Issue
Korean Journal of Chemical Engineering,
Vol.30, No.4, 871-877, 2013
H2S oxidation by multi-wall carbon nanotubes decorated with tungsten sulfide
Tungsten sulfide catalysts decorated on single and multiwall carbon nanotubes (SWNTs & MWNTs) and activated carbon were synthesized, and XRD, ICP, SEM, TEM and ASAP analyses were employed to acquire the characteristics of each catalyst. Afterwards a gas flow containing 5,000 ppm of H2S was passed over the catalyst in gas hour space velocity (GHSV) of 5,000 h^(-1), temperature of 65 ℃, steam volume percent of 20 and O2/H2S ratio equal to 2. The results revealed that the catalyst supported on MWNTs exhibited higher conversion amongst its counterparts. Then effects of GHSV, steam volume percent in the feed, catalyst loading and temperature were investigated on conversion of hydrogen sulfide to elemental sulfur for tungsten sulfide catalyst decorated on MWNTs.
[References]
  1. Gas Processors Suppliers Association, Engineering Data Book, Vol. 2, 12th Ed., 2004
  2. Maddox RN, Gas and Liquid Sweetening, Campbell Petroleum Series, Oklahoma, 1998
  3. Pahlavanzadeh H, Farazar M, Korean J. Chem. Eng., 26(4), 1112, 2009
  4. Wang R, Sep. Purif. Technol., 31(1), 111, 2003
  5. Mikhail S, Zaki T, Khalil L, Appl. Catal. A: Gen., 227(1-2), 265, 2002
  6. Funks HH, Fraenkel D, Houlding VH, US Patent, 96,049 A1, 2002
  7. Graham J, Yaun C, US Patent, 6,858,192 B2, 2005
  8. Laperdrix E, Sahibed-dine A, Costentin G, Bensitel M, Lavalley JC, Appl. Catal. B: Environ., 27(2), 137, 2000
  9. Monnery WD, Hawboldt KA, Pollock A, Svrcek WY, Chem. Eng. Sci., 55(21), 5141, 2000
  10. Chung JS, Paik SC, Kim HS, Lee DS, Nam IS, Catal. Today, 35(1-2), 37, 1997
  11. Mendioroz S, Munoz V, Alvarez E, Palacios JM, Appl. Catal. A: Gen., 132(1), 111, 1995
  12. Rolke D, Cornel P, Lell R, Stetzer K, Neuroth G, US Patent, 5,256,384, 1993
  13. Graham JR, Cheng J, US Patent, 7,241,430 B2, 2007
  14. Wang L, Cao B, Wang SD, Yuan Q, Chem. Eng. J., 118(3), 133, 2006
  15. Miller R, US Patent, 3,672,125, 1972
  16. Chun SW, Jang JY, Park DW, Woo HC, Chung JS, Appl. Catal. B: Environ., 16(3), 235, 1998
  17. Jung SJ, Kim MH, Chung JK, Moon MJ, Chung JS, Park DW, Woo HC, Stud. Surf. Sci. Catal., 146, 621, 2003
  18. Bineesh KV, Kim DK, Cho HJ, Park DW, J. Ind. Eng. Chem., 16(4), 593, 2010
  19. Keller E, Ramani S, Allison D, Lusk S, Hatcher N, Swinney L, Kirkendall K, Torres G, Stewart P, Pruitt T, US Patent, 7,226,572 B1, 2007
  20. Carlsson A, Heeringen VGJ, US Patent, 0,047,201 A1, 2009
  21. Nguyen P, Edouard D, Nhut JM, Ledoux MJ, Pham C, Pham-Huu C, Appl. Catal. B: Environ., 76(3-4), 300, 2007
  22. Keller N, Pham-Huu C, Ledoux MJ, Appl. Catal. A: Gen., 217(1-2), 205, 2001
  23. Nguyen D, Bandosz T, Micropor. Mesopor. Mater., 92, 47, 2006
  24. Klein J, Henning D, Fuel., 63, 1064, 1984
  25. Yasyerli S, Dogu G, Dogu T, Catal. Today, 117(1-3), 271, 2006
  26. Bashkova S, Baker FS, Wu X, Armstrong TR, Schwartz V, Carbon., 45, 1354, 2007
  27. Bagreev A, Bandoz TJ, Carbon., 39, 2303, 2001
  28. Primavera A, Trovarelli A, Andreussi P, Dolcetti G, Appl. Catal. A: Gen., 173(2), 185, 1998
  29. Adib A, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 34, 686, 2000
  30. Bandosz TJ, Carbon., 37, 483, 1999
  31. Bandosz TJ, J. Colloid Interface Sci., 246(1), 1, 2002
  32. Shang H, Liu C, Xu Y, Qiu J, Wei F, J. Nat. Gas Chem., 15, 203, 2006
  33. Nhut JM, Huu CP, Keller N, Ledoux MJ, Catal. Today., 92, 91, 2004
  34. Rashidi AM, Akbarnejad MM, Khodadadi AA, Mortazavi Y, Ahmadpour A, Nanotechnol., 18, 315605, 2007
  35. Mohamadalizadeh A, Towfighi J, Rashidi A, Mohajeri A, Golkar M, Ind. Eng. Chem. Res., 50(13), 8050, 2011
  36. Mohamadalizadeh A, Towfighi J, Rashidi A, Manteghian M, Mohajeri A, Arasteh R, Korean J. Chem. Eng., 28(5), 1221, 2011
  37. Habibi R, Rashidi AM, Daryan JT, Zadeh AMA, Appl. Surf. Sci., 257(2), 434, 2010
  38. Guana L, Lia H, Shi Z, Gu Z, Solid State Commun., 141, 459, 2007
  39. Mohamadalizadeh A, Towfighi J, Rashidi AM, Mohajeri A, Sattari S, Manteghian M, US Patent, 168,018 A1, 2011