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Korean Journal of Chemical Engineering, Vol.16, No.1, 111-117, 1999
DYE SOLUBILITY IN SUPERCRITICAL CARBON DIOXIDE. EFFECT OF HYDROGEN BONDING WITH COSOLVENTS
The use of supercritical carbon dioxide is emerging as a potential method for achieving pollution-free dyeing. An important factor in supercritical fluid dyeing is the solubility of the dye in supercritical carbon dioxide. Our measurements show that the solubility of C.I. Disperse Red-60 dye in supercritical carbon dioxide is significantly enhanced upon addition of polar cosolvents : ethanol and acetone. The solubility enhancement is attributed to the formation of hydrogen bonds between cosolvent and dye molecules. Observed solubility behavior is correlated using dilute-solution theory with lattice-fluid-hydrogen-bonding model. Needed physical and hydrogen-bonding molecular parameters are estimated using the experimental data.
[References]
- Bae HK, Her BK, HWAHAK KONGHAK, 34(3), 379, 1996
- Chang KH, Bae HK, Shim JJ, Korean J. Chem. Eng., 13(3), 310, 1996
- Clifford AA, Bartle KD, Textile Tech. Int., 113, 1996
- Dobbs JM, Wong JM, Lahiere RJ, Johnston KP, Ind. Eng. Chem. Res., 26(1), 56, 1987
- Ewald AH, Jepson WB, Bowlinson JS, Disc. Farad. Soc., 15, 238, 1953
- Foster NR, Singh H, Yun SLJ, Tomasko DL, Macnaughton SJ, Ind. Eng. Chem. Res., 32, 2849, 1993
- Gerbert B, Saus W, Knittel D, Buschmann HJ, Schollmeyer E, Textile Res. J., 64(7), 371, 1994
- Gupta RB, Combes JR, Johnston KP, J. Phys. Chem., 97, 707, 1993
- Gupta RB, Panayiotou C, Sanchez IC, Johnston KP, AIChE J., 38(8), 1243, 1992
- Haarhaus U, Swidersky P, Schneider GM, J. Supercrit. Fluids, 8(2), 100, 1995
- Joung SN, Yoo KP, J. Chem. Eng. Data, 43(1), 9, 1998
- Kazarian SG, Brantley NH, West BL, Vincent MF, Eckert CA, Appl. Spectroscopy, 51(4), 491, 1997
- Ke J, Jin SZ, Han BX, Yan HK, Shen DY, J. Supercrit. Fluids, 11(1), 53, 1997
- Li S, Varadarajan GS, Hartland S, Fluid Phase Equilib., 68, 263, 1991
- Ozcan AS, Clifford AA, Bartle KD, Lewis DM, Dyes Pigments, 36(2), 103, 1998
- Ozcan AS, Clifford AA, Bartle KD, Lewis DM, J. Chem. Eng. Data, 42(3), 590, 1997
- Panayiotou C, Sanchez IC, J. Phys. Chem., 95, 10090, 1991
- Prausnitz JM, Lichlenthater RN, Azevedo EG, "Molecular Thermodynamics of Fluid Phase Equilibria," 2nd ed.; Prentice-Hall Inc., Englewood Cliffs, NJ, Chapter 5, 1986
- Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2352, 1976
- Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2568, 1976
- Saus W, Knittel D, Schollmeyer E, Textile Praxis International, 47, 1052, 1992
- Saus W, Knittel D, Schollmeyer E, Textile Res. J., 63(3), 135, 1993
- Schmitt WJ, Reid RC, "The Influence of the Solvent Gas on the Solubility and Selectivity in Supercritical Extraction," In Supercritical Fluid Technology; Penninger, J.M., et al., eds.; Elsevier; New York, 123, 1985
- Shim JJ, Johnston KP, AIChE J., 35(7), 1097, 1989
- Sung HD, Shim JJ, J. Supercrit. Fluids, submitted, 1999
- Swidersky P, Tuma D, Schneider GM, J. Supercrit. Fluids, 9(1), 12, 1996
- Ting SST, Macnaughton SJ, Tomasko DI, Foster NR, Ind. Eng. Chem. Res., 32, 1471, 1993
- Ting SST, Tomasko DL, Macnaughton SJ, Foster NR, Ind. Eng. Chem. Res., 32, 1482, 1993
- Tsekhanskaya YT, Iomtev MB, Mushkina EV, Russian J. Phys. Chem., 38(9), 1173, 1964
- Wang XR, Tavlarides LL, Ind. Eng. Chem. Res., 33(3), 724, 1994
- Zhong MH, Han BX, Yan H, Peng DY, Fluid Phase Equilib., 134(1-2), 175, 1997
- Zhong MH, Han BX, Yan HK, J. Supercrit. Fluids, 10(2), 113, 1997
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- Cao X, Lee HJ, Yun HS, Koo YM, Korean Journal of Chemical Engineering, 18(1), 133, 2001
- Kim YH, Lee YW, Park JK, Lee CH, Lim JS, Korean Journal of Chemical Engineering, 19(6), 986, 2002
- Baek JK, Kim S, Lee GS, Shim JJ, Korean Journal of Chemical Engineering, 21(1), 230, 2004
- Youn HS, Roh MK, Weber A, Wilkinson GT, Chun BS, Korean Journal of Chemical Engineering, 24(5), 831, 2007
- Park SC, Tuma D, Kim S, Lee YR, Shim JJ, Korean Journal of Chemical Engineering, 27(1), 299, 2010
- Park JN, Ali-Nehari A, Woo HC, Chun BS, Korean Journal of Chemical Engineering, 29(11), 1604, 2012
- Morais AB, Jayakumar C, Gandhi NN, Korean Journal of Chemical Engineering, 30(4), 925, 2013
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