Korean Journal of Chemical Engineering, Vol.32, No.1, 168-177, 2015
Measurement and correlation of excess molar volumes for mixtures of 1-propanol and aromatic hydrocarbons
Excess molar volumes (Vm E ) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The Vm E values, for an equimolar composition, vary in the order: benzene>toluene~m-xylene>o-xylene>p-xylene. The Vm E data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the Vm E values for systems with s-shaped Vm E versus x1 graph, the Vm E values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures.
[References]
Ancillotti F, Fattore V, Fuel Process. Technol. , 57 (3), 163, 1998
Karabektas M, Ergen G, Hosoz M, Fuel , 115 , 855, 2014
Kim D, Kim S, Oh S, No SY, Fuel , 125 , 36, 2014
Karavalakis G, Short D, Vu D, Villela M, Asa-Awuku A, Durbin TD, Fuel , 128 , 410, 2014
Li RN, Wang Z, Ni PY, Zhao Y, Li MD, Li LL, Fuel , 128 , 180, 2014
Foong TM, Morganti KJ, Brear MJ, da Silva G, Yang Y, Dryer FL, Fuel , 115 , 727, 2014
http://www.epa.gov/otaq/fuels/gasolinefuels/winterprograms/index.htm.
Chan QN, Bao YM, Kook S, Fuel , 130 , 228, 2014
Mejia A, Segura H, Cartes M, Fuel , 116 , 183, 2014
Sastry SS, Babu S, Vishwam T, Parvateesam K, Tiong HS, Physica B: Condensed Matter , 420 , 40, 2013
Kumar S, Cho JH, Park J, Moon I, Renewable and Sustainable Energy Reviews , 22 , 46, 2013
Hwang IC, Park SJ, Han KJ, In SJ, J. Ind. Eng. Chem. , 18 (1), 499, 2012
Singh PP, Maken S, Pure Appl. Chem. , 66 , 449, 1994
Kumar S, Maken A, Agarwal S, Maken S, J. Mol. Liq. , 155 , 115, 2010
Rani M, Maken S, J. Ind. Eng. Chem. , 18 (5), 1694, 2012
Redlich O, Kister AT, Ind. Eng. Chem. , 40 , 345, 1948
Riddick JA, Bunger WB, Sakano TK, Organic Solvents, Physical properties and methods of purification, 4th Ed. Wiley, New York, 1986
Vogel AI, A Text Book of Practical Organic Chemistry, 4th Ed., ELBS Longman, London, 1978
Yadav BL, Maken S, Kalra KC, Singh KC, J. Chem. Thermodyn. , 25 , 1345, 1993
Weissenberger A, Physical Methods of Organic Chemistry, Interscience, New York, 1959
Zarei HA, Jalili F, J. Chem. Thermodyn. , 39 (1), 55, 2007
Zarei HA, Asadi S, Iloukhani H, J. Mol. Liq. , 141 , 25, 2008
Iloukhani H, Samiey B, Moghaddasi MA, J. Chem. Thermodyn. , 38 (2), 190, 2006
Park SJ, Han KJ, Gmehling J, Fluid Phase Equilib. , 200 (2), 399, 2002
George J, Sastry NV, J. Chem. Thermodyn. , 35 (11), 1837, 2003
Aralaguppi MI, Jadar CV, Aminabhavi TM, J. Chem. Eng. Data , 44 , 446, 1999
George J, Sastry NV, J. Chem. Eng. Data , 48 (4), 977, 2003
Kumaran MK, McGlashan ML, J. Chem. Thermodyn. , 9 , 259, 1977
Gupta V, Maken S, Kalra KC, Singh KC, Indian J. Chem. , 35 , 508, 1996
Maken S, Deshwal BR, Chadha R, Anu, Singh KC, Kim H, Park JW, Fluid Phase Equilib. , 235 (1), 42, 2005
Kier LB, in Physico-chemical properties of drugs, Yalkowski SH, Sinkula AA, Valvani SC Eds., Marcel Dekker, 1980
Harary F, Graph theory. Addison Wesley, Reading, MA, 1969
Balaban AT, Chemical applications of graph theory, Academic Press, London, 1976
Rouvray DH, Reviews , 4 , 173, 1971
Kier LB, Hall LH, Molecular connectivity in chemistry and drug research, Academic Press, New York, 1976
Gahlyan S, Rani M, Maken S, J. Mol. Liq. , 199 , 42, 2014
Patterson D, Delmas G, Discussions of the Faraday Society , 49 , 98, 1970
Flory PJ, J. Am. Chem. Soc. , 87 , 1833, 1965
Abe A, Flory PJ, J. Am. Chem. Soc. , 87 , 1838, 1965
Torres RB, Francesconi AZ, Volpe PLO, J. Mol. Liq. , 110 , 81, 2004
Rani M, Maken S, Korean J. Chem. Eng. , 30 (8), 1636, 2013
Rani M, Maken S, Thermochim. Acta , 559 , 98, 2013
Rani M, Agarwal S, Lahot P, Maken S, J. Ind. Eng. Chem. , 19 (5), 1715, 2013
Iloukhani H, Almasi M, Thermochim. Acta , 495 (1-2), 139, 2009
Gahlyan S, Rani M, Maken S, Kwon H, Tak K, Moon I, J. Ind. Eng. Chem., DOI: 10.1016/j.jiec.2014.08.032., 2014
Rani M, Gahlyan S, Om H, Verma N, Maken S, J. Mol. Liq. , 194 , 100, 2014
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