| Search / Korean Journal of Chemical Engineering |
Korean Chemical Engineering Research,
Vol.50, No.4, 632-638, 2012
Vol.50, No.4, 632-638, 2012
Hydroxyethyl Methacrylate와 Methyl Methacrylate의 첨가량 변화가 수분산 폴리우레탄-아크릴 혼성 용액의 물성에 미치는 영향
Effect of Addition Amounts of Hydroxyethyl Methacrylate and Methyl Methacrylate on the Properties of Waterborne Polyurethane-Acrylic Hybrid Solutions
Isophorone diisocyanate (IPDI), polycarbonate diol (PCD), dimethylol propionic acid (DMPA)를 출발물질로 하여 수분산 폴리우레탄(waterborne polyurethane dispersion, PUD)을 합성하였다. 이 PUD에 아크릴 단량체인 HEMA (2-hydroxyethyl methacrylate)와 MMA (methyl methacrylate)의 혼합물을 첨가하여 수분산 폴리우레탄-아크릴 혼성 용액을 제조하였다. 그 결과 제조된 혼성 용액의 평균 입도는 아크릴 단량체의 첨가량이 증가함에 따라 증가하였다. 또한 수분산 폴리우레탄-아크릴 혼성 용액으로부터 제조된 코팅 도막의 내마모성과 내화학성은 순수한 PUD 보다 크게 향상되었다.
Waterborne polyurethane dispersions (PUD) were synthesized from isophorone diisocyanate (IPDI), polycarbonate diol (PCD) and dimethylol propionic acid (DMPA) as starting materials. Subsequently, waterborne polyurethane-acrylic hybrid solutions were prepared by reacting the PUD with different amounts of the mixture of acrylate monomers, HEMA (2-hydroxyethyl methacrylate) and MMA (methyl methacrylate). As a result, the average particle size of waterborne polyurethane-acrylic hybrid solutions was increased with increasing the addition amounts of acrylate monomers. Also, the prepared coating films from waterborne polyurethane-acrylic hybrid solutions showed better abrasion resistance and chemical resistance than those of pure PUD.
Keywords:
Coating Films; Chemical Resistance; 2-Hydroxyethyl Methacrylate; Methyl Methacrylate; Waterborne Polyurethane-Acrylic Hybrid Solutions
[References]
- Shin YT, Hong MG, Choi JJ, Lee WK, Lee GB, Yoo BW, Lee MG, Song KC, Korean Chem. Eng. Res., 48(4), 434, 2010
- Hong MG, Shin YT, Choi JJ, Lee WK, Lee GB, Yoo BW, Lee MG, Song KC, Ibid., 48(5), 561, 2010
- Shin YT, Hong MG, Choi JJ, Lee WK, Lee GB, Yoo BW, Lee MG, Song KC, Ibid., 48(4), 428, 2010
- Shin YT, Hwang JH, Hong MG, Choi JJ, Lee WK, Lee GB, Yoo BW, Lee MG, Song KC, Ibid., 49(3), 285, 2011
- Kim BS, Hong MG, Yoo BW, Lee MG, Song KC, Ibid., in press, 50(3), 2012
- Shin YT, Hong MG, Choi JJ, Lee WK, Yoo BW,Lee MG, Song KC, ibid., 49(4), 411, 2011
- Shin YT, Hong MG, Kim BS, Lee WK, Yoo BW, Lee MG, Song KC, Ibid., 49(5), 548, 2011
- Han SH, Park DW, J. Korean Ind. Eng. Chem., 17(2), 132, 2006
- ASTM D 3359, “Standard Test Methods for Measuring Adhesion by Tape Test,” ASTM International, 927, 1997
- Hwang JH, Song KC, Korean Chem. Eng. Res., 49(3), 277, 2011
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.