| Search / Korean Journal of Chemical Engineering |
Korean Chemical Engineering Research,
Vol.46, No.5, 868-874, 2008
Vol.46, No.5, 868-874, 2008
일산화탄소 제거를 위한 니켈 담지 흡착제 제조
Nickel Supported Adsorbent for Removing Carbon Monoxide
실리카, 알루미늄 실리케이트, 감마 알루미나 담체에 Ni(NO3)2·6H2O와 Ni(CH3COO)2·4H2O를 원료로 침전제인 요소와 시트르산을 사용하여 90 oC에서 공침법을 사용하여 흡착제를 제조하였으며 이를 환원시켜 일산화탄소 제거 실험을 수행하였다. 흡착제는 EDS, TPR, XRD 분석을 실시하여 이를 근거로 흡착제의 성능을 해석하였다. 침전제의 종류, 니켈 금속의 담지량, 담체, 니켈 금속의 염, 수소 환원 조건을 변화시켜 최적의 흡착 성능을 보이는 흡착제를 사용하여 실험을 수행하였다. 침전제인 요소에 Ni(NO3)2·6H2O를 사용하여 실리카 담체에 니켈 54.8 wt%를 담지하여 제조한 흡착제를 500 oC에서 3시간 수소 환원 전처리 후 흡착 실험을 하였을 때 가장 효과적으로 일산화탄소를 제거함을 확인하였다.
The Ni based adsorbent was prepared by co-precipitation method and its performance for removing carbon monoxide was investigated. Here, silica, aluminium silicate and γ-alumina were used for carriers of catalyst. Ni(NO3)2·6H2O and Ni(CH3COO)2·4H2O were utilized for Ni precursors. Precipitants were urea and citric acid. After precipitation of Ni salt on the carrier and following reduction using H2 gas, adsorbent was prepared and its performance was analyzed based on EDS, TPR and XRD experiments. In accordance with change of precipitation agents, Ni salts on carrier, carriers and reduction condition. Adsorbent performance for removing carbon monoxide was investigated. The adsorbent with 54.8 wt% Ni prepared using urea precipitant under reduction condition at 500 oC for 3 h exhibited the best CO removal performance.
[References]
- Liang ZH, Zhu YJ, Hu XL, J. Phys. Chem. B, 108(11), 3488, 2004
- Xing W, Li F, Yan ZF, Lu GQ, J. Power Sources, 134(2), 324, 2004
- Jayalakshmi M, Venugopal N, Reddy BR, Rao MM, J. Power Sources, 150, 272, 2005
- Yoon YG, Pyun SI, “The Electrochemical View of Nickel Hydroxide as Cathode Materials in Alkaline Battery,” J. Corros Sci. Soc. Korea, Vol. 24 No. 2(1995)
- Kim MS, Kim KB, “A Study on the Electrochemical Redox Reaction of Electrochemically Precipitated Nickel Hydroxide,” J. Korean Inst, Met. & Mater., Vol. 33, No. 12(1995)
- Park JS, Yoon WL, Lee HT, Seo DJ, “Purification Catalyst of Reformed Gas and Preparation Method Thereof,” Korean Patent Appl., 10-2005-0091477
- Hong SJ, Lim MS, Chun YN, Korean Chem. Eng. Res., 45(6), 656, 2007
- Kwak C, Park TJ, Suh DJ, Chem. Eng. Sci., 60(5), 1211, 2005
- Sakae T, Toru S, Kiyoshi O, Int. J. Hydrogen Energy, 29, 1065, 2004
- Suh DJ, Kwak C, Kim JH, Kwon SM, Park TJ, J. Power Sources, 142(1-2), 70, 2005
- Hiroshi T, Walsh T, Wagner J, “Cross-reference to Related Applications,” Korean Patent Appl., 10-2006-7009638
- Richardson JT, Dubus RJ, J. Catalysis, 54, 207, 1978
- Ryoji T, Satoshi S, Toshiaki S, Masanori S, Nobuyuki I, Microporous and Mesoporous Materials, 66, 197, 2003
- Galo J, Matias J, Alberto ER, Miguel AB, Chem, Mater., 11, 3140, 1999
- Yazhong C, Wei Z, Zongping S, Nanping X, Catalysis Communications, 9, 1418, 2008
- Jasik A, Wojcieszak R, Monteverdi S, Ziolek M, Bettahar MM, J. Mol. Catal. A-Chem., 242(1-2), 81, 2005
- Kim SH, Nam SW, Lim TH, Lee HI, Applied Catalysis B: Environmental, 81, 97, 2008
- Ito M, Tagawa T, Goto S, Appl. Catal. A: Gen., 177(1), 15, 1999
- Cheekatamarla PK, Epling WS, Lane AM, J. Power Sources, 147(1-2), 178, 2005
- Watanabe M, Uchida H, Ohkubo K, Igarashi H, Appl. Catal. B: Environ., 46(3), 595, 2003
- Jo JS, Lee SH, Moon HM, “Apparatus for Refining a Nitrogen Gas and Method Thereof ,” Korean Patent Application, 10-2005-0030327
- Markowski ML, Bergman TJ, “Cryogenic System for Producing Ultra-high Purifity Nitrogen,” United States Patent Application, 5983667
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.