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Search / Korean Journal of Chemical Engineering
Korean Chemical Engineering Research,
Vol.48, No.3, 283-291, 2010
리튬이온전지용 TiO2 나노튜브 음전극 특성
Anode Properties of TiO2 Nanotube for Lithium-Ion Batteries
최민규, 이영기, 김광만
리튬이온전지의 음전극으로 사용하기 위해 주로 알카리 수열합성법과 열처리에 의해 제조되는 TiO2 나노튜브의 전기화학적 특성에 관한 연구결과를 조사하여, 그 충방전 특성을 분석하였다. 현재까지 리튬과 TiO2의 전기화학반응으로 생성되는 LixTiO2의 이론용량인 335 mAh g^(-1)(x=1)를 초과하는 최대방전용량 338 mAh g^(-1)(x=1.01)을 TiO2(B) 상을 갖는 나노튜브가 나타내었다. 이것은 리튬의 자가확산이 활성에너지 0.48 eV 정도로 느리므로 이보다 확산거리가 짧도록 TiO2 나노튜브의 구조를 조정하여 리튬 수송이 원활하도록 하였기 때문이다. 또한 TiO2 나노튜브 구조체는 벌크상은 물론 표면에서의 뛰어난 이온저장성 때문에 리튬이온전지의 음전극 소재뿐만 아니라 고출력 특성이 필요한 커페시터 소자의 전극소재로도 활용할 수 있다.
In this review, the studies on the electrochemical properties of TiO2 nanotube as an anode material of lithium-ion battery, which was prepared by an alkaline hydrothermal reaction and anneling process, were investigated and analyzed in terms of charge-dischage characteristics. Up to date, a maximum discharge capacity of 338 mAh g^(-1)(x=1.01) was achieved by the nanotube with TiO2(B) phase, whereas the theoretical capacity of TiO2 anode was 335 mAh g^(-1)(x=1) in the basis of LixTiO2 as a product of electrochemical reaction between TiO2 and lithium. This was due to fast lithium transport by a shortened diffusion path provided by controlling the nanostructure of TiO2, because the self-diffusion of lithium was slow in a basis of its activation energy as 0.48 eV. Due to an excellent ion storage capabilities in both the surface and the bulk phase, the TiO2 nanotube could be a promising active material as both an anode of lithium-ion battery and an electrode of capacitor with high-rate performances.
Keywords: TiO2 Nanotube; Anode; Lithium-Ion Battery; Electrochemical Property
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[Cited By]
  1. Choi MG, Kang KY, Lee YG, Kim KM, Korean Chemical Engineering Research, 50(1), 25, 2012
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