Search / Korean Journal of Chemical Engineering
Korean Chemical Engineering Research,
Vol.49, No.1, 1-9, 2011
티타니아, 바나디아, 지르코니아, 세리아를 고정한 실리카에 담지된 백금 촉매의 분산성과 안정성
Dispersion and Stability of Platinum Catalysts Supported on Titania-, Vanadia-, Zirconia- and Ceria-Incorporated Silicas
티타니아, 바나디아, 지르코니아, 세리아를 고정한 실리카에 백금을 담지한 후 과산화수소로 처리하여 제조한 백금촉매에서 산화물 고정과 과산화수소 처리가 백금의 분산 상태 및 일산화탄소 산화반응에서 이들의 촉매 활성에 미치는 영향을 조사하였다. 산화물을 고정하고 과산화수소로 처리하면 실리카에도 백금이 잘 분산될 수 있음을 XRD, TEM, EXAFS, XPS, 일산화탄소 화학흡착 방법으로 검증하였다. 그러나 일산화탄소의 흡착성질과 일산화탄소 산화반응에서 촉매 활성은 고정한 산화물 종류에 따라 상당히 달랐다. 티타니아, 지르코니아, 세리아를 실리카에 고정하고 과산화수소로 처리하여 제조한 백금 촉매에서는 백금의 분산도가 높아져서 일산화탄소 산화반응에서 활성이 증진되었다. Pt-OZr 결합이 생성되어 백금의 분산도가 크게 향상된 지르코니아 고정 백금 촉매에서 산화물 고정과 과산화수소 처리로 인한 활성 증진 효과가 가장 컸다.
Platinum catalysts were prepared by impregnating platinum precursor on titania-, vanadia-, zirconia- and ceria-incorporated silicas followed by hydrogen peroxide treatment. The effects of the oxide incorporation and the hydrogen peroxide treatment in the preparation of the platinum catalysts on their platinum dispersion and catalytic activity in carbon monoxide oxidation were investigated. XRD, TEM, EXAFS, XPS and carbon monoxide chemisorption studies confirmed the high dispersion of platinum even on silica by the oxide incorporation and hydrogen peroxide treatment. However, the type of oxides incorporated on silica caused considerable variances in the adsorption and the catalytic activity in the oxidation of carbon monoxide on them. The incorporation of titania, zirconia and ceria on silica and further hydrogen peroxide treatment enhanced the platinum dispersion, resulting in the improved catalytic activities. Among the catalysts supported on the oxide-incorporated silicas, the platinum catalyst supported on zirconia-incorporated silica exhibited the highest activity because of the highest platinum dispersion due to the formation of Pt-O-Zr bonds.
[References]
  1. Douidah A, Marecot P, Barbier J, Appl. Catal. A: Gen., 225(1-2), 11, 2002
  2. Neyestanaki AK, Klingstedt F, Salmi T, Murzin DY, Fuel, 83, 395, 2004
  3. Rase, HF, Handbook of Commercial Catalysts-Heterogeneous Catalysts, CRC Press, Boca Raton, 2000
  4. Oudenhuijzen MK, Kooyman PJ, Tappel B, van Bokhoven JA, Koningsberger DC, J. Catal., 205(1), 135, 2002
  5. Goguet A, Schweich D, Candy JP, J. Catal., 220(2), 280, 2003
  6. Miller JT, Schreier M, Kropf AJ, Regalbuto JR, J. Catal., 225(1), 203, 2004
  7. Goscianska J, Fiedorow R, Wawrzynczak A, Ziolek M, Catal. Today, 142, 298, 2009
  8. Foger K, Catalysis Science and Technology, Anderson JR, Boudart M Ed., vol. 6, chap. 4, Springer-Verlag, Berlin, 1984
  9. Mcvicker GB, Ziemiak JJ, J. Catal., 95, 473, 1985
  10. Ruiz-Martinez J, Sepulveda-Escribano A, Anderson JA, Rodriguez-Reinoso F, Phys. Chem. Chem. Phys., 11, 917, 2009
  11. Kim MY, You YS, Han HS, Seo G, Catal. Lett., 120(1-2), 40, 2008
  12. Kim MY, Jung SB, Kim MG, You YS, Park JH, Shin CH, Seo G, Catal. Lett., 129(1-2), 194, 2009
  13. Kim MY, Park JH, Shin CH, Han SW, Seo G, Catal. Lett., 133(3-4), 288, 2009
  14. Kim MY, Park SM, Seo G, Song KS, Catal. Lett., 138(3-4), 205, 2010
  15. Ramaker DE, de Graaf J, van Veen JAR, Koningsberger DC, J. Catal., 203(1), 7, 2001
  16. Ito S, Fujimori T, Nagashima K, Yuzaki K, Kunimori K, Catal. Today, 57(3-4), 247, 2000
  17. Jochuma W, Ederb D, Kaltenhausera G, Kramer R, Top. Catal., 46, 49, 2007
  18. Nagai Y, Hirabayashi T, Dohmae K, Takagi N, Minami T, Shinjoh H, Matsumoto S, J. Catal., 242(1), 103, 2006
  19. Adam W, Malisch W, Roschmann KJ, Saha-Moller CR, Schenk WA, J. Organomet. Chem., 661, 3, 2002
  20. Geobaldo F, Bordiga S, Zecchina A, Gianello E, Leofanti G, Petrini G, Catal. Lett., 16, 109, 1992
  21. Giamello E, Rumori P, Geobaldo F, Fubini B, Paganini M, Appl. Magn. Reson., 10, 173, 1996
  22. Neumann R, Levinelad M, Appl. Catal. A: Gen., 122(2), 85, 1995
  23. Aboukais A, Zhilinskaya EA, Lamonier JF, Filimonov IN, Colloid Surf. A-Physicochem. Eng. Asp., 260, 199, 2005
  24. Swatsitang E, Krochai M, J. Met. Mater. Miner., 19, 91, 2009
  25. Zosimova PA, Smirnov AV, Nesterenko SN, Yuschenko VV, Sinkler W, Kocal J, Holmgren J, Ivanova II, J. Phys. Chem. V, 111, 14790, 2007
  26. Maniguet S, Mathew RJ, Russell AE, J. Phys. Chem. B, 104(9), 1998, 2000
  27. Koningsberger DC, Gates BC, Catal. Lett., 14, 271, 1992
  28. Silvestre-Albero J, Coloma F, Sepulveda-Escribano A, Rodriguez-Reinoso F, Appl. Catal. A: Gen., 304(1), 159, 2006
  29. Silvestre-Albero J, Sepulveda-Escribano A, Rodriguez-Reinoso F, Anderson JA, J. Catal., 223(1), 179, 2004
  30. Jain SK, Crabb EM, Smart LE, Thompsett D, Steele AM, Appl. Catal. B: Environ., 89(3-4), 349, 2009
  31. Alayon EMC, Singh J, Nachtegaal M, Harfouche M, van Bokhoven JA, J. Catal., 263(2), 228, 2009
  32. Jenewein B, Penner S, Hayek K, Appl. Catal. A: Gen., 308, 43, 2006
  33. Cho SH, Park JS, Choi SH, Lee SK, Kim SH, Catal. Lett., 103(3-4), 257, 2005
  34. Graf PO, de Vlieger DJM, Mojet BL, Lefferts L, J. Catal., 262(2), 181, 2009