| Issue |
Korean Journal of Chemical Engineering,
Vol.27, No.6, 1868-1875, 2010
Vol.27, No.6, 1868-1875, 2010
Chemical absorption of carbon dioxide into phenyl glycidyl ether solution containing THA-CP-MS41 catalyst
Carbon dioxide was absorbed into the phenyl glycidyl ether (PGE) solution within a range of 0-2.0 kmol/m3 in a stirred batch tank with a planar gas-liquid interface at 333-363 K and 101.3 kPa. Trihexylamine-immobilized on chloropropyl-functionalized MCM-41 (THA-CP-MS41) was used as a mesoporous catalyst, dispersed in organic liquid for the reaction between carbon dioxide and PGE. The measured absorption rates were analyzed to obtain the reaction kinetics of the consecutive chemical reactions which consisted of two steps using the mass transfer mechanism based on film theory. The overall reaction kinetics, analyzed with the pseudo-first-order reaction constant in the consecutive reaction model, was equivalent to the consecutive reaction kinetics. Effects of polar solvent, such as N, Ndimethylacetamide, N-methyl-2-pyrrolidinone, and dimethyl sulfoxide, on the reaction rate constants were observed using the solubility parameter of the solvent.
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