Issue
Korean Journal of Chemical Engineering,
Vol.32, No.10, 2024-2030, 2015
Effect of conditions of air-lift type reactor work on cadmium adsorption
We investigated cadmium sorption by activated sludge immobilized in 1.5% sodium alginate with 0.5% polyvinyl alcohol. Experiments were conducted in an air-lift type reactor at the constant concentration of biosorbent reaching 5 d.m./dm3, at three flow rates: 0.1, 0.25 and 0.5 V/h, and at three concentrations of the inflowing cadmium solution: 10, 25 and 50mg/dm3. Analyses determined adsorption capacity of activated sludge immobilized in alginate as well as reactor’s work time depending on flow rate and initial concentration of the solution. Results achieved were described with the use of Thomas model. The highest adsorption capacity of the sorbent (determined from the Thomas model), i.e., 200.2mg/g d.m. was obtained at inflowing solution concentration of 50mg/dm3 and flow rate of 0.1V/h, whereas the lowest one reached 53.69mg/g d.m. at the respective values of 10mg/dm3 and 0.1 V/h. Analyses were also carried out to determine the degree of biosorbent adsorption capacity utilization at the assumed effectiveness of cadmium removal - at the breakthrough point (C=0.05*C0) and at adsorption capacity depletion point (C.0.9*C0). The study demonstrated that the effectiveness of adsorption capacity utilization was influenced by both the concentration and flow rate of the inflowing solution. The highest degree of sorbent capacity utilization was noted at inflowing solution concentration of 50mg/dm3 and flow rate of 0.1 V/h, whereas the lowest one at the respective values of 10mg/dm3 and 0.1 V/h. The course of the process under dynamic conditions was evaluated using coefficients of tangent inclination - a, at point C/C0=½. A distinct tendency was demonstrated in changes of tangent slope a as affected by the initial concentration of cadmium and flow rate of the solution. The highest values of a coefficient were achieved at the flow rate of 0.1 V/h and initial cadmium concentration of 50mg/dm3.
[References]
  1. Singh R, Gautam N, Mishra A, Gupta R, Indian J. Pharmacology, 43(3), 246, 2011
  2. Benavides MP, Gallego SM, Tomaro ML, Brazilian J. Plant Physiology, 17(1), 21, 2005
  3. Clemens S, Biochemie, 88(11), 1707, 2006
  4. Kapoor A, Viraraghavan T, Cullimore DR, Bioresour. Technol., 70(1), 95, 1999
  5. Chen D, Ray AK, Chem. Eng. Sci., 56(4), 1561, 2001
  6. Cazon JP, Viera M, Donati E, Guibal E, J. Environ. Manage., 129, 423, 2013
  7. Alluri HK, Ronda SR, Settalluri VS, Bondili JS, Suryanarayana V, Venkateshwar P, African J. Biotechnology, 6(25), 29, 2007
  8. Gopal M, Pakshirajan K, Swaminathan T, Appl. Biochem. Biotechnol., 102.1-6, 227, 2002
  9. Rao GP, Satyaveni S, Ramesh A, Seshaiah K, Murthy KSN, Choudary NV, J. Environ. Manage., 81.3, 265, 2006
  10. Zawierucha I, Kozlowski C, Malina G, IAH Book Series:Selected Papers on Hydrogeology, 17, 79, 2012
  11. Kuczajowska-Zadrozna M, Klimiuk E, Wojnowska-Baryla I, Pol. J. Environ. Stud., 13(2), 161, 2004
  12. Volesky B, Hydrometallurgy, 59(2), 203, 2001
  13. Baba H, Tsuneyama K, Yazaki M, Nagata K, Minamisaka T, Tsuda T, Nomoto K, Hayashi S, Miwa S, Nakajima T, Nakanishi Y, Aoshima K, Imura J, Modern Pathology, 26(9), 1228, 2013
  14. Nguyen VNH, Amal R, Beydoun D, Chem. Eng. Sci., 58(19), 4429, 2003
  15. Farooq U, Kozinski JA, Khan MA, Athar M, Bioresour. Technol., 101(14), 5043, 2010
  16. Butter TJ, Evison LM, Hancock IC, Holland FS, Water Sci. Technol., 38(6), 279, 1998
  17. Mudhoo A, Garg VK, Wang S, Environ. Chem. Lett., 10(2), 109, 2012
  18. SaG Y, Tatar B, Kutsal T, Bioresour. Technol., 89(1), 27, 2003
  19. Filipkowska U, Waraksa K, Adsorption, 14(6), 815, 2008
  20. Cavas L, Karabay Z, Alyuruk H, Dogan H, Demir GK, Chem. Eng. J., 171(2), 2011
  21. Chu KH, J. Hazard. Mater., 177(1), 1006, 2010
  22. Malkoc E, Nuhoglu Y, Chem. Eng. Sci., 61(13), 4363, 2006
  23. Xiao K, Wang X, Huang X, Waite TD, Wen X, J. Membr. Sci., 342(1), 22, 2009
  24. Swamy BY, Chang JH, Ahn H, Lee WK, Chung I, Cellulose, 20(3), 1261, 2013
  25. Mansur HS, Costa HS, Chem. Eng. J., 137(1), 72, 2008
  26. Gulnaz O, Kaya A, Dincer S, J. Hazard. Mater., 134(1), 190, 2006
  27. Song WJ, Pan X, Zhang D, Biotechnol. Biotechnol. Equip., 26(6), 3371, 2012
  28. Trgo M, Medvidovic NV, Peric J, Indian J. Chem. Technol., 18(2), 123, 2011
  29. Deng L, Su Y, Su H, Wang X, Zhu X, Adsorption, 12(4), 267, 2006
  30. Shin WS, Kang K, Kim YK, Environ. Eng. Res., 19(1), 15, 2014
  31. Pino GH, de Mesquita LMS, Torem ML, Pinto GAS, Miner. Eng., 19(5), 380, 2006
  32. Das N, Karthika P, Vimala R, Vinodhin V, Natural Product Radiance, 7(2), 133, 2008
  33. Barron-Zambrano J, Szygula A, Ruiz M, Sastre AM, Guibal E, J. Environ. Manage., 91(12), 2669, 2010