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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.10, 2153-2160, 2015
Nickel ion removal using nanoporous poly(styrene-co divinyl benzene) copolymer
Bagherian A, Ghorbani M, Mirzababaei SN
To achieve a suitable porous structure and high mechanical strength that is extremely valuable properties in adsorbent polymeric particles, poly(styrene-co-divinylbenzene) with high amounts of cross-linker and diverse proportions of diluent agent (porogen) were synthesized according to the methodology of the suspension polymerization technique. The structural characteristics of the particles and their adsorption properties for adsorption of Nickel ions were studied. Effect of solvent type and monomeric fraction on particles morphology and porosity was discussed. The solvents including n-heptane (HEP) and acetonitrile and monomer fraction was 50% and 30% of divinylbenzene (DVB). From the results obtained, we decided to apply an adsorbent with high mechanical strength and a porous structure appropriate for absorbing the Ni(II). The copolymer was characterized by Fourier transform infrared (FT-IR) analysis. We used scanning electron microscopy (SEM) and transmission electron microscopy (TEM) tests to study the morphology and particle size of the nanoparticles. According to the results, the copolymers synthesized with n-heptane have more porosity. Also an increase in the percentage of DVB caused finer pores. After synthesis of copolymer the applicability of these polymer beads to separation and concentration of Ni(II) is discussed. In separation of Ni(II) from aqueous solution, the effects of pH, temperature and time are discussed and thermodynamic and kinetic calculations are done and its isotherm are fitted with various equations.
Keywords: Coplymer; Styrene; Divinylbenzene; Adsorption; Kinetic; Thermodynamic
[References]
  1. Urban D, Takamura K (eds.), Polymer dispersions and their industrial applications, Wiley-VCH, Weinheim (2002).
  2. Fudouzi H, Xia YN, Adv. Mater., 15(11), 892, 2003
  3. Ugelstad J, Stenstad P, Kilaas L, Prestvik WS, Rian A, Nustad K, Herje R, Berge A, Macromol. Symp., 101, 491, 1996
  4. Moore JC, J. Polym. Sci. A: Polym. Chem., 2, 835, 1964
  5. Park JG, Kim JW, Oh SG, Suh KD, J. Appl. Polym. Sci., 87(3), 420, 2003
  6. Likozar B, Krajnc M, J. Appl. Polym. Sci., 110(1), 183, 2008
  7. Kaang S, Jin W, Kader MA, Nah C, Polym. -Plast. Technol. Eng., 43, 1517, 2004
  8. Lu Y, Liu L, Tian M, Geng H, Zhang L, Eur. Polym. J., 41, 589, 2005
  9. Samui AB, Dalvi VG, Chandrasekhar L, Patri M, Chakraborty BC, J. Appl. Polym. Sci., 99(5), 2542, 2006
  10. Lu Y, Liu L, Yang C, Eur. Polym. J., 41, 577, 2005
  11. Garcia-Diego C, Cuellar J, Ind. Eng. Chem. Res., 44(22), 8237, 2005
  12. Garcia-Diego C, Cuellar J, Ind. Eng. Chem. Res., 45(10), 3624, 2006
  13. Cantarero LA, Butler JE, Osborne JW, Anal. Biochem., 105, 375, 1980
  14. Lloyd LL, J. Chromatogr., 544, 201, 1991
  15. Okay O, Prog. Polym. Sci, 25, 711, 2000
  16. Yuan HG, Kalfas G, Ray WH, J. Macromol. Sci.-Phys., C-31, 215, 1991
  17. Vivaldolima E, Wood PE, Hamielec AE, Penlidis A, Ind. Eng. Chem. Res., 36(4), 939, 1997
  18. Hamielec AE, Tobita H, Polymerization Process-In Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, Germany (2002).
  19. Lovell PA, El-Aasser MS, Emulsion polymerization and emulsion polymers, Wiley, New York (1999).
  20. Napper DH Polymeric stabilization of colloidal dispersions, Academic, London (1983).
  21. Abrams IM, Millar JR, React. Funct. Polym., 35(1), 7, 1997
  22. Gazda DB, Fritz JS, Porter MD, Anal. Chim. Acta, 508, 53, 2004
  23. Allmer K, Hult A, Raanby B, J. Polym. Sci. A: Polym. Chem., 27, 3405, 1989
  24. Landoll LM, Breslow DS, J. Polym. Sci. A: Polym. Chem., 27, 2189, 1989
  25. Hasar H, J. Hazard. Mater., 97(1-3), 49, 2003
  26. Panneerselvam P, SathyaSelvaBala V, Thinakaran N, Baskaralingam P, Palanichamy M, Sivanesan S, E-J. Chem., 6, 729, 2009
  27. Yang XY, Al-Duri B, J. Colloid Interface Sci., 287(1), 25, 2005
  28. You LJ, Wu ZJ, Kim T, Lee K, J. Colloid Interface Sci., 300(2), 526, 2006
  29. Yoon JH, Baek JI, Yamamoto Y, Komai T, Kawamura T, Chem. Eng. Sci., 58(23-24), 5229, 2003
  30. Paul S, Ghoshal AK, Mandal B, Chem. Eng. Sci., 64(2), 313, 2009
  31. He BL, Huang WQ, Ion exchange and adsorption resin, Shanghai Science and Education Press, Shanghai (1995).
  32. Huang JH, Wang G, Huang KL, Chem. Eng. J., 168(2), 715, 2011
[Cited By]
  1. Ahmad H, Sharafat MK, Alam MA, Rahman MM, Tauer K, Minami H, Sultana MS, Das BK, Shabnam R, Macromolecular Research, 25(7), 671, 2017
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