| Issue |
Korean Journal of Chemical Engineering,
Vol.31, No.11, 2051-2056, 2014
Vol.31, No.11, 2051-2056, 2014
Adsorption and photodegradation of methylene blue on TiO2-halloysite adsorbents
TiO2-halloysite (TiO2-HNT) composites were fabricated by depositing anatase TiO2 on the halloysite (HNT) surfaces with calcination treatment at 100, 200, 300 and 500 ℃. The obtained composites were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) and X-Ray diffraction (XRD). HNT was attached with TiO2 particles or clusters in sizes of 10-30 nm. With the increasing of calcination temperature, the crystalline of anatase became more perfect, but the structure of HNT could be destroyed at 500 ℃. The adsorption and photodegradation of methylene blue (MB) by TiO2-HNTs were investigated. The kinetic adsorption fit the pseudo second-order, and the isotherm data followed the Langmuir model. The maximum adsorption capacities of MB were in the range of 38.57 to 54.29 mg/g. TiO2-HNTs exhibited an efficient photocatalytic activity in the decomposition of MB. For TiO2-HNT calcined at 300 ℃, 81.6% MB were degraded after 4 h treatment of UV irradiation.
[References]
- Belkassa K, Bessaha F, Marouf-Khelifa K, Batonneau-Gener I, Comparot J, Khelifa A, Colloids Surf., A, 421, 26, 2013
- Gong JL, Wang B, Zeng GM, Yang CP, Niu CG, Niu QY, Zhou WJ, Liang Y, J. Hazard. Mater., 164(2-3), 1517, 2009
- Crini G, Bioresour. Technol., 97(9), 1061, 2006
- Zhao MF, Liu P, Micropor. Mesopor. Mater., 112, 419, 2008
- Zhang AB, Pan L, Zhang HY, Liu ST, Ye Y, Xia MS, Chen XG, Colloids Surf., A, 396, 182, 2012
- Wang JH, Zhang XA, Zhang B, Zhao YF, Zhai R, Liu JD, Chen RF, Desalination, 259(1-3), 22, 2010
- Massaro M, Riela S, Cavallaro G, Gruttadauria M, Milioto S, Noto R, Lazzara G, J. Organomet. Chem., 749, 410, 2014
- Shamsi MH, Geckeler KE, Nanotechnology, 19, 075604, 2008
- Luo P, Zhao YF, Zhang B, Liu JD, Yang Y, Liu JF, Water Res., 44, 1489, 2010
- Nakata K, Fujishima A, J. Photochem. Photobiol. C, 13, 169, 2012
- Zhang YL, Guo YD, Zhang GK, Gao YY, Appl. Clay Sci., 51, 335, 2011
- Papoulis D, Komarneni S, Panagiotaras D, Stathatos E, Toli D, Christoforidis KC, Fernandez-Garcia M, Li HH, Yin S, Sato T, Katsuki H, Appl. Catal. B: Environ., 132, 416, 2013
- Wang RJ, Jiang GH, Ding YW, Wang Y, Sun XK, Wang XH, Chen WX, ACS Appl. Mater. Inter., 3, 4154, 2011
- Sookhakian M, Amin YM, Basirun WJ, Appl. Clay Sci., 283, 668, 2013
- Zhang Y, Fu LJ, Myang H, Colloids Surf., A, 414, 115, 2012
- Tierrablanca E, Romero-Garcia J, Roman P, Cruz-Silva R, Appl. Catal. A: Gen., 381(1-2), 267, 2010
- Zhang Y, Barber A, Maxted J, Lowe C, Smith R, Li TZ, Prog. Org. Coat., 76, 131, 2013
- Liu L, Wan YZ, Xie YD, Zhai R, Zhang B, Liu JD, Chem. Eng. J., 187, 210, 2012
- Wu DL, Zheng PW, Chang PR, Ma XF, Chem. Eng. J., 174(1), 489, 2011
- Xie YF, Qian DY, Wu DL, Ma XF, Chem. Eng. J., 168(2), 959, 2011
- Bulut Y, Aydin H, Desalination, 194(1-3), 259, 2006
- Wang JM, Li C, Zhuang H, Zhang JH, Food Control, 34, 372, 2013
[Cited By]
- He W, Chen Y, Zhang W, Hu C, Wang J, Wang P, Korean Journal of Chemical Engineering, 33(1), 170, 2016
- Wang X, Chen Y, Zhang W, He W, Wang J, Chen B, Korean Journal of Chemical Engineering, 33(12), 3504, 2016
- Wang X, Chen Y, Zhang W, He W, Wang J, Chen B, Korean Journal of Chemical Engineering, 33(12), 3504, 2016
- Wu D, Li J, Guan J, Liu C, Zhao X, Zhu Z, Ma C, Huo P, Li C, Yan Y, Journal of Industrial and Engineering Chemistry, 64, 206, 2018
- Somsesta N, Piyamawadee C, Sricharoenchaikul V, Aht-Ong D, Korean Journal of Chemical Engineering, 37(11), 1999, 2020
- Sundar R, Mohan SK, Vishvanathperumal S, Polymer(Korea), 46(6), 728, 2022
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