The propellant KM10, a single propellant manufactured from nitrocellulose, was known to cause natural degradation phenomena at long term storage. In this study, the self-life was estimated using high temperature acceleration aging tests and stockpile analysis test. For the life expectancy estimation, Arrhenius equation and Berthelot equation were used in the high temperature acceleration tests, and the first order regression was used in the Stockpile analysis test. The self-life of propellant KM10 using the Arrhenius equation and Berthelot equation showed significantly different results as 43.73, 16.53 years in the high temperature acceleration test, and it showed 42.94 years in the Stockpile analysis test. The value of self-life predicted by Arrhenius equation was reasonable when compared with the result of E. R. Bixon.