Issue
Korean Journal of Chemical Engineering,
Vol.32, No.10, 2097-2102, 2015
Physico-chemical characterization, morphology and performance of polyethersulfone based membrane for glycerol removal from biodiesel produced through trans-esterification of waste cooking oils
In the current research, the biodiesel purification was by use of poly ether sulfone based membrane. The biodiesel was produced from waste cooking oils by trans-esterification. Membranes were fabricated by solution casting through phase inversion method. The effect of PES concentration in the casting solution on physico-chemical characteristics, morphology and performance of membranes in glycerol removal from produced biodiesel was studied. SEM and AFM analysis have been utilized for the membrane morphological characterization. SEM images showed uniform surface for the membranes. AFM analysis revealed that the membrane surface roughness was decreased by increase of polymer concentration. The membrane flux, water content and porosity were also decreased by increase of PES concentration. Moreover, obtained results showed that membrane glycerol rejection and mechanical strength were improved by increase of polymer binder concentration. The prepared membrane with 16%wt PES showed more appropriate performance compared to others.
[References]
  1. Atadashi IM, Abdul-Aziz AR, Sulaiman NMN, Renew. Sust. Energ. Rev., 16, 3456, 2012
  2. Atadashi IM, Aroua MF, Abdul Aziz AR, Sulaiman NMN, J. Membr. Sci., 421-422, 154, 2012
  3. Atadashi IM, Aroua MK, Abdul Aziz AR, Sulaiman NMN, Renew. Sust. Energ. Rev., 15, 5051, 2011
  4. Alves MJ, Nascimento SM, Pereira IG, Martins MI, Cardoso VL, Reis M, Renew. Energy, 58, 15, 2013
  5. Wang Y, Wang XG, Liu YF, Ou SY, Tan YL, Tang SZ, Fuel Process. Technol., 90(3), 422, 2009
  6. Saleh J, Dube MA, Tremblay AY, Fuel Process. Technol., 92(7), 1305, 2011
  7. Saleh J, Marc AYT, Dub A, Fuel Process. Technol., 89, 2260, 2010
  8. Thiam LC, Subhash B, Bioresour. Technol., 99(79), 11, 2008
  9. Atadashi IM, Aroua MK, Aziz AA, Renew. Energy, 36(2), 437, 2011
  10. Jakeria MR, Haseeb ASMA, Renew. Sust. Energ. Rev., 30, 154, 2014
  11. Othman R, Mohammad AW, Ismail M, Salimon J, J. Membr. Sci., 348(1-2), 287, 2010
  12. Berrios M, Martin MA, Chica AF, Martin A, Appl. Energy, 88(11), 3625, 2011
  13. He HY, Gu X, Zhu SL, Comparison of Membrane Extraction with Traditional Extraction Methods for Biodiesel Production, T.U. Department of Chemical Engineering, Ed. (2006).
  14. Cheong S, Polymeric Membrane Application for Biodiesel Transesterification, School of Mechanical and Aerospace Engineering (2009).
  15. Aransiola EF, Ojumu TV, Oyekola OO, Madzimbamuto TF, Ikhu-Omoregbe DIO, Biomass Bioenerg., 61, 276, 2014
  16. Peyravi M, Rahimpour A, Jahanshahi M, Volume, 473, 72, 2015
  17. Gomes MCS, Pereira NC, de Barros STD, J. Membr. Sci., 352(1-2), 271, 2010
  18. Roy S, Ntim SA, Mitra S, Sirkar KK, J. Membr. Sci., 375(1-2), 81, 2011
  19. Minhas FR, Memon S, Bhanger MI, Iqbal N, Mujahid M, Appl. Surf. Sci., 282, 887, 2013
  20. Bondioli P, Bella LD, Eur. J. Lip. Sci. Technol., 107, 153, 2005
  21. Hosseini SM, Jeddi F, Nemati M, Madaeni SS, Moghadassi AR, Desalination, 341, 107, 2014
  22. Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147, 2005
  23. Hosseini SM, Madaeni SS, Khodabakhshi AR, Sep. Sci. Technol., 45(16), 2308, 2010
  24. Sata T, Ion Exchange Membranes: Preparation, Characterization, Modification and Application, The Royal Society of Chemistry, Cambridge, United Kingdom (2004).
  25. Tanaka Y, Ion Exchange Membranes: Fundamentals and Applications, Membrane Science and Technology Series, Elsevier, Netherlands, 12 (2007).
  26. Wu GP, Gan SY, Cui LZ, Xu YY, Appl. Surf. Sci., 254(21), 7080, 2008
  27. Wienk IM, Boom RM, Beerlage MA, Bulte AM, Smolders CA, Strathmann H, J. Membr. Sci., 113(2), 361, 1996
  28. Sotto A, Boromand A, Zhang RX, Luis P, Arsuaga JM, Kim J, Van der Bruggen B, J. Colloid Interface Sci., 363(2), 540, 2011
  29. Rahimpour A, Jahanshahi M, Khalili S, Mollahosseini A, Zirepour A, Rajaeian B, Desalination, 286, 99, 2012
  30. Vatanpour V, Madaeni SS, Moradian R, Zinadini S, Astinchap B, Sep. Purif. Technol., 90, 69, 2012