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Issue
Korean Journal of Chemical Engineering,
Vol.31, No.11, 2101-2107, 2014
Reversible addition-fragmentation chain transfer polymerization of vinyl acetate and vinyl pivalate in supercritical carbon dioxide
Pham QL, Haldorai Y, Nguyen VH, Kang CK, Shim JJ
Two highly supercritical CO2-soluble, poly(vinyl acetate) (PVAc)-based macro-reversible addition-fragmentation chain transfer (RAFT) agents were synthesized. The RAFT agents were used for the first time in RAFT/macromolecular design via the interchange of xanthates (MADIX) and polymerization of vinyl acetate (VAc) and vinyl pivalate (VPi) in supercritical carbon dioxide (scCO2). A homopolymer PVAc and a block copolymer PVAc-b-PVPi made by RAFT/MADIX polymerization were characterized, and the effects of time and RAFT agents on polymerization were examined. For the 8.4 wt% RAFT agent in VAc, the molecular mass (Mn) of homopolymer PVAc was 26,000 g mol^(-1) and PDI was 1.35. For the copolymerization of VPi using 9.8 wt% PVAc-RAFT agent in VPi for 24 h, the Mn and PDI of PVAc-b-PVPi reached 32,400 g mol^(-1) and 1.42, respectively. These results suggest that the polydispersity can be controlled during the clean production of PVAc and PVPi by RAFT/MADIX polymerization in scCO2.
Keywords: Poly(Vinyl Acetate); Poly(Vinyl Pivalate); Block Copolymer; RAFT Polymerization; Reversible Addition-fragmentation Chain Transfer Polymerization; Supercritical Carbon Dioxide
[References]
  1. Lyoo WS, Kwak JW, Choi KH, Noh SK, J. Appl. Polym. Sci., 94(6), 2356, 2004
  2. Desimone JM, Maury EE, Menceloglu YZ, Mcclain JB, Romack TJ, Combes JR, Science, 265(5170), 356, 1994
  3. Park JY, Shim JJ, J. Supercrit. Fluids, 27(3), 297, 2003
  4. Cooper AI, J. Mater. Chem., 10, 207, 2000
  5. Wood CD, Cooper AI, Annu. Rev. Nano Res., 2, 377, 2008
  6. Ryan J, Aldabbagh F, Zetterlund PB, Okubo M, Polymer, 46(23), 9769, 2005
  7. McHale R, Aldabbagh F, Zetterlund PB, Minami H, Okubo M, Macromolecules, 39(20), 6853, 2006
  8. Aldabbagh F, Zetterlund PB, Okubo M, Macromolecules, 41(7), 2732, 2008
  9. Aldabbagh F, Zetterlund PB, Okubo M, Eur. Polym. J., 44, 4037, 2008
  10. Xia JH, Johnson T, Gaynor SG, Matyjaszewski K, DeSimone J, Macromolecules, 32(15), 4802, 1999
  11. Minami H, Kagawa Y, Kuwahara S, Shigematsu J, Fujii S, Okubo M, Des. Monomers Polym., 7, 553, 2004
  12. Grignard B, Jerome C, Calberg C, Jerome R, Wang W, Howdle SM, Detrembleur C, Chem. Commun., 314, 2008
  13. Thurecht KJ, Gregory AM, Wang WX, Howdle SM, Macromolecules, 40(9), 2965, 2007
  14. Gregory AM, Thurecht KJ, Howdle SM, Macromolecules, 41(4), 1215, 2008
  15. Zong M, Thurecht KJ, Howdle SM, Chem. Commun., 5942, 2008
  16. Zetterlund PB, Aldabbagh F, Okubo M, J. Polym. Sci. A: Polym. Chem., 47(15), 3711, 2009
  17. Benaglia M, Chen M, Chong YK, Moad G, Rizzardo E, Thang SH, Macromolecules, 42(24), 9384, 2009
  18. Gody G, Maschmeyer T, Zetterlund PB, Perrier S, Nat. Commun., DOI:10.1038/ncomms3505., 2013
  19. Wong KH, Davis TP, Bamer-Kowollik C, Stenzel MH, Polymer, 48(17), 4950, 2007
  20. Boisse S, Rieger J, Di-Cicco A, Albouy PA, Bui C, Li MH, Charleux B, Macromolecules, 42(22), 8688, 2009
  21. Repollet-Pedrosa MH, Weber RL, Schmitt AL, Mahanthappa MK, Macromolecules, 43(19), 7900, 2010
  22. Lipscomb CE, Mahanthappa MK, Macromolecules, 42(13), 4571, 2009
  23. Stenzel MH, Cummins L, Roberts GE, Thomas PD, Vana P, Barner-Kowollik C, Macromol. Chem. Phys., 204, 1160, 2003
  24. Barner-Kowollik C, Handbook of RAFT polymerization, Wiley-VCH, Weinheim, 2008
  25. Destarac M, Charmot D, Franck X, Zard SZ, Macromol. Rapid Commun., 21(15), 1035, 2000
  26. Lee H, Pack JW, Wang WX, Thurecht KJ, Howdle SM, Macromolecules, 43(5), 2276, 2010
  27. Girard E, Tassaing T, Marty JD, Destarac M, Polym. Chem., 2, 2222, 2011
  28. Girard E, Tassaing T, Camy S, Condoret JS, Marty JD, Destarac M, J. Am. Chem. Soc., 134(29), 11920, 2012
  29. Girard E, Tassaing T, Ladaviere C, Marty JD, Destarac M, Macromolecules, 45(24), 9674, 2012
  30. Moad G, Rizzardo E, Thang SH, Aust. J. Chem., 58, 379, 2005
  31. Canelas DA, Betts DE, DeSimone JM, Yates MZ, Johnston KP, Macromolecules, 31(20), 6794, 1998
  32. Shen Z, McHugh MA, Xu J, Belardi J, Kilic S, Mesiano A, Bane S, Karnikas C, Beckman E, Enick R, Polymer, 44(5), 1491, 2003
  33. Raveendran P, Wallen SL, J. Am. Chem. Soc., 124(25), 7274, 2002
  34. Lee H, Terry E, Zong M, Arrowsmith N, Perrier S, Thurecht KJ, Howdle SM, J. Am. Chem. Soc., 130(37), 12242, 2008
  35. Bamford CH, Dyson RW, Eastmond GC, Polymer, 10, 885, 1969
  36. Guan Z, Combes JR, Menceloglu YZ, Desimone JM, Macromolecules, 26, 2663, 1993
  37. Simms RW, Davis TP, Cunningham MF, Macromol. Rapid Commun., 26(8), 592, 2005
  38. Russum JP, Barbre ND, Jones CW, Schork FJ, J. Polym. Sci. A: Polym. Chem., 43(10), 2188, 2005
  39. Pham QL, Nguyen VH, Haldorai Y, Shim JJ, Korean J. Chem. Eng., 30(5), 1153, 2013
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