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Korean Journal of Chemical Engineering, Vol.30, No.8, 1636-1643, 2013
Thermodynamics of molecular interactions in binary mixtures containing associated liquids
Experimentally measured data of excess molar volumes and enthalpies at 308.15 K for binary mixtures of formamide with 1-butanol or 2-methyl-1-propanol were fitted to the Redlich-Kister polynomial equation. Thermodynamics of molecular interaction in these mixtures was discussed using Prigogine-Flory-Patterson theory, Treszczanowicz-Benson association model and Graph theoretical approach. Extent of inter-molecular H-bonding in formamide and butanol in their binary mixtures was also reflected in their molar enthalpy of association of H-bonding ΔhH0 and association constant KH calculated from Treszczanowicz-Benson association model. All the three theories predict the excess property data reasonably well.
[References]
- Wang X, Xu N, Zhang R, Lin RS, Yan WD, J. Solution Chem., 35, 969, 2006
- Jorgensen WL, Swenson CJ, J. American Chem. Soc., 107, 569, 1985
- Garcia B, Alcalde R, Leal JM, Matos JS, J. Chem. Soc.Faraday Trans., 92, 3347, 1996
- Maken A, Maken S, J. Ind. Eng. Chem., 18(3), 1013, 2012
- Treszczanowicz AJ, Benson GC, Fluid Phase Equilib., 23, 117, 1985
- Treszczanowicz AJ, Benson GC, Fluid Phase Equilib., 41, 31, 1988
- Wang L, Benson GC, Lu BCY, J. Chem. Thermodyn., 24, 1305, 1992
- Bender M, Heintz A, Fluid Phase Equilib., 89, 197, 1993
- Funke H, Wetzel M, Heintz A, Pure Appl. Chem., 61, 1429, 1989
- Seo J, Lee J, Kim H, Fluid Phase Equilib., 172(2), 211, 2000
- Seo J, Lee J, Kim H, Fluid Phase Equilib., 182(1-2), 199, 2001
- Bhardwaj U, Maken S, Singh KC, J. Chem. Thermodyn., 28(10), 1173, 1996
- Kwon CH, Kang JW, Korean J. Chem. Eng., 26(1), 240, 2009
- Singh KC, Kalra KC, Maken S, Gupta V, Fluid Phase Equilib., 119(1-2), 175, 1996
- Gupta V, Maken S, Kalra KC, Singh KC, Thermochim. Acta, 277, 187, 1996
- Singh KC, Kalra KC, Maken S, Gupta V, Thermochim. Acta, 275(1), 51, 1996
- Stokes RH , Burfitt C, J. Chem. Thermodyn., 5, 623, 1973
- Stokes RH, Adamson M, J. Chem. Soc., Faraday Trans. 1: Physical Chemistry in Condensed Phases., 71, 1707, 1975
- Stokes RH, Marsh KN, J. Chem. Thermodyn., 8, 709, 1976
- Stokes RH, Adamson M, J. Chem. Thermodyn., 8, 683, 1976
- Hwang IC, Park SJ, Han KJ, Fluid Phase Equilib., 303(2), 150, 2011
- Hwang IC, Park SJ, Han KJ, Fluid Phase Equilib., 309(2), 145, 2011
- Shin SH, Hwang IC, Park SJ, In SJ, J. Ind. Eng. Chem., 18(2), 848, 2012
- Seo MD, Kim YJ, Lim JS, Kang JW, Korean J. Chem. Eng., 29(1), 103, 2012
- Breitholz A, Yoo KP, Lim JS, Lee CS, Kang JW, Korean J. Chem. Eng., 25(4), 833, 2008
- Lashkarbolooki M, Hezave AZ, babapoor A, Korean J. Chem. Eng., 30(1), 213, 2013
- Gupta V, Maken S, Kalra KC, Singh LC, Fluid Phase Equilib., 120(1-2), 195, 1996
- Pina CG, Francesconi AZ, Fluid Phase Equilib., 143(1-2), 143, 1998
- Torres RB, Francesconi AZ, Volpe PLO, Fluid Phase Equilib., 210(2), 287, 2003
- Acree WE, Campbell SW, Fluid Phase Equilib., 150-151, 207, 1998
- Geppert-Rybczynska M, Hofman T, Acta Phys. Pol., A., 114, 91, 2008
- Kim MG, Korean J. Chem. Eng., 29(9), 1253, 2012
- Khattab IS, Bandarkar F, Fakhree MAA, Jouyban A, Korean J. Chem. Eng., 29(6), 812, 2012
- Rani M, Maken S, Thermochim. Acta., 559, 98, 2013
- Rani M, Maken S, J. Ind. Eng. Chem., 18(5), 1694, 2012
- Flory PJ, J. American Chem. Soc., 87, 1833, 1965
- Abe A, Flory PJ, J. American Chem. Soc., 87, 1838, 1965
- Prigogine I, Trappeniers N, Mathot V, Discussions of the Faraday Society., 15, 93, 1953
- Patterson D, Delmas G, Discussions of the Faraday Society., 49, 98, 1970
- Prigogine I, Trappeniers N, Mathot V, J. Chem. Phys., 21, 559, 1953
- Prigogine I, Bellemans A, Mathot V, The Molecular Theory of Solutions, North-Holland Publishing Company, Amsterdam, 1957
- Galvao AC, Francesconi AZ, J. Mol. Liq., 139, 110, 2008
- Singh PP, Maken S, Pure Appl. Chem., 66, 449, 1994
- Maken S, Deshwal BR, Chadha R, Anu, Singh KC, Kim H, Park JW, Fluid Phase Equilib., 235(1), 42, 2005
- Rani M, Maken S, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.01.014., 2013
- Rani M, Agarwal S, Lahot P, Maken S, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.02.011., 2013
- Monk P, Wadso I, Acta Chem. Scand., 22, 1842, 1968
- Adcock DS, McGlashan ML, Proceedings of the Royal Society of London, Series A. Mathematical and Physical Sciences., 226, 266, 1954
- Kumar S, Maken A, Agarwal S, Maken S, J. Mol. Liq., 155, 115, 2010
- Verma N, Maken S, Singh KC, J. Mol. Liq., 141, 35, 2008
- Pikkarainen L, J. Chem. Thermodyn., 23, 877, 1991
- Costas M, Patterson D, J. Solution Chem., 11, 807, 1982
- Kehiaian HV, in MTP international Review of Science, Skinner HA, Ed., Thermochemistry and thermodynamics, Butteworth, London, 1972
- Bondi A, Physical properties of molecular crystals, liquids and gases, Wiley, New York, 1968
- Dunn LA, Stokes RH, Trans. Faraday Soc., 65, 2906, 1969
- Easteal AJ, Woolf LA, J. Chem. Thermodyn., 15, 195, 1983
- Bhardwaj U, Singh KC, Makin S, Indian J. Chem., 37A, 316, 1998
- Singh KC, Kalra KC, Maken S, Gupta V, Fluid Phase Equilib., 119(1-2), 175, 1996
- Conti G, Gianni P, Lepori L, Matteoli E, Fluid Phase Equilib., 105(1), 93, 1995
- Liu A, Kohler F, Karrer L, Gaube J, Spellucci P, Pure Appl.Chem., 61, 1441, 1989
- Stokes RH, J. Chem. Soc., Faraday Trans. 1: Physical Chemistry in Condensed Phases., 73, 1140, 1977
- Huggins ML, J. Phys. Chem., 74, 371, 1970
- Huggins ML, Polymer., 12, 389, 1971
- Singh PP, Maken S, Pure Appl. Chem., 66, 449, 1994
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