|
Korean Journal of Chemical Engineering, Vol.32, No.10, 2078-2086, 2015
A comprehensive study (kinetic, thermodynamic and equilibrium) of arsenic (V) adsorption using KMnO4 modified clinoptilolite
The sorption of As(V) on manganese oxide coated zeolite (MOCZ) was investigated through batch study to explore the feasibility of removing arsenic from groundwater. MOCZ was characterized by scanning electron microscopy, XRD, FTIR spectroscopy, and point of zero charge (pHPZC) measurements. The effects of process parameters such as contact time, adsorbent size, temperature and pH were investigated. Arsenic detection was carried out by atomic fluorescence spectrometer. Arsenate adsorption onto MOCZ followed the pseudo-second-order kinetic model with a correlation coefficient more than 0.99. Optimum removal of arsenate occurred within pH range of 6-10. The equilibrium data were analyzed by Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models. The maximum adsorption capacity calculated from the Langmuir and D-R models was 151 and 152.8 μg g.1, respectively, at 38 oC. The activation energy of adsorption (Ea) was found to be 3.68 kj mol.1, suggesting that the adsorption process may be physical sorption. Thermodynamic parameters: ΔHo, was 1.181 kj mol.1; ΔSo, was .0.29 kj mol.1, while the values of ΔGo were .83.9, .86.7 and 89.8 kj mol.1 at 18, 28 and 38, respectively, suggesting endothermic and spontaneous process and a rise in temperature favoring the adsorption.
[References]
- Jimenez-Cedillo M, Olguin M, Fall C, J. Hazard. Mater., 163(2), 939, 2009
- Menhage-Bena R, Kazemian H, Ghazi-Khansari M, Hosseini M, Shahtaheri S, Iran. J. Public Health, 33(14), 36, 2004
- Vu KB, Kaminski MD, Nunez L, Review of arsenic removal technologies for contaminated groundwaters, in Other Information:PBD: 2 May 2003. 2003. p. Medium: ED; Size: 43 Pages.
- Stanic T, Dakovic A, Zivanovic A, Tomasevic-Canovic M, Dondur V, Milicevic S, Environ. Chem. Lett., 7(2), 161, 2009
- Rahaman MS, Basu A, Islam MR, Bioresour. Technol., 99(8), 2815, 2008
- Siljeg M, Foglar L, Gudelj I, Chem. Ecol., 28(1), 75, 2011
- Dora TK, Mohanty YK, Roy GK, Sarangi B, J. Environ. Chem. Eng., 1(3), 150, 2013
- Naujokas MF, Anderson B, Ahsan H, Aposhian HV, Graziano JH, Thompson C, Suk WA, Environ. Health Perspect., 121(3), 295, 2013
- Chutia P, Kato S, Kojima T, Satokawa S, J. Hazard. Mater., 162(1), 440, 2009
- Mosaferi M, et al., Occurrence of arsenic in Kurdistan Province of I.R. Iran, Proceeding of Conference on Fate of Arsenic in the Environment, 1 (2003).
- Dominguez-Ramos A, Chavan K, Garcia V, Jimeno G, Albo J, Marathe KV, Yadav GD, Irabien A, Ind. Eng. Chem. Res., 53(49), 18920, 2014
- Elcik H, Cakmakci M, Sahinkaya E, Ozkaya B, Ind. Eng. Chem. Res., 52(29), 9958, 2013
- Dou X, Mohan D, Pittman CU, Water Res., 47(9), 2938, 2013
- Lacasa E, Saez C, Canizares P, Fernandez FJ, Rodrigo MA, Sep. Sci. Technol., 48(3), 508, 2012
- Chutia P, Kato S, Kojima T, Satokawa S, J. Hazard. Mater., 162(1), 204, 2009
- Li ZH, Jean JS, Jiang WT, Chang PH, Chen CJ, Liao LB, J. Hazard. Mater., 187(1-3), 318, 2011
- Baskan M, Pala A, Water, Air, Soil Pollut., 225(1), 1, 2013
- Qiu M, Jian Q, Yu D, Feng K, Desalination Water Treatment, 24(1-3), 61, 2010
- Olad A, Ahmadi S, Rashidzadeh A, Desalination Water Treatment, 51(37-39), 7172, 2013
- Zorpas AA, Desalination Water Treatment, 8(1-3), 256, 2009
- Nezamzadeh-Ejhieh A, Shahanshahi M, J. Ind. Eng. Chem., 19(6), 2026, 2013
- Camacho LM, Parra RR, Deng SG, J. Hazard. Mater., 189(1-2), 286, 2011
- Maliyekkal SM, Philip L, Pradeep T, Chem. Eng. J., 153(1-3), 101, 2009
- Teng SX, Wang SG, Gong WX, Liu XW, Gao BY, J. Hazard. Mater., 168(2-3), 1004, 2009
- Taffarel SR, Rubio J, Miner. Eng., 23(14), 1131, 2010
- Bajpai S, Chaudhuri M, J. Environ. Eng., 125(8), 782, 1999
- Faria PCC, Orfao JJM, Pereira MFR, Water Res., 38(8), 2043, 2004
- Rivera-Utrilla J, Bautista-Toledo I, Ferro-Garcia MA, Moreno-Castilla C, J. Chem. Technol. Biotechnol., 76(12), 1209, 2001
- Ho YS, McKay G, Process Saf. Environ. Protect., 76(4), 332, 1998
- Ho YS, McKay G, Chem. Eng. J., 70(2), 115, 1998
- Low MJD, Chem. Rev., 60(3), 267, 1960
- Chiron N, Guilet R, Deydier E, Water Res., 37(13), 3079, 2003
- Zou W, Han R, Chen Z, Jinghua Z, Shi J, Colloids Surf. A: Physicochem. Eng. Asp., 279(1-3), 238, 2006
- Sari A, Citak D, Tuzen M, Chem. Eng. J., 162(2), 521, 2010
- Banerjee K, Amy GK, Prevost M, Nour S, Jekel M, Gallagher PM, Blumenschein CD, Water Res., 42(13), 3371, 2008
- Al-Ghouti M, Khraisheh MAM, Ahmad MNM, Allen S, J. Colloid Interface Sci., 287(1), 6, 2005
- Bulut Y, Aydin H, Desalination, 194(1-3), 259, 2006
- Langmuir I, J. Am. Chem. Soc., 38(11), 2221, 1916
- Gimbert F, Morin-Crini N, Renault F, Badot PM, Crini G, J. Hazard. Mater., 157(1), 34, 2008
- Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2, 2010
- Tanaka H, Yamasaki N, Muratani M, Hino R, Mater. Res. Bull., 38(4), 713, 2003
- Smiciklas ID, Milonjic SK, Pfendt P, Raicevic S, Sep. Purif. Technol., 18(3), 185, 2000
- Manning BA, Fendorf SE, Bostick B, Suarez DL, Environ. Sci. Technol., 36(5), 976, 2002
- Jeon CS, Baek K, Park JK, Oh YK, Lee SD, J. Hazard. Mater., 163(2-3), 804, 2009
- Ahmad M, Lee S, Oh SE, Mohan D, Moon D, Lee Y, Ok Y, Environ. Sci. Pollut. Res., 20(12), 8364, 2013
- Ngah WSW, Fatinathan S, Yosop NA, Desalination, 272(1-3), 293, 2011
- Febrianto J, Kosasih AN, Sunarso J, Ju YH, Indraswati N, Ismadji S, J. Hazard. Mater., 162(2-3), 616, 2009
- Oke IA, Olarinoye NO, Adewusi SRA, Adsorption, 14(1), 73, 2008
- Wang XJ, Xia SQ, Chen L, Zhao JF, Chovelon JM, Nicole JR, J. Environ. Sci., 18(5), 840, 2006
- Moussavi G, Khosravi R, J. Hazard. Mater., 183(1-3), 724, 2010
- Khan T, Chaudhry S, Ali I, Environ. Sci. Pollut. Res., 20(8), 5425, 2013
- Vijayaraghavan K, Padmesh TVN, Palanivelu K, Velan M, J. Hazard. Mater., 133(1-3), 304, 2006
- Fierro V, Muniz G, Gonzalez-Sanchez G, Ballinas ML, Celzard A, J. Hazard. Mater., 168(1), 430, 2009
- Pokhrel D, Viraraghavan T, Sep. Sci. Technol., 43(13), 3545, 2008
- Saha S, Sarkar P, J. Hazard. Mater., 227-228, 68
- Maji SK, Pal A, Pal T, Adak A, J. Surf. Sci. Technol., 23(3-4), 161, 2007
- Kunzru S, Chaudhuri M, J. Environ. Eng., 131(9), 1350, 2005
- Bhunia P, Pal A, Bandyopadhyay M, J. Hazard. Mater., 141(3), 826, 2007
- Leyva-Ramos R, Jacobo-Azuara A, Diaz-Flores PE, Guerrero-Coronado RM, Mendoza-Barron J, Berber-Mendoza MS, Colloids Surf. A: Physicochem. Eng. Asp., 330(1), 35, 2008
[Cited By]
- Jafari AJ, Kakavandi B, Kalantary RR, Gharibi H, Asadi A, Azari A, Babaei AA, Takdastan A, Korean Journal of Chemical Engineering, 33(10), 2878, 2016
- Babaei AA, Kakavandic B, Rafiee M, Kalantarhormizi F, Purkaram I, Ahmadi E, Esmaeili S, Journal of Industrial and Engineering Chemistry, 56, 163, 2017
|