Korean Journal of Chemical Engineering, Vol.34, No.5, 1294-1304, 2017
Improved mechanical properties, barrier properties and degradation behavior of poly(butylenes adipate-co-terephthalate)/poly(propylene carbonate) films
Poly(butylene adipate-co-terephthalate) (PBAT) was blended with poly(propylene carbonate) (PPC) by a twin screw extruder and then the blends were made onto films via the blown film technique. PPC dispersed uniformly in the PBAT matrix, and the glass transition temperature (Tg) of PBAT were decreased with the increasing content of PPC. Wide angle X-ray diffraction confirmed that the crystallite dimension of PBAT was decreased after blending PBAT with the amorphous PPC. The results of mechanical tests indicated that the PBAT/PPC films showed high tensile strength and tear strength. In addition, the PBAT/PPC films showed high carbon dioxide permeability and moderate oxygen and nitrogen permeability. After embedding in soil, the weight loss and mechanical properties analysis demonstrated that the films were remarkably biodegraded. These findings contributed to application of the biodegradable materials, such as design and manufacture polymer packaging.
[References]
Lopez OV, Zaritzky NE, Grossmann MVE, Garcia MA, J. Food Eng. , 116 (2), 286, 2013
Li X, Deng S, Korean J. Chem. Eng. , 32 (11), 2347, 2015
Nair LS, Laurencin CT, Polym. Sci. , 32 , 762, 2007
Jiang L, Wolcott MP, Zhang JW, Biomacromolecules , 7 (1), 199, 2006
Brandelero RPH, Yamashita F, Grossmann VME, Carbohydr. Polym. , 82 , 1102, 2010
Russo P, Vetrano B, Acierno D, Mauro M, Polym. Compos. , 9 , 1461, 2012
Di YW, Iannace S, Di Maio E, Nicolais L, J. Polym. Sci. B: Polym. Phys. , 41 (7), 670, 2003
Inoue S, Koinuma H, Tsuruta T, J. Polym. Sci. B: Polym. Lett. , 7 , 287, 1969
Inoue S, Koinuma H, Tsuruta T, Makromol. Chem. , 130 , 210, 1969
Chen LJ, Qin YS, Wang XH, Li YS, Zhao XJ, Wang FS, Polym. Int. , 60 , 1697, 2011
Wang N, Zhang XX, Yu JG, Fang JM, Polym. Int. , 57 , 1027, 2008
Tao J, Song CJ, Cao MF, Hu D, Liu L, Liu N, Polym. Degrad. Stabil. , 94 , 575, 2009
Zeng SS, Wang SJ, Xiao M, Han DM, Meng YZ, Carbohydr. Polym. , 86 , 1260, 2011
Wang SJ, Du LC, Zhao XS, Meng YZ, Tjong SC, J. Appl. Polym. Sci. , 85 (11), 2327, 2002
Zhu Q, Meng YZ, Tjong SC, Zhao XS, Chen YL, Polym. Int. , 51 , 1079, 2002
Meng YZ, Du LC, Tiong SC, Zhu Q, Hay AS, J. Polym. Sci. A: Polym. Chem. , 40 (21), 3579, 2002
Li J, Lai MF, Liu JJ, J. Appl. Polym. Sci. , 98 (3), 1427, 2005
Ma XF, Yu JG, Wang N, J. Polym. Sci. B: Polym. Phys. , 44 (1), 94, 2006
Wu DD, Li W, Zhao Y, Deng YJ, Zhang HL, Zhang HX, Chin. J. Polym. Sci. , 33 , 444, 2015
Wang XL, Du FG, Jiao J, Meng YZ, Li RKY, J. Biomed. Mater. Res. Part B: Appl. Biomater. , 83 , 373, 2007
Zhang HL, Sun XH, Chen QY, Ren MQ, Zhang ZH, Zhang HF, Mo ZS, Chin. J. Polym. Sci. , 25 , 589, 2007
Chen WF, Pang MZ, Xiao M, Wang SJ, Wen LS, Meng YZ, J. Reinf. Plast. Compos. , 29 , 1545, 2010
Li XH, Meng YZ, Wang SJ, Rajulu AV, Tjong SC, J. Polym. Sci. B: Polym. Phys. , 42 (4), 666, 2004
Day M, Wiles DM, J. Appl. Polym. Sci. , 16 , 191, 1972
Torres N, Robin JJ, Boutevin B, Eur. Polym. J. , 36 , 2075, 2000
Ehrig RJ, Plastics Recycling: Products and Processes, Hanser Publishers, New York (1992).
Reigh L, Stivala S, Elements of Polymer Degradation, McGraw-Hill, New York (1971).
Colin X, Verdu J, Comptes. Rendus. Chimie. , 9 , 1380, 2006
Spinace MAS, De Paoli MA, J. Appl. Polym. Sci. , 80 (1), 20, 2001
Karlsson S, Adv. Polym. Sci. , 169 , 201, 2004
Kijchavengkul T, Auras R, Rubino M, Alvarado E, Montero JRC, Rosales JM, Polym. Degrad. Stabil. , 95 , 99, 2010
Kijchavengkul T, Auras R, Rubino M, Selke S, Ngouajio M, Fernandez RT, Polym. Degrad. Stabil. , 95 , 2641, 2010
Wu CS, Carbohydr. Polym. , 87 , 1249, 2012
Wu CS, Polym. Degrad. Stabil. , 97 , 2388, 2012
Zehetmeyer G, Meira SMM, Scheibel JM, J. Appl. Polym. Sci. , 133 , 43212, 2016
Pawar SP, Misra A, Bose S, Colloid Polym. Sci. , 293 , 2921, 2015
Muthuraj R, Misra M, Mohanty AK, J. Appl. Polym. Sci. , 132 , 42189, 2015
Mittal V, Chaudhry AU, Matsko NB, J. Appl. Polym. Sci. , 131 , 40816, 2014
Witt U, Einig T, Yamamoto M, Kleeberg I, Deckwer WD, Muller RJ, Chemosphere , 44 , 289, 2001
Nazri NAM, Lau WJ, Ismail AF, Korean J. Chem. Eng. , 32 (9), 1853, 2015
Ravati S, Beaulieu C, Zolali AM, Favis BD, AIChE J. , 60 (8), 3005, 2014
Kakudo M, Kasai N, X-Ray Diffraction by Polymers, Kodansha Press, Tokyo (1972).
Ozawa T, Bull. Chem. Soc. Jpn. , 38 , 1881, 1965
Gao M, Ren ZJ, Yan SK, Sun JR, Chen XS, J. Phys. Chem. B , 116 (32), 9832, 2012
Kuwabara K, Gan ZH, Nakamura T, Abe H, Doi Y, Biomacromolecules , 3 (2), 390, 2002
Chivrac F, Kadlecova Z, Pollet E, Averous L, J. Polym. Environ. , 14 , 393, 2006
Zhao Y, Zhang Y, Li Z, Pan H, Dong Q, Han L, Zhang H, Dong L, Korean J. Chem. Eng. , 33 (3), 1104, 2016
Liu BH, Chen LB, Zhang M, Yu AF, Macromol. Rapid Commun. , 23 (15), 881, 2002
Varghese JK, Na SJ, Park JH, Woo D, Yang I, Lee BY, Polym. Degrad. Stabil. , 95 , 1039, 2010
Hao YP, Yang HL, Zhang HL, Polym. Degrad. Stabil. , 128 , 286, 2016
Ma XF, Yu JG, Zhao A, Compos. Sci. Technol. , 66 , 2360, 2006
Seo J, Han H, Polym. Degrad. Stabil. , 77 , 477, 2002
Li L, Liu MJ, Li SJ, Polymer , 45 (8), 2837, 2004
Wen X, Zhang KY, Wang Y, Han LJ, Han CY, Zhang HL, Polym. Int. , 60 , 202, 2011
Kijchavengkul T, Auras R, Rubino M, Ngouajio M, Fernandez RT, Chemosphere , 71 , 942, 2008
Mochizuki M, Hirami M, Polym. Adv. Technol. , 8 , 203, 1997
Gan ZH, Kuwabara K, Abe H, Iwata T, Doi Y, Polym. Degrad. Stabil. , 87 , 191, 2005
Kale G, Auras R, Singh SP, Packag. Technol. Sci. , 20 , 49, 2007
Kim G, Ree M, Kim H, Kim IJ, Kim JR, Lee JI, Macromol. Res. , 16 (5), 473, 2008
Ju DD, Han LJ, Bian JJ, Guo ZQ, Li F, Chen S, RSC. Adv. , 5 , 5474, 2015
이전 논문 다음 논문
Result Search