About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.32, No.7, 1258-1266, 2015
Synthesis and physicochemical characterization of ZrO2-doped NiMo/Al2O3 nanocatalyst via precipitation and sequential impregnation methods used in hydrodesulfurization of thiophene
Jabbarnezhad P, Haghighi M, Taghavinezhad P
A series of Al2O3-ZrO2 composite with various ZrO2 contents were prepared by precipitation and NiMo was dispersed over them via sequential impregnation. The samples were characterized by XRD, FESEM, EDX, BET, TPR-H2 and FTIR techniques. XRD patterns indicate the homogeneous dispersion of ZrO2 on Al2O3 in small amounts of ZrO2. Comparison of FESEM images implies that with the incorporation of small amounts of ZrO2 (5, 12 and 17 wt%) on Al2O3, the catalyst morphology changed from large ensembles to smaller particles with uniform distribution. According to TPR-H2 profiles, adding ZrO2 increases the reducibility of nanocatalysts. Catalytic activity results showed that the NiMo over Al2O3-ZrO2 composite showed higher hydrodesulfurization activity than that of Al2O3 supported catalyst. The maximum of hydrodesulfurization activity was observed for NiMo/Al2O3-ZrO2 nanocatalyst with 12 wt% of ZrO2 content related to enhanced physicochemical properties.
Keywords: NiMo/Al2O3-ZrO2; Precipitation; Sequential Impregnation; Hydrodesulfurization; Thiophene
[References]
  1. Rashidi F, Sasaki T, Rashidi AM, Kharat AN, Jozani KJ, J. Catal., 299, 321, 2013
  2. Song H, Wang J, Wang ZD, Song HL, Li F, Jin ZS, J. Catal., 311, 257, 2014
  3. Nikulshin PA, Salnikov VA, Mozhaev AV, Minaev PP, Kogan VM, Pimerzin AA, J. Catal., 309, 386, 2014
  4. Aghamohammadi S, Haghighi M, Karimipour S, J. Nanosci. Nanotechnol., 13, 4872, 2013
  5. Khatamian M, Khandar AA, Haghighi M, Ghadiri M, Darbandi M, Powder Technol., 203(3), 503, 2010
  6. Wang DH, Li XG, Qian EKWH, Ishihara A, Kabe T, Appl. Catal. A: Gen., 238(1), 109, 2003
  7. Leliveld RG, Vandillen AJ, Geus JW, Koningsberger DC, J. Catal., 165(2), 184, 1997
  8. Azizi N, Ali SA, Alhooshani K, Kim T, Lee Y, Park JI, Miyawaki J, Yoon SH, Mochida I, Fuel Process. Technol., 109, 172, 2013
  9. Li X, Han D, Xu Y, Liu X, Yan Z, Mater. Lett., 65, 1765, 2011
  10. Fan Y, Shi G, Liu HY, Bao XJ, Fuel, 90(5), 1717, 2011
  11. Huirache-Acuna R, Nava R, Peza-Ledesma CL, Lara-Romero J, Alonso-Nuez G, Pawelec B, Rivera-Munoz EM, Materials, 6, 4139, 2013
  12. Stanislaus A, Marafi A, Rana MS, Catal. Today, 153(1-2), 1, 2010
  13. Valencia D, Klimova T, Catal. Today, 166(1), 91, 2011
  14. Maity SK, Rana MS, Srinivas BN, Bej SK, Dhar GM, Rao TSRP, J. Mol. Catal. A-Chem., 153(1-2), 121, 2000
  15. Jia ML, Afanasiev P, Vrinat M, Appl. Catal. A: Gen., 278(2), 213, 2005
  16. Mazurelle J, Lamonier C, Lancelot C, Payen E, Pichon C, Guillaume D, Catal. Today, 130(1), 41, 2008
  17. Song H, Dai M, Song H, Wan X, Xu X, Zhang C, Wang H, Catal. Commun., 43, 151, 2014
  18. Vissenberg MJ, van der Meer Y, Hensen EJM, de Beer VHJ, van der Kraan AM, van Santen RA, van Veen JAR, J. Catal., 198(2), 151, 2001
  19. Kouzu M, Kuriki Y, Hamdy F, Sakanishi K, Sugimoto Y, Saito I, Appl. Catal. A: Gen., 265(1), 61, 2004
  20. Shang H, Liu C, Xu Y, Qiu J, Wei F, J. Nat. Gas Chem., 15, 203, 2006
  21. Turaga UT, Song CS, Catal. Today, 86(1-4), 129, 2003
  22. Hussain M, Song SK, Ihm SK, Fuel, 106, 787, 2013
  23. Klimova TE, Valencia D, Mendoza-Nieto JA, Hernandez-Hipolito P, J. Catal., 304, 29, 2013
  24. Damyanova S, Centeno MA, Petrov L, Grange P, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 57, 2495, 2001
  25. Damyanova S, Petrov L, Centeno MA, Grange P, Appl. Catal. A: Gen., 224(1-2), 271, 2002
  26. Damyanova S, Grange P, Delmon B, J. Catal., 168(2), 421, 1997
  27. Zhang DQ, Duan AJ, Zhao Z, Wan GF, Gao ZY, Jiang GY, Chi KB, Chuang KH, Catal. Today, 149(1-2), 62, 2010
  28. Li GR, Li W, Zhang MH, Tao KY, Catal. Today, 93-95, 595, 2004
  29. Li GR, Li W, Zhang MH, Tao KY, Appl. Catal. A: Gen., 273(1-2), 233, 2004
  30. Pophal C, Kameda F, Hoshino K, Yoshinaka S, Segawa K, Catal. Today, 39(1-2), 21, 1997
  31. Grzechowiak JR, Wereszczako-Zielinska I, Mrozinska K, Catal. Today, 119(1-4), 23, 2007
  32. Song H, Dai M, Guo YT, Zhang YJ, Fuel Process. Technol., 96, 228, 2012
  33. Vafaeian Y, Haghighi M, Aghamohammadi S, Energy Conv. Manag., 76, 1093, 2013
  34. Ghodrati MS, Haghighi M, Mohammadzadeh JSS, Pourabas B, Pipelzadeh E, Reac. Kin. Mech. Catal., 104, 49, 2011
  35. Khoshbin R, Haghighi M, Asgari N, Mater. Res. Bull., 48(2), 767, 2013
  36. Khoshbin R, Haghighi M, Catal. Sci. Technol., 4, 1779, 2014
  37. Baneshi J, Haghighi M, Jodeiri N, Abdollahifar M, Ajamein H, Energy Conv. Manag., 87, 928, 2014
  38. Allahyari S, Haghighi M, Ebadi A, Hosseinzadeh S, Saeedi HG, React. Kinet. Mech. Catal., 112, 101, 2014
  39. Dominguez JM, Hernandez JL, Sandoval G, Appl. Catal. A: Gen., 197(1), 119, 2000
  40. Liu E, Locke AJ, Frost RL, Martens WN, J. Mol. Catal. A-Chem., 353-354, 95, 2012
  41. Klimova T, Rojas ML, Castillo P, Cuevas R, RamArez J, Microporous Mesoporous Mater., 20, 293, 1998
  42. Al-Daous MA, Ali SA, Fuel, 97, 662, 2012
  43. Rahemi N, Haghighi M, Babaluo AA, Jafari MF, Estifaee P, J. Ind. Eng. Chem., 19(5), 1566, 2013
  44. Khoshbin R, Haghighi M, Chem. Eng. Res. Des., 91(6), 1111, 2013
  45. Saedy S, Haghighi M, Amirkhosrow M, Particuology, 10, 729, 2012
  46. Abbasi Z, Haghighi M, Fatehifar E, Rahemi N, Asia-Pac. J. Chem. Eng., 7, 868, 2012
  47. Sharma A, Kumar S, Budhiraja N, Singh R, Singh M, Adv. App. Sci. Res., 4, 252, 2013
  48. Rahmani F, Haghighi M, Estifaee P, Microporous Mesoporous Mater., 185, 213, 2014
  49. Allahyari S, Haghighi M, Ebadi A, Hosseinzadeh S, Ultrason. Sonochem., 21, 663, 2014
  50. Barrera MC, Escobar J, de los Reyes JA, Cortes MA, Viniegra M, Hernandez A, Catal. Today, 116(4), 498, 2006
  51. Taavoni-Gilan A, Taheri-Nassaj E, Naghizadeh R, Akhondi H, Ceram. Int., 36, 1147, 2010
  52. Sohn JR, Chun EW, Pae YI, Bull. Korean Chem. Soc., 24, 1785, 2003
  53. Kagami N, Advances in HDS catalysts design: relation between catalyst structure and feed composition, Delft University of Technology, Netherlands (2006).
  54. Valencia D, Garcia-Cruz I, Klimova T, Effect of citrate addition in NiMo/SBA-15 catalysts on selectivity of DBT hydrodesulfurization, In Studies in Surface Science and Catalysis, Gaigneaux EM, M.D. S. H. P. A. J. J. A. M, Ruiz P, Eds., Elsevier, 175, 529 (2010).
  55. Wang HM, Iglesia E, J. Catal., 273(2), 245, 2010
[Cited By]
  1. Yin C, Wang Y, Korean Journal of Chemical Engineering, 34(4), 1004, 2017
  2. Hong EP, Baek SW, Shin M, Suh YW, Shin CH, Journal of Industrial and Engineering Chemistry, 54, 137, 2017
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.