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Issue
Korean Journal of Chemical Engineering,
Vol.31, No.8, 1480-1489, 2014
Influence of thermally induced, dehydroxylated nanoclay on polymer nanocomposites
Pandey P, Mohanty S, Nayak SK
This work reports a novel approach towards a chemical-free treatment of nanoclay through extensive thermal exposure. Dehydroxylation at high temperature was utilized to enhance the influence of nanoclay on the properties of polymer. The effect of this treatment of nanoclay, on the polymer properties, with reference to Polypropylene (PP) has been investigated. The FTIR spectra revealed the successful removal of water from the intergallery spacing of the nanoclay. The maintained structural configuration of the clay was confirmed using WAXD pattern. The uniform dispersion and exfoliation of thermally treated clay layers inside the polymer matrix was confirmed through enhanced mechanical properties. Improved crystallization properties, thermal stability and flame retardant characteristic were also noticed in the nanocomposites reinforced with thermally dehydroxylated clay. This study revealed that the dehydroxylation approach of modification of nanoclay may provide much enhanced properties of polymer, without involvement of any chemical for modification.
Keywords: Chemical Free; Thermal; Dehydroxylation; Mechanical Properties
[References]
  1. Alexandre M, Dubois P, Mater. Sci. Eng., 28, 1, 2000
  2. Giannelis EP, Adv. Mater., 8(1), 29, 1996
  3. Lei SG, Hoa SV, Thon-That MT, Compos. Sci. Technol., 66, 1274, 2006
  4. Fuad MYA, Hanim H, Zarina R, Ishak ZAM, Hassan A, Exp. Polym. Lett., 4, 611, 2010
  5. Ray SS, Okamoto M, Prog. Polym. Sci, 28, 1539, 2003
  6. Gianelli W, Ferrara G, Camino G, Pellegatti G, Rosenthal J, Trombini RC, Polymer, 46(18), 7037, 2005
  7. Liu XH, Wu QJ, Polymer, 42(25), 10013, 2001
  8. Yao HY, Zhu J, Morgan AB, Wilkie CA, Polym. Eng. Sci., 42(9), 1808, 2002
  9. Nese A, Sen S, Tasdelen MA, Nugay N, Yagci Y, Macromol. Chem. Phys., 207, 820, 2006
  10. Cui L, Dirnitri MKB, Christopher WBB, Hunter DL, Yoon PJ, Paul DR, Polymer, 49(17), 3751, 2008
  11. Mittal V, Thermally stable flame retardant polymer nanocomposites, Cambridge University Press, United Kingdom (2011).
  12. Chrissopoulou K, Altintzi I, Andrianaki I, Shemesh R, Retsos H, Giannelis EP, Anastasiadis SH, J. Polym. Sci. B: Polym. Phys., 46(24), 2683, 2008
  13. Chafidz A, Ali I, Mohsin MEA, Elleithy R, Zahrani SA, J. Polym. Res., 19, 9906, 2012
  14. Rohlmann CO, Failla MD, Quinzani LM, Polymer, 47(22), 7795, 2006
  15. Zhou Z, Wang SF, Lu L, Zhang Y, Zhang YX, J. Polym. Sci. B: Polym. Phys., 45(13), 1616, 2007
  16. Lee SY, Kim SJ, J. Colloid Interface Sci., 248(2), 231, 2002
  17. He XF, Yang J, Zhu LC, Wang B, Sun GP, Lv PF, Phang IY, Liu TX, J. Appl. Polym. Sci., 102(1), 542, 2006
  18. Lopez-Quintanilla ML, Sanchez-Valdes S, de Valle LFR, Miranda RG, Polym. Bull., 57(3), 385, 2006
  19. Lee JW, Lim YT, Park OO, Polym. Bull., 45(2), 191, 2000
  20. Karakassides MA, Gournis D, Petridis D, Clay Min., 34, 429, 1999
  21. Bergaya F, Theng BKG, Lagaly G, Handbook of clay science, Elsevier, Amsterdam (2006).
  22. Khunova V, Zamorsky Z, Polym. -Plast. Technol. Eng., 32, 289, 1999
  23. Mohanty S, Nayak SK, Polym. Compos., 28, 153, 2007
  24. Szazdi I, Abranyi A, Pukanszky B, Vancso GJ, Macromol. Mater. Eng., 291, 858, 2006
  25. Van Groos AFK, Guggenheim S, Am. Mineral., 74, 627, 1989
  26. Xu WB, Liang GD, Wang W, Tang SP, He PS, Pan WP, J. Appl. Polym. Sci., 88(14), 3225, 2003
  27. Raka L, Bogoeva-Gaceva G, Loos J, J. Therm. Anal. Calorim., 100, 629, 2010
  28. Zhang KL, Wang LX, Wang F, Wang GJ, Li ZB, J. Appl. Polym. Sci., 91(4), 2649, 2004
  29. D'Amico DA, Manfredi LB, Cyras VP, Thermochim. Acta, 544, 47, 2012
  30. Marco C, Ellis G, Gomez MA, Arribas JM, J. Appl. Polym. Sci., 88(9), 2261, 2003
  31. Dogan F, Polypropylene, InTech. Sd., Croatia (2012).
  32. Naffakh M, Martin Z, Marco C, Gomez MA, Jimenez I, Thermochim. Acta, 472(1-2), 11, 2008
  33. Furlan LG, Ferreira CI, Dal Castel C, Santos KS, Mello AC, Liberman SA, Oviedo MAS, Mauler RS, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 528, 6715, 2011
  34. Navratilova Z, Wojtowicz P, Vaculikova L, Sugarkova V, Acta Geodyn. Geomater., 147, 59, 2007
  35. Karakassides MA, Gournis D, Petridis D, Clay Min., 34, 438, 1999
  36. Liu W, Hoa SV, Pugh M, Compos. Sci. Technol., 65, 2364, 2005
  37. Kusmono, Wildan MW, Ishak ZAM, Int. J. Polym. Sci., 2013
  38. Inceoglu AB, Yilmazer U, Polym. Eng. Sci., 43(3), 661, 2003
  39. Garces J, Moll DJ, Bicerano J, Fibiger R, McLeod DG, Adv. Mater., 12, 1839, 2000
  40. Manias E, Touny A, Wu L, Strawhecker K, Lu B, Chung TC, Chem. Mater., 13, 3516, 2001
  41. Olewnik E, Garman K, Czerwinski W, J. Therm. Anal. Calorim., 101, 323, 2012
  42. Theng BKG, Formation and properties of clay-polymer complex, Elsevier, Amsterdam (1979).
  43. Araujo EM, Barbosa R, Morais CRS, Soledade LEB, Souza AG, Vieira MQ, J. Therm. Anal. Calorim., 90, 841, 2007
  44. Pascual J, Fages E, Fenollar O, Garcia D, Balart R, Polym. Bull., 62(3), 367, 2009
  45. Ding C, Jia D, He H, Guo B, Hong H, Polym. Test, 24, 94, 2005
  46. Benerjee S, Joshi M, Ghosh AK, J. Appl. Polym. Sci., DOI:10.1002/App.39590., 2013
  47. Ma H, Tong L, Xu Z, Fang Z, Nanotechnology, 18, 375602, 2007
  48. Jash P, Wilkie CA, Polym. Degrad. Stabil., 88, 401, 2005
  49. Sahoo PK, Samal R, Polym. Degrad. Stabil., 92, 1700, 2007
[Cited By]
  1. Thenepalli T, Ahn YJ, Han C, Ramakrishna C, Ahn JW, Korean Journal of Chemical Engineering, 32(6), 1009, 2015
  2. Kim D, Ock HG, Ahn KH, Lee SJ, Korean Chemical Engineering Research, 53(6), 709, 2015
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