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Issue
Korean Journal of Chemical Engineering,
Vol.33, No.1, 248-254, 2016
Vapor-liquid equilibria for the binary mixtures of dimethyl ether (DME)+dimethyl carbonate (DMC)
Jeong WJ, Lim JS
Isothermal vapor-liquid equilibrium data for the binary system of dimethyl ether (DME)+dimethyl carbonate (DMC) were measured at 303.15, 313.15, 323.15, 333.15 and 343.15 K using a circulation-type equilibrium apparatus with on-line gas chromatography analysis. The experimental data were correlated with the Peng-Robinson equation of state (PR-EoS) using the van der Waals one fluid mixing rule and the Peng-Robinson equation of state (PR-EoS) using the Wong-Sandler mixing rule combined with the NRTL excess Gibbs free energy model. This system showed negative deviation from Raoult’s law, and no azeotropic behavior was observed for all the temperature ranges studied here. Calculated results with PR-EoS using both two mixing rules showed good agreement with experimental data.
Keywords: Vapor Liquid Equilibria; Dimethyl Ether (DME); Dimethyl Carbonate (DMC); Peng-Robinson Equation of State (PR-EoS)
[References]
  1. Tundo P, Selva M, Accounts Chem. Res., 35, 706, 2002
  2. Ono Y, Appl. Catal. A: Gen., 155(2), 133, 1997
  3. Pacheco MA, Marshall CL, Energy Fuels, 11(1), 2, 1997
  4. Ono Y, Catal. Today, 35(1-2), 15, 1997
  5. Shaikh AA, Sivaram S, Chem. Rev., 96(3), 951, 1996
  6. Ein-Eli Y, Electrochem. Commun., 4, 644, 2002
  7. Delledonne D, Rivetti F, Romano U, Appl. Catal. A: Gen., 221(1-2), 241, 2001
  8. Romano U, Tesel R, Mauri MM, Ind. Eng. Chem. Prod. Res. Dev., 19, 396, 1980
  9. Matsuzaki T, Nakamura A, Catal. Surv. Asia, 1, 77, 1997
  10. Fang SN, Fujimoto K, Appl. Catal. A: Gen., 142(1), L1, 1996
  11. Li CF, Zhong SH, Catal. Today, 82(1-4), 83, 2003
  12. Hong ST, Park HS, Lim JS, Lee YW, Anpo M, Kim JD, Res. Chem. Intermed., 32, 737, 2006
  13. Hong ST, Park HS, Lim JS, Yoo KP, Korean Chem. Eng. Res., 46(3), 550, 2008
  14. Tomishige K, Sakaihori T, Ikeda Y, Fujimoto K, Catal. Lett., 58(4), 225, 1999
  15. Almusaiteer K, Catal. Commun., 10, 1127, 2009
  16. Tomishige K, Kunimori K, Appl. Catal. A: Gen., 237(1-2), 103, 2002
  17. Kim SA, Yim JH, Byun HS, Lim JS, Korean J. Chem. Eng., 28(12), 2324, 2011
  18. Lee MH, Yim JH, Kang JW, Lim JS, Fluid Phase Equilib., 318, 77, 2012
  19. Lee MH, Yim JH, Lim JS, Korean J. Chem. Eng., 29(10), 1418, 2012
  20. Cho H, Yim JH, Lim JS, J. Supercrit. Fluids, 81, 7, 2013
  21. Cho H, Kim JE, Lim JS, Fluid Phase Equilib., 379, 52, 2014
  22. Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59, 1976
  23. Shibata SK, Sandler SI, Ind. Eng. Chem. Res., 28, 1893, 1989
  24. Im J, Kim M, Lee J, Kim H, J. Chem. Eng. Data, 49(2), 243, 2004
  25. Wong DSH, Sandler SI, AIChE J., 38, 671, 1992
  26. Abrams DS, Prausnitz JM, AIChE J., 21, 116, 1975
  27. Renon H, Prausnitz JM, AIChE J., 14, 135, 1968
  28. Frenkel M, Chirico RD, Diky V, Muzny CD, Kazakov AF, NIST ThermoData Engine, NIST Standard Reference Database 103b-Pure Compounds, Binary Mixtures, and Chemical Reactions, Version 5.0, Standard Reference Data Program, National Institute of Standards and Technology, Gaithersburg, MD (2010).
[Cited By]
  1. Jeong WJ, Cho HK, Lim JS, Korean Journal of Chemical Engineering, 33(10), 2961, 2016
  2. Jeong WJ, Lim JS, Korean Journal of Chemical Engineering, 34(2), 463, 2017
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