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Korean Journal of Chemical Engineering, Vol.38, No.10, 2113-2121, 2021
Separation of valuable metals from mixed cathode materials of spent lithium-ion batteries by single-stage extraction
With the intensity of resource scarcities and environmental problems, the disposal and recovery of spent lithium-ion batteries, especially recovery of valuable metals, becomes vital. In this work, a method of co-extracting nickel, cobalt, manganese and being separated from lithium by single-stage solvent extraction is proposed. The extraction and separation process of D2EHPA was studied. The effects of extractant concentration, saponification percentage, extraction time and O:A on the extraction efficiency of D2EHPA were systematically studied. Nearly 100% manganese, 94% cobalt and about 90% nickel were co-extracted and separated from lithium using D2EHPA in kerosene by single-stage extraction. The maximum value of separation factors (βNi/Li, βCo/Li and βMn/Li) was 13.03, 23.42 and 1904.24. The mathematical model of extraction of four ions was developed by combination of Levenberg-Marquardt method and Universal Global Optimization method. The proposed extraction model accurately fits the experimental data and helps to predict the extraction efficiency of each metal under the corresponding conditions.
[References]
- Zhang T, He Y, Wang F, Ge L, Zhu X, Li H, Waste Manag., 34(6), 1051, 2014
- Wang Y, Zeng L, Zhang G, Guan W, Sun Z, Zhang D, Qing J, Hydrometallurgy, 185, 55, 2019
- Yang Y, Lei S, Song S, Sun W, Wang L, Waste Manage., 102, 131, 2020
- Yue Y, Wei S, Yongjie B, Chenyang Z, Shaole S, Yuehua H, ACS Sustain. Chem. Eng., 6(8), 10445, 2018
- Fu Y, He Y, Li J, Qu L, Yang Y, Guo X, Xie W, J. Alloy. Compd., 847, 156489, 2020
- Quijada-Maldonado E, Olea F, Sepulveda R, Castillo J, Cabezas R, Merlet G, Romero J, Sep. Purif. Technol., 251, 117289, 2020
- Stefaniak J, Karwacka S, Janiszewska M, Dutta A, Rene ER, Regel-Rosocka M, Chemosphere, 254, 126869, 2020
- Wang Y, Yang H, Zhang G, Kang J, Wang C, Chem. Eng. J. Adv., 3, 100023, 2020
- Liu C, Lin J, Cao H, Zhang Y, Sun Z, J. Clean Prod., 228, 801, 2019
- Wang J, Lu J, Zhang M, Tang M, Lu Q, Qin Y, Lu Y, Yu B, J. Hazard. Mater., 405, 124211, 2021
- Xu L, Chen C, Fu ML, Hydrometallurgy, 197, 105439, 2020
- Zante G, Trebouet D, Boltoeva M, Appl. Geochem., 123, 104783, 2020
- Sulaiman RNR, Noah NFM, Othman N, Jusoh N, Rosly MB, Korean J. Chem. Eng., 38(3), 514, 2021
- Sulaiman RNR, Othman N, J. Hazard. Mater., 340, 77, 2017
- Li Z, Li XH, Raiguel S, Binnemans K, Sep. Purif. Technol., 201, 318, 2018
- Shuya L, Yang C, Xuefeng C, Wei S, Yaqing W, Yue Y, Sep. Purif. Technol., 250, 117258, 2020
- Ye Q, Li GH, Deng BN, Luo J, Rao MJ, Peng ZW, Zhang YB, Jiang T, Sep. Purif. Technol., 209, 175, 2019
- Sun Q, Yang LM, Huang ST, Xu Z, Li Y, Wang W, Miner. Eng., 132, 284, 2019
- Coll MT, Fortuny A, Kedari CS, Sastre AM, Hydrometallurgy, 125-126, 24, 2012
- Torkaman R, Asadollahzadeh M, Torab-Mostaedi M, Maragheh MG, Sep. Purif. Technol., 186, 318, 2017
- Jung MJ, Venkateswaran P, Lee YS, J. Ind. Eng. Chem., 14(1), 110, 2008
- Chen J, Handbook of hydrometallurgy, Metallurgical industry Press, Beijing (2005).
- Joo SH, Shin SM, Shin D, Oh C, Wang JP, Hydrometallurgy, 156, 136, 2015
- Chu W, Zhang Y, Chen X, Huang Y, Cui H, Wang M, Wang J, J. Power Sources, 449, 227567, 2020
- Yang Y, Xu S, He Y, Waste Manage., 64, 219, 2017
- Virolainen S, Fini MF, Laitinen A, Sainio T, Sep. Purif. Technol., 179, 274, 2017
- Liu T, Chen J, Li H, Li K, Sep. Purif. Technol., 245, 116869, 2020
- Wang L, Wang Y, Cui L, Gao J, Guo Y, Cheng F, Sep. Purif. Technol., 251, 117371, 2020
- Santanilla AJM, Aliprandini P, Benvenuti J, Tenorio JAS, Espinosa DCR, Miner. Eng., 160, 106691, 2021
- Shi D, Cui B, Li L, Xu M, Zhang Y, Peng X, Zhang L, Song F, Ji L, Desalination, 479, 114306, 2020
- Wang H, Feng Y, Li H, Li H, Wu H, Hydrometallurgy, 195, 105404, 2020
- Li HF, Li LJ, Li W, Chem. Phys. Lett., 754, 137675, 2020
[Cited By]
- Hyun KH, Shin MG, Kwon YC, Korean Journal of Chemical Engineering, 39(12), 3315, 2022
- Liu DY, Lou WB, Sun SN, Zhang Y, Zhang Y, Zheng SL, Korean Journal of Chemical Engineering, 39(12), 3323, 2022
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