About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.32, No.2, 206-215, 2015
Quaternary Pt2Ru1Fe1M1/C (M=Ni, Mo, or W) catalysts for methanol electro-oxidation reaction
Jeon MK, Lee KR, Jeon HJ, McGinn PJ, Kang KH, Park GI
Quaternary Pt2Ru1Fe1M1/C (M=Ni, Mo, or W) catalysts were investigated for the methanol electro-oxidation reaction (MOR). Electrocatalytic activities of the quaternary catalysts for CO electro-oxidation were studied via CO stripping experiments, and the Pt2Ru1Fe1Ni1/C and Pt2Ru1Fe1W1/C catalysts exhibited lowered on-set potential compared to that of a commercial PtRu/C catalyst. MOR activities of the quaternary catalysts were determined by linear sweep voltammetry (LSV) experiments, and the Pt2Ru1Fe1W1/C catalyst outperformed the commercial PtRu/C catalyst by 170 and 150% for the mass and specific activities, respectively. X-ray photoelectron spectroscopy (XPS) was employed to analyze surface oxidation states of constituent atoms, and it was identified that the structure of the synthesized catalysts are close to a nano-composite of Pt and constituent metal hydroxides and oxides. In addition, the XPS results suggested that the bi-functional mechanism accounts for the improved performance of the Pt2Ru1Fe1Ni1/C and Pt2Ru1 Fe1W1/C catalysts.
Keywords: Methanol Electro-oxidation Reaction; Direct Methanol Fuel Cell; Electrocatalyst; X-ray Photoelectron Spectroscopy; CO Electro-oxidation
[References]
  1. Arico AS, Srinivasan S, Antonucci V, Fuel Cells, 1, 133, 2001
  2. Watanabe M, Motoo S, J. Electroanal. Chem., 229, 395, 1987
  3. Markovic NM, Gasteiger HA, Ross PN, Jiang XD, Villegas I, Weaver MJ, Electrochim. Acta, 40(1), 91, 1995
  4. Chrzanowski W, Wieckowski A, Langmuir, 14(8), 1967, 1998
  5. Petrii OA, J. Solid State Electrochem., 12, 609, 2008
  6. Choi JH, Park KW, Kwon BK, Sung YE, J. Electrochem. Soc., 150, 973, 2003
  7. Wang ZB, Yin GP, Shi PF, Sun YC, Electrochem. Solid-State Lett., 9, 13, 2006
  8. Liu JY, Cao JY, Huang QH, Li XW, Zou ZQ, Yang H, J. Power Sources, 175(1), 159, 2008
  9. Ribeiro VA, Correa OV, Neto AO, Linardi M, Spinace EV, Appl. Catal. A: Gen., 372(2), 162, 2010
  10. Jeon MK, Lee KR, Daimon H, Nakahara A, Woo SI, Catal. Today, 132(1-4), 123, 2008
  11. Cooper JS, McGinn PJ, J. Power Sources, 163(1), 330, 2006
  12. Lima A, Coutanceau C, Leger JM, Lamy C, J. Appl. Electrochem., 31(4), 379, 2001
  13. Umeda M, Ojima H, Mohamedi M, Uchida I, J. Power Sources, 136(1), 10, 2004
  14. Goetz M, Wendt H, J. Appl. Electrochem., 31(7), 811, 2001
  15. Roth C, Goetz M, Fuess H, J. Appl. Electrochem., 31(7), 793, 2001
  16. Antolini E, Appl. Catal. B: Environ., 74(3-4), 324, 2007
  17. Lamy C, Lima A, LeRhun V, Delime F, Coutanceau C, Leger JM, J. Power Sources, 105(2), 283, 2002
  18. Demirci UB, J. Power Sources, 173(1), 11, 2007
  19. Ralph TR, Hogarth MP, Platin. Met. Rev., 46, 3, 2002
  20. Urian RC, Gulla AF, Mukerjee S, J. Electroanal. Chem., 554, 307, 2003
  21. Lopes PP, Feitas KS, Ticianelli EA, Electrocatal., 1, 200, 2010
  22. Ehteshami SMM, Chan SH, Electrochim. Acta, 93, 334, 2013
  23. Jeon MK, Won JY, Lee KR, Woo SI, Electrochem. Commun., 9, 2163, 2007
  24. Lee KR, Jeon MK, Woo SI, Appl. Catal. B: Environ., 91(1-2), 428, 2009
  25. Schmidt TJ, Gasteiger HA, Stab GD, Urban PM, Kolb DM, Behm RJ, J. Electrochem. Soc., 145(7), 2354, 1998
  26. Antolini E, Cardellini F, J. Alloys Compd., 315, 118, 2001
  27. Watanabe K, Trans. Jpn. Inst. Met., 29, 80, 1988
  28. Leroux C, Cadeville MC, Pierron-Bohnes V, Inden G, Hinz F, J. Phys. F: Met. Phys., 18, 2033, 1988
  29. Raub E, Mahler W, Z. Metallkd., 46, 210, 1955
  30. Luo HL, J. Less Common Met., 156, 299, 1968
  31. Rolison DR, Hagans PL, Swider KE, Long JW, Langmuir, 15(3), 774, 1999
  32. Long JW, Stroud RM, Swider-Lyons KE, Rolison DR, J. Phys. Chem. B, 104(42), 9772, 2000
  33. Jeon MK, Lee KR, Jeon HJ, Woo SI, J. Appl. Electrochem., 39(9), 1503, 2009
  34. He CZ, Kunz HR, Fenton JM, J. Electrochem. Soc., 144(3), 970, 1997
  35. Jeon MK, Daimon H, Lee KR, Nakahara A, Woo SI, Electrochem. Commun., 9, 2692, 2007
  36. Camara GA, Giz MJ, Paganin VA, Ticianelli EA, J. Electroanal. Chem., 537(1-2), 21, 2002
  37. Kwok RWM, XPS peak fitting program for WIN95/98 XPSPEAK version 4.1, Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong, 2000
  38. Watanabe M, Igarashi H, Fujino T, Electrochem., 6, 1194, 1999
  39. Watanabe M, Zhu YM, Uchida H, J. Phys. Chem. B, 104(8), 1762, 2000
  40. Jeon MK, Won JY, Woo SI, Electrochem. Solid-State Lett., 10, 23, 2007
  41. Kennedy BJ, Smith AW, J. Electroanal. Chem., 293, 103, 1990
  42. Roine A, Outokumpu HSC chemistry for windows, Pori, Finland, 2002
  43. Manoharan R, Goodenough GB, J. Mater. Chem., 2, 875, 1992
  44. Park KW, Choi JH, Kwon BK, Lee SA, Sung YE, Ha HY, Hong SA, Kim H, Wieckowski A, J. Phys. Chem. B, 106(8), 1869, 2002
  45. Tsiouvaras N, Pena MA, Fierro JLG, Pastor E, Martinez-Huerta MV, Catal. Today, 158(1-2), 12, 2010
  46. Ioroi T, Yasuda K, Siroma Z, Fujiwara N, Miyazaki Y, J. Electrochem. Soc., 150, 1225, 2003
  47. Liu Z, Hu JE, Wang Q, Gaskell K, Frenkel AI, Jackson GS, Eichhorn B, J. Am. Chem. Soc., 131(20), 6924, 2009
  48. Ma LA, Zhao XA, Si FZ, Liu CP, Liao JH, Liang LA, Xing W, Electrochim. Acta, 55(28), 9105, 2010
  49. Teliz E, Diaz V, Perez I, Corengia M, Zinola CF, Int. J. Hydrog. Energy, 37(19), 14761, 2012
  50. Jeon MK, Lee KR, Woo SI, Korean J. Chem. Eng., 26(4), 1028, 2009
  51. Wang ZB, Zuo PJ, Yin GP, J. Alloys Compd., 479, 395, 2009
  52. Micoud F, Maillard F, Bonnefont A, Job N, Chatenet M, Phys. Chem. Chem. Phys., 12, 1182, 2010
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.