Search / Korean Journal of Chemical Engineering
HWAHAK KONGHAK,
Vol.33, No.3, 282-291, 1995
석탄-물혼합연료(CWM)의 유동 특성 및 배관에서의 압력 손실
Rheological Characteristics of Coal-Water Mixture Fuel and Pressure Losses in Pipe Flow
석탄-물 혼합연료(CWM)의 유동 성질을 power law model을 도입하여 Haake 점도계로 분석해 본 결과 전단속도가 0.1-512s-1인 범위에서 첨가제를 0.1wt% 이상 혼합한 CWM연료는 모두 pseudoplastic으로 표시되는 비뉴튼 유체의 특성을 나타냈다. CWM의 온도, 석탄의 평균 입경, 첨가제로 사용되는 음이온성 계면활성제의 투입량이 감소할수록 CWM의 겉보기 점도는 증가하였고, 첨가제를 사용하지 않을 경우에 측정되는 yield stress는 석탄 성분의 농도와 석탄 입자의 크기에 따라 차이를 보였다. 석탄의 농도가 줄어들면 CWM은 n=1인 뉴튼유체에 접근하였으며, 첨가제 사용량, 석탄의 평균 입경, 온도가 감소할수록 CWM의 비뉴튼 성질은 증가하였다. 또한 내경이 27.0mm인 파이프로 구성된 test loop에서 측정된 압력 손실은 power law 상수로부터 유도된 관계식에 의해 계산된 수치와 거의 일치하며, 비뉴특 유체에 적용되는 레이놀드 수(N*Re)-마찰 계수(f) 관계식을 사용하여 수평관을 통과하는 층류 상태의 CWM에 대한 압력 손실을 표시할 수 있었다.
The rheological characteristics of coal-water mixture(CWN) fuel, based on the power law model, were investigated using the Haake rotational viscometer, which produced shear rates from 0.1 to 512 s-1. Test results showed that all the slurries exhibited non-Newtonian properties of shear-thinning behavior, i.e., pseudoplastic or yield-pseudoplastic. The slurries become more viscous as the temperature, the mean particle size, and the amount of anionic surfactant were lowered. Furthermore, the yield stress measured in the case of no additive varied with the solid volume fraction and the coal particle size. The CWMs displayed a higher degree of pseudoplasticity with an increase in coal content and with a decrease in the mean size of the coal particles, the amount of additive, and the temperature. The pressure loss data obtained in the CWM test loop were coincided with the calculated values from the correlation based on the power law constants. Also, the generalized Reynolds number(N*Re)-friction factor(f) relationship could be applied to the laminar flow of CWM fuel.
[References]
  1. 김동찬, "CWM의 연소효율 증대를 위한 버너 및 분무기술 개발 연구(IV)," 한국에너지기술연구소 연구보고서, KRC-90G-T20, 1991
  2. 김동찬, "석탄-물 혼합연료의 기술개발 연구," 한국전력공사 기술연구원 연구보고서, KRC-85G-J04, 1990
  3. Papachristodoulou G, Trass O, Can. J. Chem. Eng., 65, 177, 1987
  4. Kang SW, Ph.D. Thesis, Dept. of MEchanical Engineering, M.I.T., Cambridge, Mass., 1988
  5. Ohene F, Bowman K, Williams A, Obonna B, Dooher JP, Proc. AM. Chem. Soc., Div. of Fuel Chemistry, 36, 129, 1991
  6. Olen KR, ASME Paper No. 84-JPGC-FU-D, p. 7, 1984
  7. Handerson CB, Scheffee RS, McHale ET, Energy Prog., 3, 69, 1983
  8. Boger DV, Leong YK, Mainwaring DE, Christie GB, Proc. 3rd Eur. Conf. on Coal Liquid Mxtures, Malmo," Sweden, October, 1, 1987
  9. Woskoboenko F, Siemon SR, Creasy DE, Fuel, 66, 1299, 1987
  10. Usui H, Sano Y, J. Chem. Eng. Jpn., 18, 519, 1985
  11. Szymanski JK, Mansour NA, Fuel Sci. Technol. Int., 5, 63, 1987
  12. Morgan ME, Heaton HL, Scheffee RS, Proc. 7th Int. Symp. on Coal Slurry Combustion and Technology, New Orleans, Louisiana, May, 104, 1985
  13. Sengun MZ, Probstein RF, Rheol. Acta, 28, 382, 1989
  14. Schramm G, "Introduction to Practical Viscometry," Gebrüder HAAKE GmbH, West Germany, 1981
  15. Govier GW, Aziz K, "The Flow of Complex Mixtures in Pipes," Robert E. Krieger Publishing Co., Inc., New York, 1972
  16. Skelland AHP, "Non-Newtonian Flow and Heat Transfer," John Wiley & Sons, Inc., New York, 1967
  17. Kaji R, Muranaka Y, Miyadera H, Hishinuma Y, AIChE J., 33, 11, 1987
  18. Tsai SC, Knell EW, Fuel, 65, 566, 1986
  19. Turian RM, Fakhreddine MK, Avramidis KS, Sung DJ, Fuel, 72, 1305, 1993
  20. Krishna CR, Sapienza RS, Proc. 2nd Eur. Conf. on Coal Liquid Mixtures, London, Spetember, 115, 1984
  21. Stover NSH, Thambimuthu KV, Todd A, Proc. 15th Int. Conf. on Coal & Slurry Technologies, Clearwater, Florida, April, 397, 1989
  22. Tadros TF, Proc. 2nd Eur. Conf. on Coal Liquid Mixtures, London, September, 1, 1985
  23. Dinger DR, Funk JE, Proc. 4th Int. Symp. on Coal Slurry Combustion, Orlando, Florida, May, 1982
  24. Hiemenz PC, "Principles of Colloid and Surface Chemistry," 2nd ed., Marcel Dekker, Inc., New York, 1986
  25. Morrison JL, Miller BG, Scaroni AW, Proc. 18th Int. Tech. Conf. on Coal Utilization & Fuel Systems, Clearwater, Florida, April, 361, 1993
  26. Hara S, Arai H, Sugawara H, Ukigai T, Yoshida E, Ogawa J, Proc. 17th Int. Conf. on Coal Utilization & Slurry Technologies, Clearwater, Florida, April, 71, 1992
  27. Zhaoxiang H, Yifeng W, Yizhen W, Zhangjie L, Wenhui Z, Proc. 5th Int. Symp. on Coal Slurry Combustion and Technology, Tampa, Florida, June, 1000, 1983
  28. Usui H, Yamasaki Y, Sano Y, J. Chem. Eng. Jpn., 20, 65, 1987
  29. Andrade EN, Nature, 125, 309, 1930
  30. Metzner AB, Reed JC, AIChE J., 1, 434, 1955
  31. Metzner AB, Ind. Eng. Chem., 49, 1429, 1957