|
Korean Journal of Chemical Engineering, Vol.29, No.11, 1615-1621, 2012
Tie-line data for aqueous mixtures of butyric acid with isobutyl acetate at various temperatures
Experimental liquid-liquid equilibrium (LLE) data for the system of (water+butyric acid+iso-butyl acetate) were obtained at T=(298.2, 303.2, 308.2, and 313.2) K and atmospheric pressure. This ternary system exhibits type-1 behavior of LLE. The experimental tie-line data were correlated using the UNIQUAC and NRTL models. The reliability of the experimental tie-line data was determined by applying the Othmer.Tobias and Hand correlations. Distribution coefficients and separation factors were calculated over the immiscibility regions.
[References]
- Senol A, Fluid Phase Equilib., 243(1-2), 51, 2006
- Ozmen D, J. Chem. Thermodyn., 39(1), 123, 2007
- Ozmen D, Fluid Phase Equilib., 269(1-2), 12, 2008
- Uslu H, Kirbaslar SI, Fluid Phase Equilib., 287(2), 134, 2010
- Sahin S, Kirbaslar SI, Bilgin M, J. Chem. Thermodyn., 41(1), 97, 2009
- Kirbaslar SI, Sahin S, Bilgin M, J. Chem. Thermodyn., 39(11), 1463, 2007
- Bilgin M, Arisoy C, Fluid Phase Equilib., 250(1-2), 59, 2006
- Almuhtaseb SA, Fahim MA, Fluid Phase Equilib., 123(1-2), 189, 1996
- Vandak D, Zigova J, Syturdik E, Schlosser S, Process Biochem., 32, 245, 1977
- Sabolova E, Schlosser S, Martak J, J. Chem. Eng. Data., 46, 735, 2001
- Li ZY, Qin W, Dai YY, J. Chem. Eng. Data, 47(4), 843, 2002
- Kirbaslar SI, Sahin S, Bilgin M, J. Chem. Thermodyn., 39(9), 1279, 2007
- Kirbaslar SI, J. Chem. Thermodyn., 38(6), 696, 2006
- Kirbaslar SI, Bilgin M, Batr D, J. Chem. Thermodyn., 37(2), 175, 2005
- Bilgin M, J. Chem. Thermodyn., 38, 1643, 2006
- Bilgin M, Kirbaslar SI, Ozcan O, Dramur U, J. Chem. Thermodyn., 37(4), 297, 2005
- Gok A, Kirbaslar SI, Uslu H, Gilani HG, Fluid Phase Equilib., 303(1), 71, 2011
- Ghanadzadeh H, Ghanadzadeh A, Asgharzadeh S, Dastmoozeh N, Thermochim. Acta, 523(1-2), 154, 2011
- Ghanadzadeh H, Ghanadzadeh A, Aghajani Z, Abbasnejad S, Shekarsaraee S, J. Chem. Thermodyn., 42(6), 695, 2010
- Abrams DS, Prausnitz JM, AIChE J., 21, 116, 1975
- Renon H, Prausnitz JM, AIChE J., 14, 135, 1968
- Peschke N, Sandler SI, J. Chem. Eng. Data, 40(1), 315, 1995
- Li HD, Tamura K, Fluid Phase Equilib., 263(2), 223, 2008
- Merzougui A, Hasseine A, Kabouche A, Korichi M, Fluid Phase Equilib., 309(2), 161, 2011
- Bondi A, J. Phys. Chem., 68, 441, 1964
- Bondi A, Physical Properties of Molecular Crystals, Liquids and Glasses, John Wiley and Sons Inc., New York, 1968
- Banerjee T, Singh MK, Sahoo RK, Khanna A, Fluid Phase Equilib., 234(1-2), 64, 2005
- Othmer DF, Tobias PE, Ind. Eng. Chem., 34, 690, 1942
- Brandani V, Chianese A, Rossi M, J. Chem. Eng. Data., 30, 27, 1985
- Chafer A, de la Torre J, Monton JB, Lladosa E, Fluid Phase Equilib., 265(1-2), 122, 2008
- Ghanadzadeh Gilani H, Golpour M, Abbasi Souraki B, AAPG Bull., 49, 39, 2010
|