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Korean Chemical Engineering Research,
Vol.50, No.2, 300-303, 2012
Vol.50, No.2, 300-303, 2012
고분자 첨가에 의한 탄산칼슘의 상 변화
Phase Change of Calcium Carbonate by Adding Polymers
침전탄산칼슘 결정화계에서 첨가제인 ethylenediaminetetraacetic acid(EDTA), diethylene triaminepentaacetic acid (DTPA), citric acid(CIT), pyromellitic amid(PMA) 첨가에 의한 탄산칼슘 결정의 형상 변화를 연구하였다. 첨가제를 넣지 않았을 때 낮은 온도 20 ℃에서는 calcite 결정이 생성되었고, 높은 온도 80 ℃에서는 aragonite 결정이 생성되었으며 EDTA와 DTPA 첨가에 의한 40, 60 ℃ 중간온도에서는 aragonite 결정이 생성됨을 알 수 있었다. CIT와 PMA 첨가에 의해 aragonite의 성장이 지연되었으며 calcite 단일상이 나타났다. 첨가제가 단일상의 탄산칼슘을 만드는데 중요한 요소임이 발견되었다.
Phase change of calcium carbontae crystals in crystallization of precipitated calcium carbonate was researched by adding additives such as ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), citric acid (CIT) and pyromellitic amid (PMA). At low temperature 20 ℃, calcite crystal was made. At high temperature 80 ℃, aragonite crystal was made without additives. At middle temperature 40 ℃ and 60 ℃, Aragonite crystal also made by adding EDTA, DTPA. The crystal growth of Aragonite was retarded by the presence of CIT, PMA and the single phase of calcite was made. It was found that additives were important factors to make the single phase of calcium carbonate.
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