 77 (6), 1169, 1999
Yu WF, Hidajat K, Ray AK, Appl. Catal. A: Gen. , 260 (2), 191, 2004
Park JY, Lee JS, Wang ZM, Kim DK, Korean J. Chem. Eng. , 27 (6), 1791, 2010
Jamal Y, Luo G, Kuo CH, Rabie A, Boulanger B, J. Food Process Eng. , 37 , 27, 2014
Feng YH, Zhang AQ, Li JX, He BQ, Bioresour. Technol. , 102 (3), 3607, 2011
Food Chemicals Codex, Institute of Medicine (U.S.), Committee on Food Chemicals Codex National Academies Press (2003).
Barnwala BK, Sharma MP, Sustain. Energy Rev. , 9 , 363, 2005
Kocsisova T, Cvengros J, Lutisan J, Eur. J. Lipid Sci. Technol. , 107 , 87, 2005
Marchetti JM, Miguel VU, Errazu AF, Fuel , 86 (5-6), 906, 2007
Basumatary S, Deka DC, Der Chemica Sinica , 3 , 1384, 2012
Al-Arafi N, Salimon J, E-Journal Chem. , 9 , 99, 2012
[Cited By]
Chandane VS, Rathod AP, Wasewar KL, Sonawane SS, Korean Journal of Chemical Engineering , 34 (4), 987, 2017
Amani P, Amani M, Hasanvandian R, Korean Journal of Chemical Engineering , 34 (5), 1456, 2017
이전 논문 다음 논문
Result Search