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Issue
Korean Journal of Chemical Engineering,
Vol.31, No.8, 1368-1376, 2014
Presulfidation and activation mechanism of Mo/Al2O3 catalyst sulfided by ammonium thiosulfate
Tang M, Ge H, Fan W, Wang G, Lyu Z, Li X
Mo/Al2O3 catalyst was presulfided with (NH4)2S2O3 to elucidate presulfidation and activation mechanism. It is illustrated that the Mo oxide is firstly partially sulfided during presulfidation and then in situ reduced into MoS2-x in activation, and finally sulfided to active state during hydrodesulfurization (HDS). A synergistic effect between the S2- and S6+ ions in (NH4)2S2O3 produces a positive influence on the HDS performance. The S2- ions contribute to the sulfidation of Mo ions, while the S6+ species interact with Al2O3 support, weakening the interaction of active species with support.
Keywords: Hydrodesulfurization; Ammonium Thiosulfate; Presulfidation; Activation; Support Interaction
[References]
  1. Song CS, Catal. Today, 86(1-4), 211, 2003
  2. Frizi N, Blanchard P, Payen E, Baranek P, Rebeilleau M, Dupuy C, Dath JP, Catal. Today, 130(2-4), 272, 2008
  3. KIM KL, CHOI KS, Korean J. Chem. Eng., 5(2), 177, 1988
  4. Abghari SZ, Shokri S, Baloochi B, Marvast MA, Ghanizadeh S, Behroozi A, Korean J. Chem. Eng., 28(1), 93, 2011
  5. Welch JG, Poyer P, Skelly RF, Oil Gas J., 92, 56, 1994
  6. Dufresne P, Brahma N, Muff SR, US Patent, 5,985,787 (1993).
  7. de Wind M, Heinerman JJL, Lee SL, Plantenga FL, Oil Gas J., 90, 49, 1992
  8. Qian W, Yamada S, Ishihara A, Ichinoseki M, Kabe T, Sekiyu Gakkaishi, 44, 225, 2001
  9. Ge H, Li X, Qin Z, Liang F, Wang J, Korean J. Chem. Eng., 26(2), 576, 2009
  10. Massoth FE, J. Catal., 36, 164, 1975
  11. Arnold P, van den Heijkant JAM, de Bok GD, Moulijn JA, J. Catal., 92, 35, 1985
  12. de Boer M, van Dillen AJ, Koningsberger DC, Geus JW, J. Appl. Phys., 32, 460, 1993
  13. Weber T, Muijsers JC, Vanwolput HJ, Verhagen CP, Niemantsverdriet JW, J. Phys. Chem., 100(33), 14144, 1996
  14. Payen E, Kasztelan S, Houssenbay S, Szymanski R, Grimblot J, J. Phys. Chem., 93, 6501, 1989
  15. Silvy RP, Grange P, Delmon B, Stud. Surf. Sci. Catal., 53, 233, 1989
  16. de Jong AM, Borg HJ, van Ijzendoorn LJ, Soudant VGFM, de Beer VHJ, van Veen JAR, Niemantsverdriet JW, J. Phys. Chem., 97, 6477, 1993
  17. Ramirez J, Sanchez-Minero F, Catal. Today, 130(2-4), 267, 2008
  18. Hensen EJM, de Beer VHJ, van Veen JAR, van Santen RA, Catal. Lett., 84(1-2), 59, 2002
  19. Okamoto Y, Kato A, Usman, Rinaldi N, Fujikawa T, Koshika H, Hiromitsu I, Kubota T, J. Catal., 265(2), 216, 2009
  20. Dugulan A, Hensen EJM, van Veen JAR, Catal. Today, 130(1), 126, 2008
  21. Hinnemann B, Norskov JK, Topsoe H, J. Phys. Chem. B, 109(6), 2245, 2005
  22. Byskov LS, Norskov JK, Clausen BS, Topsoe H, J. Catal., 187(1), 109, 1999
  23. Raybaud P, Hafner J, Kresse G, Kasztelan S, Toulhoat H, J. Catal., 189(1), 129, 2000
  24. Ge H, Li X, Qin Z, Lu Z, Wang J, Catal. Commun., 9, 2578, 2008
  25. Ge H, Li X, Fan W, Qin Z, Lu Z, Wang J, Chin. J. Catal., 30, 111, 2009
  26. Rueda N, Bacaud R, Vrinat M, J. Catal., 169(1), 404, 1997
  27. Topsoe H, Hinnemann B, Norskov JK, Lauritsen JV, Besenbacher F, Hansen PL, Hytoft G, Egeberg RG, Knudsen KG, Catal. Today, 12, 107, 2005
  28. Plazenet G, Payen E, Lynch J, Rebours B, J. Phys. Chem. B, 106(28), 7013, 2002
  29. Berhault G, Mehta A, Pavel AC, Yang JZ, Rendon L, Yacaman MJ, Araiza LC, Moller AD, Chianelli RR, J. Catal., 198(1), 9, 2001
  30. Texier S, Berhault G, Perot G, Diehl F, Appl. Catal. A: Gen., 293, 105, 2005
  31. La Parola V, Deganello G, Venezia AM, Appl. Catal. A: Gen., 260(2), 237, 2004
  32. Shang HY, Liu CG, Zhao RY, Wu MB, Wei F, Chin. J. Chem., 22, 1250, 2004
  33. Paul JF, Cristol S, Payen E, Catal. Today, 130(1), 139, 2008
  34. Ferdous D, Dalai AK, Adjaye J, Appl. Catal. A: Gen., 260(2), 137, 2004
  35. Topsoe NY, Topsoe H, J. Catal., 139, 631, 1993
  36. Blashka S, Bond G, Ward D, Oil Gas J., 96, 36, 1998
  37. Ge H, Li X, Wang J, Lu Z, Qin Z, Zhou L, J. Fuel Chem. Technol., 37, 199, 2009
  38. Scheffer B, Arnoldy P, Moulijn JA, J. Catal., 112, 516, 1988
  39. Scheffer B, van Oers EM, Arnoldy P, de Beer VJH, Moulijn JA, Appl. Catal., 25, 303, 1986
  40. de Jong AM, Borg HJ, van Ijzendoorn LJ, Soudant VGFM, de Beer VHJ, van Veen JAR, Niemantsverdriet JW, J. Phys. Chem., 97, 6477, 1993
  41. Muijsers JC, Weber T, Vanhardeveld RM, Zandbergen HW, Niemantsverdriet JW, J. Catal., 157(2), 698, 1995
  42. Guichard B, Roy-Auberger A, Devers E, Legens C, Raybaud P, Catal. Today, 130(1), 97, 2008
  43. Candia R, Sorensen O, Villadsen J, Topsoe NY, Clausen BS, Topsoe H, Bull. Soc. Chim. Belg., 93, 763, 1984
  44. Topsoe H, Clausen BS, Appl. Catal., 25, 273, 1986
  45. Sun MY, Nicosia D, Prins R, Catal. Today, 86(1-4), 173, 2003
  46. Medici L, Prins R, J. Catal., 163(1), 28, 1996
  47. Fujikawa T, Kimura H, Kiriyama K, Hagiwara K, Catal. Today, 111(3-4), 188, 2006
  48. Hayden TF, Dumesic JA, Sherwood RD, Baker RTK, J. Catal., 105, 299, 1987
  49. Vissers JPR, Scheffer B, de Beer JHJ, Moulijn JA, Prins R, J. Catal., 105, 277, 1987
  50. van Veen JAR, Gerkema E, van der Kraan AM, Knoester A, Chem. Commun., 1684, 1987
  51. Louwers SP, Craje MW, Vanderkraan AM, Geantet C, Prins R, J. Catal., 144(2), 579, 1993
  52. Browne VM, Louwers SPA, Prins R, Catal. Today, 10, 345, 1991
  53. Usman, Yamamoto T, Kubota T, Okamoto Y, Appl. Catal., 328, 219, 2007
  54. Yamada S, Qian W, Ishihara A, Wang G, Li L, Kabe T, Sekiyu Gakkaishi, 44, 217, 2001
  55. Chen CL, Wang CH, Weng HS, Chemosphere, 56, 425, 2004
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