Korean Journal of Chemical Engineering, Vol.32, No.7, 1305-1313, 2015
Effect of the TiO2 phase and loading on oxygen reduction reaction activity of PtCo/C catalysts in proton exchange membrane fuel cells
We investigated the effect of the TiO2 phase, as either pure rutile (TiO2(R)) or a 4 : 1 (w/w) anatase: rutile ratio (TiO2(AR)), and the loading on the activity of PtCo/C catalyst in the oxygen reduction reaction (ORR) in a proton exchange membrane (PEM) fuel cell. The incorporation of the different phases and loading of TiO2 on the PtCo/C catalyst did not affect the alloy properties or the crystalline size of the PtCo/C catalyst, but affected importantly the electrochemical surface area (ESA), conductivity of catalyst layer and the water management ability. The presence of TiO2(AR) at appropriate quantity can decrease the mass transport limitation as well as the ohmic resistance of catalyst layer. As a result, the optimum loading of TiO2(AR) used to incorporated in the layer of PtCo/C catalyst was 0.06mg/cm2. At this content, the TiO2(AR)-PtCo/C catalyst provided the highest current density of 438 mA/cm2 at 0.6V at atmospheric pressure in PEM fuel cell and provided the kinetic current in acid solution of 20.53 mA/cm2. In addition, the presence of TiO2(AR) did not alter the ORR electron pathway of PtCo/C catalyst. The electron pathway of ORR of TiO2(AR)-PtCo/C was still the four-electron pathway.
[References]
Lin JH, Chen WH, Su YJ, Ko TH, Fuel , 87 (12), 2420, 2008
Tang Y, Yuan W, Pan MQ, Li ZT, Chen GQ, Li Y, Appl. Energy , 87 (4), 1410, 2010
Zhang XQ, Guo JC, Chen JC, Energy , 35 (12), 5294, 2010
Bezerra CWB, Zhang L, Liu HS, Lee KC, Marques ALB, Marques EP, Wang HJ, Zhang JJ, J. Power Sources , 173 (2), 891, 2007
Trongchuankij W, Pruksathorn K, Hunsom M, Appl. Energy , 88 (3), 974, 2011
Kocha SS, Electrochemical degradation: Electrocatalyst and support durability, Polymer electrolyte fuel cell degradation. In: Mench MM, Kumbur EC, Nejat Veziroglu T (Eds.) Massachusetts, Elsevier (2011).
Vante NA, Tributsch H, Nature , 323 , 431, 1986
Fernandez JL, Raghuveer V, Manthiram A, Bard AJ, J. Am. Chem. Soc. , 127 (38), 13100, 2005
Bagotsky VS, Fuel cells, Problems and Solution. Chichester, UK, Wiley (2009).
Yongjun F, Nicolas AV, Phys. Status Solidi B , 245 , 1792, 2008
Zhang L, Zhang JJ, Wilkinson DP, Wang HJ, J. Power Sources , 156 (2), 171, 2006
Baresel D, Sarholz W, Scharner P, Bunsen-Ges JS, Phys. Chem. Chem. Phys. , 78 , 608, 1974
Susac D, Sode A, Zhu L, Wong PC, Teo M, Bizzotto D, Mitchell KAR, Parsons PR, Campbell SA, J. Phys. Chem. B , 110 , 10760, 2006
Lee K, Zhang L, Zhang J, Electrochem. Commun. , 9 , 1704, 2007
Zhong H, Zhang H, Liu G, Liang Y, Hu J, Yi B, Electrochem. Commun. , 8 , 707, 2006
Zhong HX, Zhang HM, Liang YM, Zhang JL, Wang MR, Wang XL, J. Power Sources , 164 (2), 572, 2007
Charreteur F, Jaouen F, Ruggeri S, Dodelet JP, Electrochim. Acta , 53 (6), 2925, 2008
Wang X, Lee JS, Zhu Q, Liu L, Wang Y, Dai S, Chem. Mater. , 22 , 2178, 2010
Kim JH, Ishihara A, Mitsushima S, Kamiya N, Ota KI, Chem. Lett. , 36 (4), 514, 2007
Bezerra CWB, Zhang L, Lee KC, Liu HS, Zhang JL, Shi Z, Marques ALB, Marques EP, Wu SH, Zhang JJ, Electrochim. Acta , 53 (26), 7703, 2008
Gojkovic SL, Gupta S, Savinell RF, Electrochim. Acta , 45 (6), 889, 1999
Contamin O, Debiemme-Chouvy C, Savy M, Scarbeck G, J. New Mater Electrochem. Syst. , 3 , 67, 2000
Schulenburg H, Stankov S, Schunemann V, Radnik J, Dorbandt I, Fiechter S, Bogdanoff P, Tributsch H, J. Phys. Chem. B , 107 (34), 9034, 2003
Medard C, Lefevre M, Dodelet JP, Jaouen F, Lindbergh G, Electrochim. Acta , 51 (16), 3202, 2006
Baker R, Wilkinson DP, Zhang JJ, Electrochim. Acta , 53 (23), 6906, 2008
Pylypenko S, Mukherjee S, Olson TS, Atanassov P, Electrochim. Acta , 53 (27), 7875, 2008
Koslowski UI, Abs-Wurmbach I, Fiechter S, Bogdanoff P, J. Phys. Chem. C , 112 , 15356, 2008
Herrmann I, Kramm UI, Fiechter S, Bogdanoff P, Electrochim. Acta , 54 (18), 4275, 2009
Jalan V, Taylor EJ, J. Electrochem. Soc. , 130 , 2299, 1983
Paffett MT, Berry GJ, Gottesfeld S, J. Electrochem. Soc. , 135 , 1431, 1988
Beard BC, Ross PN, J. Electrochem. Soc. , 137 , 3368, 1990
Toda T, Igarashi H, Uchida H, Watanabe M, J. Electrochem. Soc. , 146 , 3750, 1993
Elezovic NR, Babic BM, Radmilovic VR, Vracar LM, Krstajic NV, Electrochim. Acta , 54 (9), 2404, 2009
Bauer A, Song CJ, Ignaszak A, Hui R, Zhang JJ, Chevallier L, Jones D, Roziere J, Electrochim. Acta , 55 (28), 8365, 2010
Huang SY, Ganesan P, Popov BN, Appl. Catal. B: Environ. , 96 (1-2), 224, 2010
Chisaka M, Ishihara A, Ota K, Muramoto H, Electrochim. Acta , 113 , 735, 2013
Limpattayanate S, Hunsom M, J. Solid State Electrochem. , 17 , 1221, 2013
Huang SY, Ganesan P, Popov BN, Appl. Catal. B: Environ. , 102 , 102, 2011
Fugane K, Mori T, Ou DR, Suzuki A, Yoshikawa H, Masuda T, Uosaki K, Yamashita Y, Ueda S, Kobayashi K, Okazaki N, Matolinova I, Matolin V, Electrochim. Acta , 56 (11), 3874, 2011
Vuk AS, Jese R, Orel B, Drazic G, Int. J. Photoenergy , 7 , 163, 2005
Thanasilp S, Hunsom M, Electrochim. Acta , 56 (3), 1164, 2011
Trongchuankij W, Poochinda K, Pruksathorn K, Hunsom M, Renew. Energy , 12 , 2839, 2010
Yin SB, Mu SC, Lv HF, Cheng NAC, Pan M, Fu ZY, Appl. Catal. B: Environ. , 93 (3-4), 233, 2010
Ungar T, Gubieza J, Tichy G, Pantea C, Zerda TW, Compos. Pt. A-Appl. Sci. Manuf. , 36 , 431, 2005
Ra Y, Lee J, Kim I, Bong S, Kima H, J. Power Sources , 187 (2), 363, 2009
Wang ZB, Yin GP, Shi PF, Sun YC, Electrochem. Solid State Lett. , 9 (1), A13, 2006
Lopes T, Antolini E, Gonzalez ER, Int. J. Hydrog. Energy , 33 (20), 5563, 2008
Fujishima A, Hashimoto K, Watanabe T, TiO2 Photocatalysis, Fundamentals and Applications, Tokyo Japan, BKC Inc. (1990).
Eppler AM, Ballard IN, Nelson J, Physica E , 14 , 197, 2002
Pomoni K, Sofianou MV, Georgakopoulos T, Boukos N, Trapalis C, J. Alloy. Compd. , 548 , 194, 2013
Kim J, Lee SM, Srinivasan S, Chamberlin CE, J. Electrochem. Soc. , 142 (8), 2670, 1995
Antolini E, Giorgi L, Pozio A, Passalacqua E, J. Power Sources , 77 (2), 136, 1999
Santiago EI, Isidoro RA, Dresch MA, Matos BR, Linardi M, Fonseca FC, Electrochim. Acta , 54 (16), 4111, 2009
Liu ZL, Guo B, Huang JC, Hong L, Han M, Gan LM, J. Power Sources , 157 (1), 207, 2006
Bard AJ, Faulkner LR, Electrochemical methods: Fundamentals and applications, 2nd Ed. New York, Wiley (2000).
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