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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.10, 2142-2152, 2015
Micellization behavior of mixtures of amphiphilic promazine hydrochloride and cationic aniline hydrochloride in aqueous and electrolyte solutions
Rub MA, Azum N, Khan F, Sehemi GA, Asiri AM
We studied the influence of cationic hydrotrope aniline hydrochloride on the micellization behavior of cationic amphiphilic phenothiazine drug promazine hydrochloride in the presence and absence of 50mmol kg.1 NaCl. The experimental critical micelle concentration (CMC) values came out to be lower than ideal CMC (CMCid) values, signifying attractive interactions between the two components in mixed micelles. NaCl further decreases the CMC of pure PMZ and aniline hydrochloride as well as their mixture due to screening of the electrostatic repulsion among the polar head groups. The bulk properties of solution were examined by using different theoretical models for justification and comparison of results. The micellar mole fraction of aniline hydrochloride (X1 Rub, X1 M, X1 Rod and X1 id) was evaluated by different proposed models, showing greater contribution of hydrotrope in mixed micelle. The negative values of interaction parameter (β) indicate synergistic interactions and negative values of β further decrease by the addition of salt in mixed systems. From the CMC values as a function of temperature, various thermodynamic properties have been evaluated and discussed in detail.
Keywords: Phenothiazine Drug; Promazine Hydrochloride (PMZ); Critical Micelle Concentration (CMC); Hydrotrope; Interaction Parameter; Thermodynamic Parameters
[References]
  1. Tanford C, The hydrophobic effect: Formation of micelles and biological membranes, Wiley, New York (1980).
  2. Rub MA, Asiri AM, Khan JM, Khan RH, Kabir-ud Din, J. Mol. Struct., 1050, 35, 2013
  3. Li GH, Cho CG, Korean J. Chem. Eng., 25(6), 1444, 2008
  4. Azum N, Rub MA, Asiri AM, Colloids Surf. B: Biointerfaces, 121, 158, 2014
  5. Liu J, Zhang Y, Korean J. Chem. Eng., 23(5), 699, 2006
  6. Rub MA, Asiri AM, Khan JM, Khan F, Khan RH, Kabirud-Din, J. Taiwan Institute Chem. Eng., 45, 2068, 2014
  7. Rub MA, Azum N, Kumar D, Asiri AM, Marwani HM, J. Chem. Thermodyn., 74, 91, 2014
  8. Rosen MJ, Surfactants and interfacial phenomena, 3rd Ed., Wiley, New York (2004).
  9. Canto GS, Dalmora SL, Oliveira AG, Drug Dev. Ind. Pharm., 25, 1235, 1995
  10. Allen TM, Hansen CB, Menenez DEL, Adv. Drug Deliv. Rev., 16, 267, 1995
  11. Jones MC, Leroure JC, Eur. J. Pharma. Biopharm., 48, 101, 1999
  12. Booth HS, Everson HE, Ind. Eng. Chem., 40, 1491, 1948
  13. Srinivas V, Balasubramanian D, Langmuir, 14(23), 6658, 1998
  14. Roy BK, Moulik SP, Current Science, 85, 1148, 2003
  15. Balasubramanian D, Srinivas V, Gaikar VG, Sharma MM, J. Phys. Chem., 93, 3865, 1989
  16. Balasubramanian D, Friberg SE, in Surface and colloid science, Matijevic E Ed., Plenum Press, New York (1993).
  17. Neuberg C, Biochem. Z., 76, 107, 1916
  18. Attwood D, Florence AT, Surfactant systems, their chemistry, pharmacy and biology, Chapman and Hall, New York (1983).
  19. Schreier S, Malheiros SVP, de Paula E, Biochim. Biophys. Acta, 1508, 210, 2000
  20. Azum N, Rub MA, Asiri AM, Pharm. Chem. J., 48, 201, 2014
  21. Rub MA, Asiri AM, Azum N, Khan A, Khan AAP, Kabir-ud-Din, Tenside Surfactants Detergents, 50, 376, 2013
  22. Kabir-ud-Din, Khan AB, Naqvi AZ, J. Mol. Liq., 187, 374, 2013
  23. Rub MA, Kumar D, Azum N, Khan F, Asiri AM, J. Solution Chem., 43, 930, 2014
  24. Khan ZA, Kamil M, Sulaiman O, Hashim R, Ibrahim MNM, Khanam AJ, Kabir-ud-Din, J. Dispersion Sci. Technol., 32, 1452, 2011
  25. Mukerjee P, in Solution chemistry of surfactants, Mittal KL Ed., vol. 1, Plenum Press, New York (1979).
  26. Clint JH, J. Chem. Soc.-Faraday Trans., 71, 1327, 1975
  27. Scamehorn JF, An Overview of phenomena involving surfactant mixtures: Phenomena in mixed surfactant systems, Chapter 1, ACS Symposium Series 311 (1986).
  28. Javadian S, Gharibi H, Bromand Z, Sohrabi B, J. Colloid Interface Sci., 318(2), 449, 2008
  29. Schick MJ (Ed.), Nonionic Surfactants: Physical Chemistry, Dekker, New York (1987).
  30. Mosquera V, del Rio JM, Attwood D, Garcia M, Jones MN, Prieto G, Suarez MJ, Sarmiento F, J. Colloid Interface Sci., 206(1), 66, 1998
  31. Akhtar F, Hoque MA, Khan MA, J. Chem. Thermodyn., 40(7), 1082, 2008
  32. Hoque MA, Khan MA, Hossain MD, J. Chem. Thermodyn., 60, 71, 2013
  33. Hoque MA, Hossain MD, Khan MA, J. Chem. Thermodyn., 63, 135, 2013
  34. Kabir-ud-Din, Siddiqui US, Kumar S, Dar AA, Colloid Polym. Sci., 284, 807, 2006
  35. Ruiz CC, Diaz-Lopez L, Aguiar J, J. Colloid Interface Sci., 305(2), 293, 2007
  36. Islam MN, Kato T, J. Phys. Chem. B, 107(4), 965, 2003
  37. Rub MA, Sheikh MS, Khan F, Khan SB, Asiri AM, Z. Phys. Chem., 228, 747, 2014
  38. Rub MA, Azum N, Khan SB, Khan F, Asiri AM, J. Dispersion Sci. Technol., 36, 521, 2015
  39. Asakawa T, Kitano H, Ohta A, Miyagishi S, J. Colloid Interface Sci., 242(2), 284, 2001
  40. Iijima H, Kato T, Soderman O, Langmuir, 16(2), 318, 2000
  41. Zana R, J. Colloid Interface Sci., 78, 330, 1980
  42. Gorski N, Kalus J, Langmuir, 17(14), 4211, 2001
  43. Chauhan MS, Sharma K, Kumar G, Chauhan S, Colloids Surf. A: Physicochem. Eng. Asp., 221, 135, 2003
  44. Rubingh DN, in: Mittal KL (Ed.), Solution chemistry of surfactants, Plenum, New York (1979).
  45. Motomura K, Yamanaka M, Aratono M, Colloid Polym. Sci., 262, 948, 1984
  46. Rodenas E, Valiente M, Villafruela MD, J. Phys. Chem. B, 103(21), 4549, 1999
  47. Lange H, Beck KH, Kolloid Z. Z. Polym., 251, 424, 1973
  48. Singh OG, Ismail K, Colloids Surf. A: Physicochem. Eng. Asp., 414, 209, 2012
  49. Nusselder JJH, Engberts JBFN, J. Colloid Interface Sci., 148, 353, 1992
  50. Kresheck GC, in: Franks F (Ed.), Water. A comprehensive treatise, Plenum, New York (1995).
  51. Hall DG, J. Chem. Soc.-Faraday Trans., 87, 3529, 1991
  52. Maeda H, J. Phys. Chem. B, 109(33), 15933, 2005
  53. Rub MA, Asiri AM, Kumar D, Azum N, Khan F, Acta Phys. Chim. Sin., 30, 699, 2014
  54. Azum N, Rub MA, Asiri AM, J. Mol. Liq., 196, 14, 2014
  55. Azum N, Rub MA, Asiri AM, Marwani HM, J. Mol. Liq., 197, 339, 2014
[Cited By]
  1. Alfaifi SYM, Kumar D, Rub MA, Khan F, Azum N, Khan A, Asiri AM, Dzudzevic-Cancar H, Korean Journal of Chemical Engineering, 38(2), 386, 2021
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