Issue
Korean Journal of Chemical Engineering,
Vol.32, No.10, 2161-2167, 2015
Removal characteristics of Cd(II) ions from aqueous solution on ordered mesoporous carbon
Ordered mesoporous carbon (CMK-3) was synthesized using SBA-15 mesoporous molecular sieve as a template and sucrose as carbon source. The materials were characterized by XRD, TEM and N2 physical adsorption technique. The resulting CMK-3 was used as adsorbent to remove Cd(II) ions from aqueous solution. The effect of pH, contact time and temperature on adsorption process was investigated in batch experiments. The results showed that the removal percentage could reach ca. 90% at the conditions of initial Cd(II) ions concentration of 20 mg/L, dose of 20mg, pH 6.5, contact time of 3h and 293K. Langmuir and Freundlich models were employed to describe the adsorption equilibrium. The kinetics data were described by the pseudo-first-order and pseudo-second-order models, respectively. The adsorption isotherm was well fitted to the Langmuir model, and the adsorption process was well described by the pseudo-second-order kinetic model.
[References]
  1. Wang H, Yuan XZ, Wu Y, Huang HJ, Zeng GG, Liu Y, Wang XL, Lin NB, Qi Y, Appl. Surf. Sci., 279, 432, 2013
  2. Sukpreabprom H, Arqueropanyo O, Naksata W, Sooksamiti P, Janhom S, Korean J. Chem. Eng., 32(5), 896, 2015
  3. Khorzughy SH, Eslamkish T, Ardejani FD, Heydartaemeh MR, Korean J. Chem. Eng., 32(1), 88, 2015
  4. Wang FY, Wang H, Ma JW, J. Hazard. Mater., 177(1-3), 300, 2010
  5. Ghosh P, Samanta AN, Ray S, Desalination, 266(1-3), 213, 2011
  6. Liu LH, Wu J, Li X, Ling YL, Sep. Purif. Technol., 103, 92, 2013
  7. Dbrowski A, Hubicki Z, Podkocielny P, Robens E, Chemosphere, 56, 91, 2004
  8. Mohsen-Nia M, Montazeri P, Modarress H, Desalination, 217(1-3), 276, 2007
  9. Argun ME, Dursun S, Karatas M, Guru M, Bioresour. Technol., 99(18), 8691, 2008
  10. Mohammadi T, Moheb A, Sadrzadeh M, Razmi A, Sep. Purif. Technol., 41(1), 73, 2005
  11. Zhao FP, Repo E, Yin DL, Sillanpaa MET, J. Colloid Interface Sci., 409, 174, 2013
  12. Chen SP, Hong JX, Yang HX, Yang JZ, J. Environ. Radioact., 126, 253, 2013
  13. Huang ZH, Zheng XY, Lv W, Wang M, Yang QH, Kang FY, Langmuir, 27(12), 7558, 2011
  14. Liu SG, Ding YQ, Li PF, Diao KS, Tan XC, Lei FH, Zhan YH, Lib QM, Huang B, Huang ZY, Chem. Eng. J., 248, 135, 2014
  15. Xu P, Zeng GM, Huang DL, Feng CL, Hu S, Zhao MH, Lai C, Wei Z, Huang C, Xie GX, Liu ZF, Sci. Total Environ., 424, 1, 2012
  16. Hu J, Lo MC, Chen GH, Water Sci. Technol., 50, 139, 2004
  17. Zhao G, Li J, Ren X, Chen C, Wang X, Environ. Sci. Technol., 45, 10454, 2011
  18. Srivastava VC, Mall ID, Mishra IM, Chem. Eng. Process., 47, 1269, 2008