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Issue
Korean Journal of Chemical Engineering,
Vol.30, No.7, 1485-1492, 2013
Recovery and enrichment of heavy metals using new hybrid Donnan dialysis systems combining cation exchange textile and solvent impregnated resin
Berdous D, Akretche DE
The purpose of this work is to apply Donnan dialysis coupled with the cation exchange membrane (CMX), the cation exchange grafted textile (CET) and the solvent impregnated resin (SIR) for recovery and enrichment of heavy metal ions from dilute solutions. The influence of some analytical parameters was investigated. The transport results show that the three barriers enhance the diffusion of silver, lead and copper, but the osmosis phenomenon is limited when the transport is carried out through CET and the SIR. The results of enrichments indicate that SIR and CET increase the enrichment factor of less hydrated ions. For instance, and for a volume ratio equal to 10, the values of silver enrichment factor obtained for (CMX/CMX/CMX), (CMX/CET/CMX) and (CMX/SIR/CMX) are equal to 2.5, 8.92 and 4.98, respectively. In addition, the use of SIR improves the enrichment of lead, whereas the CET improves the silver's one.
Keywords: Heavy Metals; Enrichment; Donnan Dialysis; Hybrid System; Cation Exchange Grafted Textile; Solvent Impregnated Resin; Extractant; D2EHPA; TOPO; DPTU
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