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Issue
Korean Journal of Chemical Engineering,
Vol.31, No.3, 522-527, 2014
Experimental measurement and correlation of phase behavior for the CO2+heptafluorobutyl acrylate and CO2+heptafluorobutyl methacrylate systems at high pressure
Yoon SD, Byun HS
Experimental data of high pressure phase behavior from 313.2 to 393.2 K and pressures up to about 14.3 MPa were reported for binary mixture of 2,2,3,3,4,4,4-heptafluorobutyl acrylate (HFBA) and 2,2,3,3,4,4,4-heptafluorobutyl methacrylate (HFBMA) in supercritical carbon dioxide. The high pressure experiment was performed by static method using variable-volume view cell apparatus. The CO2+HFBA and CO2+HFBMA systems are correlated with the Peng-Robinson equation of state using a van der Waals one-fluid mixing rule. The CO2+HFBA and CO2+HFBMA systems exhibit type-I phase behavior with continuous critical mixture curves.
Keywords: Carbon Dioxide; 2,2,3,3,4,4,4-Heptafluorobutyl Acrylate; 2,2,3,3,4,4,4-Heptafluorobutyl Methacrylate; High Pressure Phase Behavior; Peng-Robinson EOS
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[Cited By]
  1. Gwon JM, Shin HY, Kim SH, Kim H, Korean Chemical Engineering Research, 53(2), 193, 2015
  2. Jang YS, Choi YS, Byun HS, Korean Journal of Chemical Engineering, 32(5), 958, 2015
  3. Byun HS, Korean Chemical Engineering Research, 54(2), 206, 2016
  4. Byun HS, Rhee SY, Korean Journal of Chemical Engineering, 34(4), 1170, 2017
  5. Lee BS, Byun HS, Korean Journal of Chemical Engineering, 34(7), 2056, 2017
  6. Lee H, Jeong JD, Byun HS, Korean Chemical Engineering Research, 56(5), 732, 2018
  7. Jeong JD, Byun HS, Korean Chemical Engineering Research, 57(6), 826, 2019
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