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Issue
Korean Journal of Chemical Engineering,
Vol.32, No.7, 1361-1368, 2015
Application of modified Tao-Mason equation of state to refrigerant mixtures
Kiani M, Papari MM, Nowruzian Z, Moghadasi J
In our previous work, we modified the Tao-Mason EOS [1] to predict the volumetric properties of pure refrigerants [2]. In the present study, we have successfully extended the modified Tao-Mason EOS to refrigerant mixtures. The second virial coefficient, B2(T), and the temperature-dependent correction factor α(T) and van der Waals co-volume b(T) were calculated from a two-parameter corresponding-states correlation along with the enthalpy of vaporization and the molar density, both at the normal boiling point. Then the cross parameters B12(T), α12(T), and b12(T), were determined with the help of simple combining rules. The constructed Tao-Mason EOS was employed to predict the densities and vapor pressures of several HFC, hydrocarbons and HFO mixtures. The calculated results were compared with literature data. The overall agreement between our results and literature values is remarkable.
Keywords: Refrigerant; Mixtures; Equation of State; Volumetric Properties; Corresponding States Principle
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