About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.33, No.1, 132-139, 2016
Deep extractive desulfurization of oil over 12-Molibdophosphoric acid encapsulated in metal-organic frameworks
Rafiee E, Nobakht N
A desulfurization process for model oil and real oil was investigated based on the chemical oxidation of mixed sulfur containing compounds in the presence of nitrogen compounds (indole and quinoline) using hydrogen peroxide as oxidizing agent and dodecamolibdophosphoric acid (H3PMo12O40) encapsulated in a kind of metal-organic framework (HKUST-1) as PMo@HKUST-1. The effect of isopropanol, ethanol and acetonitrile as extractive solvent and 1-ring (toluene, xylene and mesitylene) and 2-ring (naphthalene) aromatic hydrocarbons in desulfurization of model oil was studied. The desulfurization of sulfur-containing compounds was accelerated in the presence of aromatic hydrocarbons. In fact, a higher desulfurization efficiency of the heterogeneous catalyst could be achieved with system containing a polar solvent in contact with an aromatic hydrocarbon. Quinoline had no effect on oxidative desulfurization (ODS) reaction, whereas indole had a slightly negative effect. Presence of aromatic compounds had slightly positive effect on ODS reaction.
Keywords: Oxidative Desulfurization; Real Oil; Polyoxometalates; Metal-organic Frameworks
[References]
  1. de Souza WF, Guimaraes LR, Guerreiro MC, Oliveira LCA, Appl. Catal. A: Gen., 360(2), 205, 2009
  2. Stanislaus A, Marafi A, Rana MS, Catal. Today, 153(1-2), 1, 2010
  3. Jiang X, Li HM, Zhu WS, He LN, Shu HM, Lu JD, Fuel, 88(3), 431, 2009
  4. Zhang G, Yu F, Wang R, Petroleum & Coal, 51, 196, 2009
  5. Yu F, Wang R, Molecules, 18, 13691, 2013
  6. Ribeiro S, Granadeiro CM, Silva P, Paz FAA, de Biani FF, Cunha-Silva L, Balula SS, Catal. Sci. Technol., 3, 2404, 2013
  7. Huang D, Wang YJ, Yang LM, Luo GS, Ind. Eng. Chem. Res., 45(6), 1880, 2006
  8. Ishihara A, Wang DH, Dumeignil F, Amano H, Qian EWH, Kabe T, Appl. Catal. A: Gen., 279(1-2), 279, 2005
  9. Prasad VVDN, Jeong KE, Chae HJ, Kim CU, Jeong SY, Catal. Commun., 9, 1966, 2008
  10. Garcia-Gutierrez JL, Fuentes GA, Hernandez-Teran ME, Murrieta F, Navarrete J, Jimenez-Cruz F, Appl. Catal. A: Gen., 305(1), 15, 2006
  11. Chica A, Corma A, Domine ME, J. Catal., 242(2), 299, 2006
  12. Campos-Martin JM, Capel-Sanchez MC, Fierro JLG, Green Chem., 6, 557, 2004
  13. Corma A, Iglesias M, Sanchez F, Catal. Lett., 39(3-4), 153, 1996
  14. Cedeno-Caero L, Ramos-Luna M, Mendez-Cruz M, Ramirez-Solis J, Catal. Today, 172(1), 189, 2011
  15. Kim TW, Kim MJ, Kleitz F, Nair MM, Nicolas RG, Jeong KE, Chae HJ, Kim CU, Jeong SY, ChemCatChem., 4, 687, 2012
  16. Shiraishi Y, Tachibana K, Hirai T, Komasawa I, Ind. Eng. Chem. Res., 41(17), 4362, 2002
  17. Zhang J, Wang AJ, Li X, Ma XH, J. Catal., 279(2), 269, 2011
  18. Cho KS, Lee YK, Appl. Catal. B: Environ., 147, 35, 2014
  19. Cedeno-Caero L, Gomez-Bernal H, Fraustro-Cuevas A, Guerra-Gomez HD, Cuevas-Garcia R, Catal. Today, 133, 244, 2008
  20. Navarro-Amador JF, Gomez-Bernaly H, Cedeno-Caero L, Revista Mexicana de Ingenieria Quimica, 5, 293, 2006
  21. Jia Y, Li G, Ning G, Jin C, Catal. Today, 140, 192, 2009
  22. Balula MSS, Santos ICMS, Simoes MMQ, Neves MGPMS, Cavaleiro JAS, Cavaleiro AMV, J. Mol. Catal. A-Chem., 222(1-2), 159, 2004
  23. Ishimoto R, Kamata K, Mizuno N, Angew. Chem.-Int. Edit., 51, 4662, 2012
  24. Yu R, Kuang XF, Wu XY, Lu CZ, Donahue JP, Coord. Chem. Rev., 253, 2872, 2009
  25. Sun CY, Liu SX, Liang DD, Shao KZ, Ren YH, Su ZM, J. Am. Chem. Soc., 131(5), 1883, 2009
  26. Yang H, Li J, Wang L, Dai W, Lv Y, Gao S, Catal. Commun., 35, 101, 2013
  27. Yan XM, Mei P, Xiong L, Gao L, Yang Q, Gong L, Catal. Sci. Technol., 3, 1985, 2013
  28. Yan XM, Ping ZM, Yang MQ, J. Porous Mat., 21, 729, 2014
  29. Tang L, Luo G, Kang L, Zhu M, Dai B, Korean J. Chem. Eng., 30(2), 314, 2013
  30. Liu D, Lu Y, Tan HQ, Chen WL, Zhang ZM, Li YG, Wang EB, Chem. Commun., 49, 3673, 2013
  31. Janssens N, Wee LH, Bajpe S, Breynaert E, Kirschhock CEA, Martens JA, Chem. Sci., 3, 1847, 2012
  32. Yu F, Zheng PQ, Long YX, Ren YP, Kong XJ, Long LS, Yuan YZ, Huang RB, Zheng LS, Eur. J. Inorg. Chem., 4526, 2010
  33. Granadeiro CM, Barbosa ADS, Silva P, Paz FAA, Saini VK, Fires J, de Castro B, Balula SS, Cunha-Silva L, Appl. Catal. A: Gen., 453, 316, 2013
  34. Maksimchuk NV, Timofeeva MN, Melgunov MS, Shmakov AN, Chesalov YA, Dybtsev DN, Fedin VP, Kholdeeva OA, J. Catal., 257(2), 315, 2008
  35. Corma A, Garcia H, Xamena FXL, Chem. Rev., 110(8), 4606, 2010
  36. Lee J, Farha OK, Roberts J, Scheidt KA, Nguyen ST, Hupp JT, Chem. Soc. Rev., 38, 1450, 2009
  37. Liu HY, Wu H, Ma JF, Liu YY, Yang J, Ma JC, J. Chem. Soc.-Dalton Trans., 40, 602, 2011
  38. Rodriguez-Albelo LM, Ruiz-Salvador AR, Sampieri A, Lewis DW, Gomez A, Nohra B, Mialane P, Marrot J, Secheresse F, Mellot-Draznieks C, Biboum RN, Keita B, Nadjo L, Dolbecq A, J. Am. Chem. Soc., 131(44), 16078, 2009
  39. Ranocchiari M, van Bokhoven JA, Phys. Chem. Chem. Phys., 13, 6388, 2011
  40. Song J, Luo Z, Britt DK, Furukawa H, Yaghi OM, Hardcastle KI, Hill CL, J. Am. Chem. Soc., 133(42), 16839, 2011
  41. Rafiee E, Nobakht N, J. Mol. Catal. A-Chem., 398, 17, 2015
  42. Hulea V, Fajula F, Bousquet J, J. Catal., 198(2), 179, 2001
  43. Chotani G, Dodge T, Hsu A, Kumar M, LaDuca R, Trimbur D, Weyler W, Sanford K, Biochem. Biophys. Acta, 1543, 434, 2000
  44. Thomsen AB, Laturnus F, J. Hazard. Mater., 81(1-2), 193, 2001
  45. Bonchio M, Campestrini S, Conte V, Di Furia F, Moro S, Tetrahedron, 51, 12372, 1995
  46. Bernal HG, Caero LC, Gutierrez-Alejandre A, Catal. Today, 142, 227, 2009
  47. Long ZY, Yang CP, Zeng GM, Peng LY, Dai CH, He HJ, Fuel, 130, 19, 2014
  48. Jiang CY, Wang JJ, Wang ST, Guan HY, Wang XH, Huo MX, Appl. Catal. B: Environ., 106(3-4), 343, 2011
  49. Garcia-Gutierrez JL, Fuentes GA, Hernandez-Teran ME, Garcia P, Murrieta-Guevara F, Jimenez-Cruz F, Appl. Catal. A: Gen., 334(1-2), 366, 2008
  50. Luo GQ, Kang LH, Zhu MY, Dai B, Fuel Process. Technol., 118, 20, 2014
[Cited By]
  1. Haruna A, Merican ZMA, Musa SG, Journal of Industrial and Engineering Chemistry, 112, 20, 2022
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.