Issue
Korean Journal of Chemical Engineering,
Vol.32, No.10, 2014-2023, 2015
Preparation of reusable conductive activated charcoal plate as a new electrode for industrial wastewater treatment
A conductive activated charcoal plate (ACP) was prepared from a low-cost, abundant, and non-conductive charcoal. The prepared ACP was characterized using N2 adsorption/desorption isotherms, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). Brunauer-Emmett-Teller (BET) surface area of the charcoal and the ACP was 0.58m2 g.1 and 461.67m2 g.1, respectively. The ACP was employed in textile wastewater treatment using electrosorption process. Response surface methodology (RSM) was applied to design the experiments. The decolorization efficiency of 76% at optimum conditions of voltage=450mV, pH=4, and contact time=120 min indicated that the ACP has promising potential to decolorize textile wastewater. Moreover, the results of the kinetic analyses demonstrated that wastewater treatment followed pseudo-first order kinetic model. The ACP electrode could be regenerated and reused effectively at five successive cycles of electrosorption/electrodesorption.
[References]
  1. Hossain MM, Mahmud MI, Parvez MS, Cho HM, Environ. Eng. Res., 18, 157, 2013
  2. Karthikeyan S, Titus A, Gnanamani A, Mandal AB, Sekaran G, Desalination, 281, 438, 2011
  3. Aber S, Salari D, Feiz BA, Water Sci. Technol., 63, 1389, 2011
  4. Mondal MK, Korean J. Chem. Eng., 27(1), 144, 2010
  5. Shirzad-Siboni M, Jafari SJ, Farrokhi M, Yang JK, Environ. Eng. Res., 18, 247, 2013
  6. Ban A, Schafer A, Wendt H, J. Appl. Electrochem., 28(3), 227, 1998
  7. Foo KY, Hameed BH, J. Hazard. Mater., 170(2-3), 552, 2009
  8. Zhan YK, Nie CY, Li HB, Pan LK, Sun Z, Electrochim. Acta, 56(9), 3164, 2011
  9. Hou CH, Huang CY, Desalination, 314, 124, 2013
  10. Huang CC, He JC, Chem. Eng. J., 221, 469, 2013
  11. Asghar HMA, Hussain SN, Sattar H, Roberts EPL, Brown NW, Korean J. Chem. Eng., 31(5), 834, 2014
  12. Ayranci E, Conway BE, J. Electroanal. Chem., 513(2), 100, 2001
  13. Kong Y, Li W, Wang Z, Yao C, Tao Y, Electrochem. Commun., 26, 59, 2013
  14. Han YH, Quan X, Chen S, Zhao HM, Cui CY, Zhao YZ, Sep. Purif. Technol., 50(3), 365, 2006
  15. Zhan Y, Nie C, Li H, Pan L, Sun Z, Phys. Status Solidi A-Appl. Res., 9, 55, 2012
  16. Li H, Lu T, Pan L, Zhang Y, Sun Z, J. Mater. Chem., 19, 6773, 2009
  17. Farmer JC, Bahowick SM, Harrar JE, Fix DV, Martinelli RE, Vu AK, Carroll KL, Energy Fuels, 11(2), 337, 1997
  18. Wang G, Qian BQ, Dong Q, Yang JY, Zhao ZB, Qiu JS, Sep. Purif. Technol., 103, 216, 2013
  19. Association APH, Standard Methods for the Examination of Water and Wastewater, Washington D.C., USA (1989).
  20. Aber S, Sheydaei M, Clean - Soil Air Water, 40, 87, 2012
  21. Brunauer S, Emmett PH, Teller E, J. Am. Chem. Soc., 60, 309, 1938
  22. Lippens BC, de Boer JH, J. Catal., 4, 319, 1965
  23. Barrett EP, Joyner LG, Halenda PP, J. Am. Chem. Soc., 73, 373, 1951
  24. Mikhail RS, Brunauer S, Bodor EE, J. Colloid Interface Sci., 26, 45, 1968
  25. Karthikeyan S, Magthalin CJ, Mandal AB, Sekaran G, RSC Advances, 4, 19183, 2014
  26. Sheydaei M, Aber S, CLEAN - Soil, Air, Water, 41, 890, 2013
  27. Dey S, Mukherjee S, J. Environ. Sci., 25, 698, 2013
  28. Murugesan S, Rajiv S, Thanapalan M, Korean J. Chem. Eng., 26(2), 364, 2009
  29. Chun SY, An SW, Lee SJ, Kim JT, Chang SW, Korean J. Chem. Eng., 31(6), 994, 2014
  30. Afkhami A, Madrakian T, Karimi Z, J. Hazard. Mater., 144(1-2), 427, 2007
  31. Aworn A, Thiravetyan P, Nakbanpote W, J. Anal. Appl. Pyrolysis, 82, 279, 2008
  32. Aber S, Khataee A, Sheydaei M, Bioresour. Technol., 100(24), 6586, 2009
  33. Shi Q, Zhang J, Zhang C, Li C, Zhang B, Hu W, Xu J, Zhao R, J. Environ. Sci., 22, 91, 2010
  34. Karthikeyan S, Anandan C, Subramanian J, Sekaran G, RSC Advances, 3, 15044, 2013
  35. Karthikeyan S, Boopathy R, Gupta VK, Sekaran G, J. Mol. Liq., 177, 402, 2013
  36. Wang ZM, Kanoh H, Kaneko K, Lu GQ, Do D, Carbon, 40, 1231, 2002
  37. Vijayakumar G, Yoo CK, Elango KGP, Dharmendirakumar M, Clean, 38, 202, 2010
  38. Sing KSW, Pure Appl. Chem., 54, 2201, 1982
  39. Karthikeyan S, Kumar MA, Maharaja P, Partheeban T, Sridevi J, Sekaran G, J. Taiwan Inst. Chem. E., 45, 1739, 2014
  40. Martin MJ, Artola A, Balaguer MD, Rigola M, Chem. Eng. J., 94(3), 231, 2003
  41. Runyan WR, Semiconductor Measurements and Instrumentation, McGraw-Hill, New York (1975).
  42. Bansal RC, Goyal M, Activated Carbon Adsorption, CRC Press, Boca Raton, FL (2005).
  43. Karthikeyan S, Sekaran G, Phys. Chem. Chem. Phys., 16, 3924, 2014
  44. Shahrezaei F, Mansouri Y, Zinatizadeh AAL, Akhbari A, Powder Technol., 221, 203, 2012
  45. Rong C, Xien H, J. Colloid Interface Sci., 290(1), 190, 2005
  46. Ho YS, McKay G, Process Biochem., 34(5), 451, 1999
  47. Allen SJ, Gan Q, Matthews R, Johnson PA, J. Colloid Interface Sci., 286(1), 101, 2005
  48. Chen ZL, Song CY, Sun XW, Guo HF, Zhu GD, Desalination, 267(2-3), 239, 2011