| Search / Korean Journal of Chemical Engineering |
HWAHAK KONGHAK,
Vol.32, No.2, 222-232, 1994
Vol.32, No.2, 222-232, 1994
막반응기에서 Aliquat 336에 의한 n-butyl acetate의 알칼리 가수분해반응 I.이론적 고찰
Alkaline Hydrolysis of n-Butyl Acetate with Aliquat 336 in a Membrane Reactor-I. Theoretical Study
막반응기를 사용하여 상이동촉매에 의한 유기상과 수용액상간 불균일 반응계에서 준1차 화학반응을 수반한 물질전달기구를 경막설에 적용한 확산방정식의 수치해로부터 막내의 각 성분에 대한 농도 분포와 전화율을 산출하고, 막박응기의 특성치를 사용하여 액-액 접촉계면 저항이 상이동촉매 반응에 미치는 영향을 검토하여 막반응기의 성능을 모사하였다.
A theoretical model about a phase transfer catalyzed liquid-liquid heterogeneous reaction system in a hydrophobic membrane reactor was developed by the chemical-diffusion equations from the mass transfer mechanism with the approximated pseudo 1st-order reaction, and the performance of the membrane reactor was analyzed with the interaction of mass transfer with chemical reaction from this simulation.
[References]
- Starks CM, J. Am. Chem. Soc., 93, 195, 1971
- Weber WP, Gokel GW, "Phase Transfer Catalysis in Organic Synthesis," Springer-Verlag, New York, 1977
- Starks CM, "Phase Transfer Catalysis," Academic Press, New York, 37, 1978
- Dehmlow EV, Dehmlow SS, "Phase Transfer Catalysis," Verlag Chemie GmbH, Weinheim, 1983
- Freedman HH, Pure Appl. Chem., 58, 857, 1986
- Starks CM, "Phase Transfer Catalysis-New Chemistry, Catalysts, and Applications," Symp. Am. Chem Soc., 1987
- Wang D, Weng H, Chem. Eng. Sci., 43, 2019, 1988
- Wang M, Yang H, Ind. Eng. Chem. Res., 29, 522, 1990
- Do J, Chou T, Ind. Eng. Chem. Res., 29, 1095, 1990
- Wang M, Wu H, Chem. Eng. Sci., 46, 509, 1991
- Park SW, Moon JB, Park DW, Shin JH, HWAHAK KONGHAK, 30(5), 612, 1992
- Park SW, Moon JB, Park DW, Shin JH, HWAHAK KONGHAK, 31(1), 107, 1993
- Park SW, Moon JB, Hwang KS, J. Korean Ind. Eng. Chem., to be submitted, 1993
[Cited By]
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.